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Cyclopropylboronic acid

Cyclopropylboronic acid ??? ???
?? ??:
411235-57-9
???:
Cyclopropylboronic acid
???(??):
Cyclopropylboronic;Cyclopropaneboronic acid;AKOS BRN-0457;Boronocyclopropane;Cyclopropylboronica;CYCLOROPYLBORONIC ACID;CYCLOPROPYLBORONIC ACID;B-Cyclopropylboronic Acid;Boronic acid, cyclopropyl-;Cyclopropylboronic acid 95%
CBNumber:
CB3133570
???:
C3H7BO2
??? ??:
85.9
MOL ??:
411235-57-9.mol
MSDS ??:
SDS

Cyclopropylboronic acid ??

???
90-95 °C (lit.)
?? ?
205.1±23.0 °C(Predicted)
??
1.11±0.1 g/cm3(Predicted)
?? ??
-20°C
???
? ???DMSO
?? ?? (pKa)
10.49±0.20(Predicted)
??? ??
??
??
???
??
moisture sensitive
InChIKey
WLVKDFJTYKELLQ-UHFFFAOYSA-N
CAS ??????
411235-57-9(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn,T
?? ???? ?? 22-36-61-60-36/37/38
????? 26-36-45-53-37/39
WGK ?? 3
TSCA No
?? ?? IRRITANT, IRRITANT-HARMFUL
HS ?? 29319090
????(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H318 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 1 ?? GHS hazard pictograms P280, P305+P351+P338, P310
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P201 ?? ? ?? ???? ?????.
P261 ??·?·??·???·??·...·????? ??? ????.
P280 ????/???/???/?????? ?????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P308+P313 ?? ?? ??? ???? ???? ??· ??? ????.
P405 ???? ?????.
NFPA 704
1
2 1

Cyclopropylboronic acid C??? ??, ??, ??

??? ??

White to off-white powder

??

Reagent used for• ;Microwave-assisted copper(II)-catalyzed N-cyclopropylation1• ;Nickel- and copper-catalyzed Suzuki-Miyaura coupling reaction of arenes2• ;Palladacycle-catalyzed Suzuki-cross coupling of aryl halides with cyclopropylboronic acid3• ;Palladium(0)-catalyzed cyclopropane C-H bond functionalization4• ;Palladium-catalyzed decarboxylative coupling5• ;Palladium-catalyzed ligand-directed oxidative functionalization of cyclopropanes6• ;Palladium-catalyzed Suzuki coupling reaction7Reagent used in Preparation of• ;Diaryl ketones by arylation

Cyclopropylboronic acid ?? ?? ? ???

???

?????????????????????? Potassium cyclopropyltrifluoroborate Cyclopropylboronic acid pinacol ester Cyclopropylmagnesium bromide ??????

?? ??

Benzene, 1,4-dicyclopropyl-2-nitro- ??-????????? 2-BroMo-5-?????????? 2-broMo-5-????????? 3-?????????? 4-???-1-??????-1H-??? 4,4'-DICHLORODIPHENYL DISULFIDE 5-???????-2-?????????? 3-CYCLOPROPYL-5-(TRIFLUOROMETHYL)ANILINE 3-Bromo-5-cyclopropylisonicotinonitrile

Cyclopropylboronic acid ?? ??

???( 540)?? ??
??? ?? ??? ?? ?? ? ??
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Cyclopropylboronic acid ?? ??:

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