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1-???-4-??????????

1-???-4-??????????
1-???-4-?????????? ??? ???
?? ??:
407-14-7
???:
1-???-4-??????????
???(??):
1-???-4-(??????????)??;1-???-4-??????????;1-???-4-(?????????)??
???:
1-Bromo-4-(trifluoromethoxy)benzene
???(??):
4-Bromozbenzotrifluoride;P-BROMOTRIFLUOROMETHOXYBENZENE;4-(TRIFLUOROMETHOXY)BROMOBENZENE;1-Bromo-4-(trifL;TIMTEC-BB SBB006606;1-Bromo-4-(trifluoro;Benzene, 1-bromo-4-(trifluo;P-Bromotrifluoromethoxybenzen;1-Bromo-4-(Trifluoromethoxy)Be;P-TRIFLUOROMETHOXY BROMOBENZENE
CBNumber:
CB1413764
???:
C7H4BrF3O
??? ??:
241.01
MOL ??:
407-14-7.mol
MSDS ??:
SDS

1-???-4-?????????? ??

?? ?
80 °C50 mm Hg(lit.)
??
1.622 g/mL at 25 °C(lit.)
???
20 hPa (55 °C)
???
n20/D 1.461(lit.)
???
154 °F
?? ??
Sealed in dry,Room Temperature
???
11.7mg/L
??? ??
??
Specific Gravity
1.64
??
??~???? ???
???
11.7mg/L
BRN
2046332
InChI
InChI=1S/C7H4BrF3O/c8-5-1-3-6(4-2-5)12-7(9,10)11/h1-4H
InChIKey
SEAOBYFQWJFORM-UHFFFAOYSA-N
SMILES
C1(Br)=CC=C(OC(F)(F)F)C=C1
CAS ??????
407-14-7(CAS DataBase Reference)
NIST
P-bromophenyl trifluoromethyl ether(407-14-7)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn,N,Xi
?? ???? ?? 22-36/37/38-43-51/53
????? 26-36/37-61-37/39-36
????(UN No.) UN 3082 9/PG 3
WGK ?? 1
?? ?? IRRITANT
HS ?? 29093090
?? LD50 orally in Rabbit: > 2500 mg/kg
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
NFPA 704
2
1 0

1-???-4-?????????? MSDS


1-Bromo-4-(trifluoromethoxy)benzene

1-???-4-?????????? C??? ??, ??, ??

??? ??

CLEAR COLOURLESS TO YELLOW LIQUID

??

1-Bromo-4-(trifluoromethoxy)benzene was used in the synthesis of 4-{[4-[(2-ethylhexyloxy)-6-(4-morpholinylmethyl)-4-trifluoromethyl][1,1-biphenyl]-3-yl]methyl}morpholine.

?? ??

1-Bromo-4-(trifluoromethoxy)benzene on treatment with lithium diisopropylamide (LIDA) at -100°C gives 5-bromo-2-(trifluoromethoxy)phenyllithium and at -75°C it eliminates lithium bromide, thus generating 1,2-dehydro-4-(trifluoromethoxy)benzene.

1-???-4-?????????? ?? ?? ? ???

???

?????

?? ??

1-Iado-4-(trifluoromethoxy)benzene 4-(?????????)??? 3-(Trifluoromethoxy)bromobenzene (4-???-??)-(4-?????????-??)-??? 3-[4-(?????????)??]????? ??5-???-2-(?????????)????? 4-Trifluoromethoxyphenylboronic acid

1-???-4-?????????? ?? ??

???( 481)?? ??
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