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(S)-(+)-4-METHYL-2-???

(S)-(+)-4-METHYL-2-???
(S)-(+)-4-METHYL-2-??? ??? ???
?? ??:
14898-80-7
???:
(S)-(+)-4-METHYL-2-???
???(??):
(S)-(+)-4-METHYL-2-???
???:
(S)-(+)-4-METHYL-2-PENTANOL
???(??):
4-METHYL (S)-2-PENTANOL;(S)-1,3-Dimethyl-1-butanol;(S)-(+)-4-METHYL-2-PENTANOL;(S)-(+)-4-METHYLPENTAN-2-OL;2-Pentanol, 4-methyl-, (2S)-;(S)-(+)-4-Methyl-2-pentanol 1GR;(S)-(+)-Methyl isobutyl carbinol;(S)-(+)-4-METHYL-2-PENTANOL, 99% (99+% ee);(S)-(+)-4-METHYL-2-PENTANOL ISO 9001:2015 REACH;(S)-(+)-4-Methyl-2-pentanol(S)-(+)-Methyl isobutyl carbinol
CBNumber:
CB5156546
???:
C6H14O
??? ??:
102.17
MOL ??:
14898-80-7.mol

(S)-(+)-4-METHYL-2-??? ??

?? ?
138 °C(lit.)
??
0.802 g/mL at 25 °C(lit.)
???
n20/D 1.4790(lit.)
???
106 °F
?? ??
Flammables area
??? ??
??
?? ?? (pKa)
15.31±0.20(Predicted)
Specific Gravity
0.802
??
???
???
?? ?? ?????. ???? ?????.
BRN
1718991
LogP
1.546 (est)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi,Xn
?? ???? ?? 10-37-66-20
????? 24/25-46
????(UN No.) UN 2053 3/PG 3
WGK ?? 1
?? ?? 3
???? III
HS ?? 29051900
????(GHS): GHS hazard pictogramsGHS hazard pictograms
?? ?:
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H226 ??? ?? ? ?? ??? ?? ?? 3 ??
H303 ??? ??? ? ?? ?? ?? ?? - ?? ?? 5 P312
H313 ??? ???? ??? ? ?? ?? ?? ?? - ?? ?? 5 P312
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P262 ?, ??, ??? ?? ??? ???.
NFPA 704
2
2 0

(S)-(+)-4-METHYL-2-??? C??? ??, ??, ??

??? ??

Clear colorless liquid

??

It is employed in the reaction of 2-methoxyethyl acetals with allylsilanes in the presence of titanium tetrachloride: regioselective carbon-oxygen bond cleavage of the unsymmetrical acetals.

(S)-(+)-4-METHYL-2-??? ?? ?? ? ???

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(S)-(+)-4-METHYL-2-??? ?? ??

???( 56)?? ??
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(S)-(+)-4-METHYL-2-??? ?? ??:

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