ChemicalBook >?? ???? >N-?????-N-?????
N-?????-N-?????
|
|
N-?????-N-????? ??
- ?? ?
- 313 °C(lit.)
- ??
- 1.035 g/mL at 25 °C(lit.)
- ???
- n
20/D 1.56(lit.)
- ???
- 125-127°C/4mm
- ?? ??
- Inert atmosphere,Room Temperature
- ??? ??
- ??? ??
- ?? ?? (pKa)
- 4.54±0.50(Predicted)
- ??
- White to Yellow to Green
- Specific Gravity
- 1.05
- BRN
- 2803416
- CAS ??????
- 94-34-8(CAS DataBase Reference)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
??? ?? | Xn | ||
---|---|---|---|
?? ???? ?? | 20/21/22-36/37/38-21/22 | ||
????? | 26-36-36/37 | ||
WGK ?? | 3 | ||
TSCA | Yes | ||
???? | III | ||
HS ?? | 29214300 | ||
???? ?? | KE-24804 |
N-?????-N-????? C??? ??, ??, ??
Synthesis
An activated carbon-supported platinum catalyst (Pt / C, 0.06 mg platinum, 0.0003 mmol, 0.1 mol percent) was added to a 10 mL Schlenk tube; after the evacuation of argon, add 1 mL of solvent (toluene). Under argon protection, to the above system, Were successively added phenylsilane (78.9 mg, 0.75 mmol), 3-Anilinopropionitrile (43.9 mg, 0.3 mmol) and formic acid (27.6 mg, 0.6 mmol). The whole anti-reaction was carried out at 80 ° C with stirring for 15 hours. After completion of the reaction, 3 mL of ethyl acetate was added to the system. The reaction was quenched with aqueous sodium hydroxide (3 mol / L, 3 mL). Ethyl acetate (3 x 10 mL), the organic phase was separated, Dried over anhydrous Na2SO4, and filtered; the solvent was removed by rotary evaporation. The residue was purified by column chromatography on ethyl acetate/petroleum ether = 1: 50 mixed solvent. Separation and purification gave N-(2-Cyanoethyl)-N-methyl aniline 226.4 mg, yield of 55 per cent.N-?????-N-????? ?? ?? ? ???
???
?? ??
N-?????-N-????? ?? ??
???( 152)?? ??
??? | ?? | ??? | ?? | ?? ? | ?? |
---|---|---|---|---|---|
Shaanxi Dideu Medichem Co. Ltd | +86-29-81148696 +86-15536356810 |
1022@dideu.com | China | 3882 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 |
sales1@chuanghaibio.com | China | 5893 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 18754 | 58 |
Anhui Royal Chemical Co., Ltd. | +86-25-86655873 +8613962173137 |
marketing@royal-chem.com | China | 192 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29885 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 |
sales@chemdad.com | China | 39894 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49374 | 58 |
SIMAGCHEM CORP | +86-13806087780 |
sale@simagchem.com | China | 17365 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 |
sales@tnjchem.com | China | 34553 | 58 |
N-?????-N-????? ?? ??:
N-????? ?????(2-) N-????? 3-???????????? ????-p-?????? N,N-?????? ?????(3-) C.I. ???? ??? 30 ??????? 3-[[2-(?????)??]?????]??????; N-?????-N-????????? ??????
3,3',5,5'-Tetramethylbenzidine dihydrochloride
3-Ethylanilinopropiononitrile
N-Cyanoethyl-hydroxyethyl aniline
N-CYCLOHEXYLFORMAMIDE
N-Cyanoimido-S,S-dimethyl-dithiocarbonate
CHES
N-Cyclohexyl-4-methylbenzenesulfonamide