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???????? ??? ???
?? ??:
6138-90-5
???:
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???(??):
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GERANYL BROMIDE
???(??):
(E)-1-bromo-3,7-dimethylocta-2,6-diene;1-BROMO-3,7-DIMETHYL-2,6-OCTADIENE;trans-Geranyl bromide;DK843;eranyL;GERANYL BROMIDE;Einecs 228-123-7;Geranylbromide,97%;Geranyl bromide 95%;Geranyl Bromide (>
CBNumber:
CB1238712
???:
C10H17Br
??? ??:
217.15
MOL ??:
6138-90-5.mol
MSDS ??:
SDS

???????? ??

?? ?
101-102 °C12 mm Hg(lit.)
??
1.094 g/mL at 25 °C(lit.)
???
n20/D 1.504(lit.)
???
203 °F
?? ??
2-8°C
???
?????, ???? ???
??? ??
??
??
Clear Yellow to Pale Orange
???
?? ??? ????.
??
Light Sensitive
BRN
1422412
InChIKey
JSCUZAYKVZXKQE-JXMROGBWSA-N
CAS ??????
6138-90-5(CAS DataBase Reference)
EPA
2,6-Octadiene, 1-bromo-3,7-dimethyl-, (2E)- (6138-90-5)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36
????(UN No.) 2810
WGK ?? 3
F ?????? 8-10-19
TSCA Yes
?? ?? 6.1(b)
???? III
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
2
2 0

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Geranyl bromide is used for the preparation of 3,7-dihydroxyflavone derivatives and baicalein. It is also involved in the synthesis of potential flavonoidic modulators of P-glycoprotein activity. Further, it reacts with benzenesulfinic acid to prepare geranyl phenyl sulfone. In addition to this, it takes part in the palladium catalyzed cross coupling with aryl and alkenylgold(I) phosphanes.

?? ??

Geranyl bromide undergoes palladium catalyzed cross-coupling reaction with aryl and alkenylgold(I) phosphanes.

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