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ChemicalBook >> CAS DataBase List >>Nessler's Reagent

Nessler's Reagent

CAS No.
7783-33-7
Chemical Name:
Nessler's Reagent
Synonyms
Nessler;potassium tetraiodomercurate;NESSLER REAGENT;nessler’s;nessler'S;MAYER'S REAGENT;NESSLERS REAGENT;NESSLER'S REAGENT;NESSLER'S REAGENT;AMMONIA NITROGEN 2
CBNumber:
CB2481117
Molecular Formula:
HgI4K2
Molecular Weight:
786.4
MDL Number:
MFCD00049656
MOL File:
7783-33-7.mol
Last updated:2024-12-18 14:08:52

Nessler's Reagent Properties

Melting point 120-127 °C(lit.)
Boiling point 105°C
Density 1.16 g/mL at 20 °C
Flash point >230 °F
solubility very soluble in H2O; soluble in ethanol,ethyl ether, acetone
form Liquid
color Yellow to orange
Specific Gravity 1.097
Odor Odorless
Water Solubility Soluble in water.
Sensitive Hygroscopic
Merck 13,7773
Exposure limits ACGIH: TWA 0.025 mg/m3 (Skin)
NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3
Stability Stable, but light sensitive. Incompatible with strong oxidizing agents.
InChIKey OPCMAZHMYZRPID-UHFFFAOYSA-J
FDA UNII 7N83S6IU0F
EPA Substance Registry System Potassium mercuric iodide (7783-33-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H290-H301+H331-H310-H314-H373-H410
Precautionary statements  P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P314
Hazard Codes  T,N,T+
Risk Statements  26/27/28-33-35-51/53-52/53-23/24/25-48/21/22-25-50/53-68-24/25
Safety Statements  45-36/37-61-36/37/39-28-26-60-13
RIDADR  UN 3287 6.1/PG 3
WGK Germany  3
RTECS  OU9670000
8-30
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  28521000
Hazardous Substances Data 7783-33-7(Hazardous Substances Data)
NFPA 704
1
4 1

Nessler's Reagent price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 72190 Nessler’s reagent for qualitative det. of ammonia and ammonium compounds 7783-33-7 500ml $324 2022-05-15 Buy
Alfa Aesar 039307 Mercury(II) potassium iodide 7783-33-7 250g $1068 2023-06-20 Buy
GFS CHEMICALS 49952 MERCURICPOTASSIUMIODIDE 7783-33-7 20g $83.32 2021-12-16 Buy
Usbiological 241357 Potassium tetraiodomercurate 7783-33-7 25g $174 2021-12-16 Buy
GFS CHEMICALS 49951 MERCURICPOTASSIUMIODIDE 7783-33-7 100g $271.24 2021-12-16 Buy
Product number Packaging Price Buy
72190 500ml $324 Buy
039307 250g $1068 Buy
49952 20g $83.32 Buy
241357 25g $174 Buy
49951 100g $271.24 Buy

Nessler's Reagent Chemical Properties,Uses,Production

Chemical Properties

light yellow liquid

Uses

Mercury(II) potassium iodide is used as a pharmaceutical intermediate. It is also used as reagents, chemical research and organic intermediates.

Uses

Nessler's reagent (K2[HgI4]) is used to detect the presence of ammonia, particularly in very small amounts.

Preparation

It is prepared by mixing 2g potassium iodide in 5ml water. To this solution, 3g of mercury (II) iodide is added, and the resulting solution is made to 20ml. Finally, 40g potassium hydroxide (30 %) is added to provide the alkaline base.

Definition

Nessler's Reagent is a periodometallate salt that is solution of mercuric iodide in potassium iodide. It contains a tetraiodomercurate(2-).

General Description

Mercuric potassium iodide, [solid] appears as odorless yellow crystals. Crystallizes with either one, two or three molecules of water. Soluble in water and denser than water. Commercially available in the anhydrous form. Highly toxic by ingestion, inhalation, and skin absorption.

