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(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE

(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE ??? ???
?? ??:
71042-55-2
???:
(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE
???(??):
(-)-NORPHOS;(R,R)-NORPHOS;(2R,3R)-(-)-Norphos;(5R,6R)-5,6-Bis(diphenylphosphino)bicyclo[2.2.1]hept-2-ene;(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO) B IC.(2.2.1)HEPT-5-EN;(1β,4β)-5β,6α-Bis(diphenylphosphino)bicyclo[2.2.1]hepta-2-ene;(1α,4α)-5β,6α-Bis(diphenylphosphino)bicyclo[2.2.1]hepta-2-ene;(2R,3R)-(-)-2,3-Bis(diphenylphosphino)-bicylo[2.2.1]hept-5-ene;(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE;(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicycle(2.2.1)hept-5-ene
CBNumber:
CB2255466
???:
C31H28P2
??? ??:
462.51
MOL ??:
71042-55-2.mol

(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE ??

???
120-125 °C
?? ?
577.0±50.0 °C(Predicted)
??
-47° (c 1, CHCl3)
?? ??
2-8°C
??? ??
?? ??
??
???
??
air sensitive
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36
WGK ?? 3
F ?????? 10-23
TSCA No
HS ?? 2931.90.6000
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P280 ????/???/???/?????? ?????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P405 ???? ?????.

(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE C??? ??, ??, ??

?? ??

  1. Ligand used in the enantioselective rhodium catalyzed hydrogenation of α–dehydroaminoesters and enamides.
  2. Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
  3. Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.
  4. Iridium or Rhodium-catalyzed asymmetric Diels-Alder reaction.
Reactions of 71042-55-2

(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE ?? ?? ? ???

???

?? ??

(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE ?? ??

???( 64)?? ??
??? ?? ??? ?? ?? ? ??
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(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE ?? ??:

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