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935-04-6
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Benzyl vinyl ether
???(??):
BenzylVinylEther;Vinyl benzyl ether;1-(Benzyloxy)ethene;Benzyl ethenyl ether;ethenoxymethylbenzene;Vinyloxymethyl-benzene;[(ethenyloxy)methyl]benzene;Benzene,[(ethenyloxy)methyl]-;Benzyl vinyl ether/((Vinyloxy)methy)benzene
CBNumber:
CB51073941
???:
C9H10O
??? ??:
134.18
MOL ??:
935-04-6.mol

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183-184 °C
??
0.9710 g/cm3
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68 °C
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under inert gas (nitrogen or Argon) at 2-8°C
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Specific Gravity
0.97
InChI
InChI=1S/C9H10O/c1-2-10-8-9-6-4-3-5-7-9/h2-7H,1,8H2
InChIKey
AZDCYKCDXXPQIK-UHFFFAOYSA-N
SMILES
C1(COC=C)=CC=CC=C1
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  • ?? ? ???? ?? (GHS)
HS ?? 2909309090
????(GHS): GHS hazard pictograms
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H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? GHS hazard pictograms P264, P270, P301+P312, P330, P501
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P280 ????/???/???/?????? ?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

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Benzyl vinyl ether is an organic raw material intermediate compound used in the synthesis of 2-(Benzyloxy)acetaldehyde and 3-(Benzyloxy)cyclobutanone.

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A crystalline poly(benzyl vinyl ether) (PBVE) was obtained by the polymerization of benzyl vinyl ether (BVE). The benzyl vinyl ether polymerization has been investigated in toluene by Et3Al-TiCJ4 catalyst. When the catalyst preparation and the monomer addition were carried out at 0°C, and the reaction mixture was brought to 60°C, an insoluble polymeric product was obtained with poly(benzyl vinyl ether) (PBVE). This was formed by the reaction of PBVE and TiC14 in the catalyst system and the subsequent hydrolysis of the reaction product. The living cationic polymerization of benzyl vinyl ether was achieved by the CH3CH(OiBu)OCOCHil)/EtAICl2 initiating system in the presence of added bases. Polymerizations in the presence of ethyl acetate at below 0°C in a non-polar solvent (toluene or CCl4 ) gave living polymers with a narrow molecular weight distribution (MWD) (Mw/M. - 1.1)[1-2].

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