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14242-05-8
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SILVER PERCHLORATE HYDRATE
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SILVER PERCHLORATE;SILVER PERCHLORATE HYDRATE;SILVER PERCHLORATE, HYDRATED;SILVER PERCHLORATE 1-HYDRATE;SILVER(I) PERCHLORATE HYDRATE;SILVER PERCHLORATE MONOHYDRATE;Silver perchlorate hydrate 99 %;Silverperchloratemonohydrate,99%;SILVER(I) PERCHLORATE MONOHYDRATE;Silver perchlorate hydrate, 99% 5GR
CBNumber:
CB5180174
???:
AgClH3O5
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226.34
MOL ??:
14242-05-8.mol
MSDS ??:
SDS

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43 °C
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2,8 g/cm3
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Refrigerator (+4°C)
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Light Sensitive & Hygroscopic
Merck
14,8523
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CAS ??????
14242-05-8(CAS DataBase Reference)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
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?? ???? ?? 8-34-1
????? 26-36/37/39-45
????(UN No.) UN 1481 5.1/PG 2
WGK ?? 3
F ?????? 3-8-10
TSCA Yes
?? ?? 5.1
???? II
HS ?? 28432900
????(GHS): GHS hazard pictogramsGHS hazard pictograms
?? ?: Danger
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?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H272 ??? ???? ?; ??? ??? ??;??? ?? ?? 2
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GHS hazard pictograms P210, P220, P221P280, P370+P378,P501
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
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P210 ?·???·??·????? ????? - ?? ???.
P220 ?? ??? ??? ????? ?????.
P260 ??·?·??·???·??·...·????? ???? ???.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
0
2 2
OX

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WHITE CRYSTALS OR CRYSTALLINE POWDER

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Silver perchlorate can be used in the manufacturing of explosives. It is generally used as a source of silver ions during silver nanoparticles synthesis. It is used as a catalyst in organic chemistry.

Purification Methods

Reflux it with *benzene (6mL/g) in a flask fitted with a Dean and Stark trap until all the water is removed azeotropically (ca 4hours). The solution is cooled and diluted with dry pentane (4mL/g of AgClO4). The precipitated AgClO4 is filtered off and dried in a desiccator over P2O5 at 1mm for 24hours [Radell et al. J Am Chem Soc 83 3958 1961]. It has also been recrystallised from perchloric acid. [Caution due to its EXPLOSIVE nature in the presence of organic matter.] Store it in the dark.

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