Air & Water Reactions

Deliquescent. Very water soluble.

Reactivity Profile

MERCURIC POTASSIUM IODIDE is incompatible with acetylene, ammonia, chlorine dioxide, azides, calcium (amalgam formation), sodium carbide, lithium, rubidium, copper . NESSLER'S REAGENT behave in aqueous solution as a weak acid.

Hazard

Highly toxic by ingestion, inhalation, and skin absorption.

Health Hazard

Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.

Safety Profile

A poison. Moderately toxic by skin contact and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of Hg, K2O, and I-. See also MERCURY.

Nessler's Reagent Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 144)Suppliers
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Henan Tianfu Chemical Co.,Ltd.
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Aladdin Scientific
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SHANGHAI KEAN TECHNOLOGY CO., LTD.
+8613817748580 cooperation@kean-chem.com China 40066 58

Nessler's Reagent Spectrum

NESSLER'S REAGENT SOLUTION AMMONIA NITROGEN 2 MAYER'S REAGENT MERCURY(II) POTASSIUM IODIDE MERCURIC POTASSIUM IODIDE MERCURIC-POTASSIUM IODIDE TS MERCURIC-POTASSIUM IODIDE TS, ALKALINE Mercury potassium iodide DIPOTASSIUM TETRAIODOMERCURATE(II) IN DILUTE SODIUM HYDROXIDE channing’ssolution dipotassium,(beta-4)-mercurate(2-tetraiodo- solutionpotassiumiodohydragyrate tetraiodo-,dipotassium,(T-4)-Mercurate(2-) tetraiodo-mercurate(2-dipotassium NESSLER'S REAGENT FOR DET. OF AMMONIA AN D AMMONIUM COMP. NESSLER'S REAGENT (King's ) MERCURIC POTASSIUM IODIDE REAGENT Mercurate(2-), tetraiodo-, dipotassium, (T-4)- potassium tetraiodomercurate - potassium hydroxide solution Kaliumtetrajodomercurat (II) Mercury(II) chloride - potassium iodide solution POTASSIUM TETRAIODOMERCURATE(II), 99.99% Mercuric potassium iodite Nessler’s reagent,Potassium tetraiodomercurate – Potassium hydroxide solution Nessler’s reagent,Dipotassium tetraiodomercurate(II) in dilute sodium hydroxide Dipotassium tetraiod Potassium tetraiodomercurate(II), (trace metal basis), 99.99% PotassiuM tetraiodoMercurate(II), 99.99%, (trace Metal basis) Mayers Reagent, USP Test Solution POTASSIUM TETRAIODOMERCURATE(II) POTASSIUM MERCURY IODIDE POTASSIUM MERCURIC IODIDE NESSLER'S SOLUTION NESSLER REAGENT, APHA NESSLER REAGENT, FOLIN-WU NESSLER REAGENT, FOLIN-WU, MODIFIED NESSLERS REAGENT NESSLER'S REAGENT NESSLER'S REAGENT A NESSLER'S REAGENT, DILUTE FOLIN-WU NITROGEN DETECTION NESSLER'S REAGENT (QUANTITATIVE) dipotassiumtetraiodomercurate dipotassiumtetraiodomercurate(2-) mercuricpotassiumiodide,[solid] mercuricpotassiumiodide,solid mercurypotassiumiodide(k2hgi4) nessler’s potassiumiodomercurate potassiummercuriiodide tetraiodomercury(2-) MERCURIC POTASSIUM IODIDE, REAGENTMERCURIC POTASSIUM IODIDE, REAGENTMERCURIC POTASSIUM IODIDE, REAGENTMERCURIC POTASSIUM IODIDE, REAGENT Alkaline mercuric iodide potassium solution NESSLER'S REAGENT ISO 9001:2015 REACH Nessler reagent[improved Potassium mercuric iodide, solution Nessler's (King) reagent Mercurate(2-),tetraiodo-, potassium (1:2), (T-4)- Nessler