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?????? ??? ???
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12124-97-9
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???(??):
????HYDROBROMICACIDMONOAMMONIATE;??????;???????;???????;???????;???????;????;??????;????????
???:
Ammonium bromide
???(??):
(NH4)Br;FR-11;Azanium bromide;ammonmm bromide;AMMONIUM BROMIDE;AmmoniumBromideGr;Ammonium Bromide AR;AMMONIUM BROMIDE, ACS;AMMONIUM BROMIDE pure;Ammonium bromide 99+ %
CBNumber:
CB1126958
???:
BrH4N
??? ??:
97.94
MOL ??:
12124-97-9.mol

?????? ??

???
452 °C (lit.)
?? ?
396 °C/1 atm (lit.)
??
2.43 g/mL at 25 °C (lit.)
???
1 mm Hg ( 198.3 °C)
?? ??
Inert atmosphere,Room Temperature
???
H2O: 1 M at 20 °C, ??, ??
?? ?? (pKa)
-1.03±0.70(Predicted)
??? ??
??/??
??
???
Specific Gravity
2.429
??
?? ??
pH ??
4.5 - 6.0
??????(pH)
5.0-6.0 (25℃, 50mg/mL in H2O)
???
97g/100mL(25℃)
??
Hygroscopic
Merck
14,505
Dielectric constant
7.2(0.0℃)
???
????. ?, ??? ??, ??? ??, ???? ???? ??? ???? ????.
LogP
-1 at 25℃
CAS ??????
12124-97-9(CAS DataBase Reference)
NIST
Ammonium bromide(12124-97-9)
EPA
Ammonium bromide (12124-97-9)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn,Xi
?? ???? ?? 22-36/37/38-36
????? 22-24/25
WGK ?? 2
RTECS ?? BO9155000
TSCA Yes
HS ?? 28275900
?? ?? ??? 12124-97-9(Hazardous Substances Data)
?? LD50 orally in Rabbit: 2714 mg/kg
???? ?? KE-01639
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P337+P313 ?? ?? ??? ???? ???? ??· ??? ????.
NFPA 704
0
2 0

?????? MSDS


Ammonium bromide

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??? ????? (NH4Br)? ?? ?? ?? ? ?? ??? ??? ???? ?????.
?? ???? ?? ? ?? ??? biocide? ?????.

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Ammonium bromide is soluble in water and alcohol and is not particularly hazardous under normal conditions.

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Ammonium bromide is a weak acid with a pKa of approximately 5 in water. It is an acid salt because the ammonium ion hydrolyzes slightly in water.
NH4Br(s) → NH+4(aq) + Br-(aq)
It decomposes to ammonia and hydrogen bromide when heated at elevated temperatures.

??? ??

Colorless rhombic crystal; odor of ammonia; sublimes at 60°C; very soluble in cold water; decomposes in hot water; slightly soluble in alcohol; insoluble in acetone.

??

Ammonium bromide is a colorless crystals used for its bromide ion, it was also used as a halide in collodion formulas and as a restrainer in alkaline developers.

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Ammonium bromide can be prepared by the direct action of hydrogen bromide on ammonia. NH3 + HBr → NH4Br

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ChEBI: An ammonium salt composed of ammonium and bromide ions in a 1:1 ratio.

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White odorless crystals or granules that become yellow upon exposure to air. Sinks and mixes in water.

??? ?? ??

Water soluble

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Bromine trifluoride reacts explosively with the following Ammonium bromide, ammonium chloride, ammonium iodide [Mellor 2 Supp. 1:165 1956].

????

INHALATION: Dust irritating - disturbed behavior, sedation. EYES: Slight irritation. SKIN: Slight irritation only with repeated or prolonged contact. INGESTION: Weakness, nervousness, anorexia, confusion, hallucinations, drowsiness, irritability, ataxia, vertigo, skin rash.

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Special Hazards of Combustion Products: Material decomposes into N 2 and HBr or Br 2 under extreme temperatures.

Purification Methods

It crystallises from 95% EtOH and is slightly hygroscopic.

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