(????????)??
|
|
(????????)?? ??
- ???
- 161-163 °C (lit.)
- ??
- 1.6865 (estimate)
- ???
- n/D 1.444
- ?? ??
- Keep in dark place,Sealed in dry,Room Temperature
- ???
- ???
- ??? ??
- ??
- ??
- ??~?? ??~??
- ???
- ???
- ??
- Light Sensitive
- BRN
- 1879369
- ???
- ?? ??? ???
- InChIKey
- ZBIKORITPGTTGI-UHFFFAOYSA-N
- CAS ??????
- 3240-34-4(CAS DataBase Reference)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
??? ?? | Xi | ||
---|---|---|---|
?? ???? ?? | 36/37/38 | ||
????? | 22-24/25-37/39-26-36/37/39-27 | ||
????(UN No.) | 1479 | ||
WGK ?? | 3 | ||
RTECS ?? | DA3525000 | ||
F ?????? | 4.10-8 | ||
?? ?? ?? | Irritant | ||
TSCA | Yes | ||
?? ?? | 6.1(b) | ||
???? | III | ||
HS ?? | 29310095 |
(????????)?? C??? ??, ??, ??
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white to light yellow crystal powderOrigin
This reagent was originally prepared by Conrad Willgerod by reacting iodobenzene with a mixture of acetic acid and peracetic acid:C6H5I + CH3CO3H + CH3CO2H → C6H5I(O2CCH3)2 + H2O
Purification Methods
The purity of diacetoxyiodobenzene can be checked by treatment with H2SO4 then KI and the liberated I2 is estimated with standard thiosulfate. It has been recrystallised from 5M acetic acid and dried overnight in a vacuum desiccator over CaCl2. The surface of the crystals may become slightly yellow but this does not affect its usefulness. [Sharefkin & Saltzman Org Synth Coll Vol V 600 1973, Beilstein 5 IV 693.](????????)?? ?? ?? ? ???
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4-???????????
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Trimethylsilyl acetate
[N-(p-??????)???]??????
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(????????)?? ?? ??:
?????? ????
Cuprous iodide
Irinotecan hydrochloride
Irinotecan hydrochloride trihydrate
Topotecan hydrochloride
Iodosobenzene
2,4,6-TRIMETHYL(DIACETOXYIODO)BENZENE
[Bis(trifluoroacetoxy)iodo]benzene
P-(DIACETOXYIODO)-TOLUENE
(Diacetoxyiodo)benzene
Dess-Martin periodinane
[BIS(TRIFLUOROACETOXY)IODO]PENTAFLUOROBENZENE
BIS(ACETATO-O)(3-METHOXYPHENYL)IODINE
IODOSOBENZENE DIACETATE, [(DIACETOXYIODO)BENZENE; PHENYLIODOSODIACETATE)
IODOSOBENZENEDIACETATE, [(DIACETOXYIODO)BENZENE; PHENYLIODOSODIACETATE)
AKOS MSC-0741
AURORA KA-4499