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3-(BENZYLAMINO)PROPIONITRILE

3-(BENZYLAMINO)PROPIONITRILE ??? ???
?? ??:
706-03-6
???:
3-(BENZYLAMINO)PROPIONITRILE
???(??):
β-(Benzylamino)propionitrile;3-(BENZYLAMINO)PROPIONITRILE;3-(Benzylamino)propionitrile 97%;3-(BENZYLAMINO)PROPIONITRILE, 97+%;N-(2-Cyanoethyl)benzenemethanamine;3-[(Phenylmethyl)amino]propanenitrile;Propanenitrile, 3-[(phenylmethyl)amino]-
CBNumber:
CB1159680
???:
C10H12N2
??? ??:
160.22
MOL ??:
706-03-6.mol
MSDS ??:
SDS

3-(BENZYLAMINO)PROPIONITRILE ??

???
70 °C
?? ?
276.13°C (rough estimate)
??
1.024 g/mL at 25 °C (lit.)
???
n20/D 1.5308(lit.)
???
>230 °F
?? ??
Refrigerator
???
DMSO? ?????.
??? ??
??
?? ?? (pKa)
7.29±0.19(Predicted)
??
???
Specific Gravity
1.024
CAS ??????
706-03-6
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn,Xi
?? ???? ?? 20/21/22-36/37/38
????? 26-37/39
????(UN No.) UN3276
WGK ?? 3
?? ?? 6.1
???? III
HS ?? 29269095
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P280 ????/???/???/?????? ?????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
1
2 0

3-(BENZYLAMINO)PROPIONITRILE C??? ??, ??, ??

??? ??

CLEAR COLOURLESS LIQUID

??

3-(BenzylaMino)propionitrile is used in the michael addition of primary and secondary amines to acrylonitrile catalyzed by lipases.

?? ??

3-(Benzylamino)propionitrile was used as starting reagent in the synthesis of:
(3R,4S)-1-benzyl-4-phenylpyrrolidine-3-carboxylic acid, key chiral building block for synthesis of biologically active compounds
1-{[benzyl-(2-cyano-ethyl)-amino]-methyl}-5-methyl-1H-pyrazole-3-carboxylic acid ethyl ester
3-[benzyl-(3,5-dimethyl-pyrazol-1-ylmethyl)-amino]-propionitrile

?? ??

3-(Benzylamino)propionitrile undergoes aza-type Michael reaction with 1-hydroxymethyl-5-methyl-1H-pyrazole-3-carboxylic acid ethyl ester under mild conditions.

3-(BENZYLAMINO)PROPIONITRILE ?? ?? ? ???

???

?? ??

3-(BENZYLAMINO)PROPIONITRILE ?? ??

???( 53)?? ??
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3-(BENZYLAMINO)PROPIONITRILE ?? ??:

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