ChemicalBook >> CAS DataBase List >>Chlorodimethylphenylsilane
Chlorodimethylphenylsilane
- CAS No.
- 768-33-2
- Chemical Name:
- Chlorodimethylphenylsilane
- Synonyms
- DMPSCl;PHENYLDIMETHYLCHLOROSILANE;DIMETHYLPHENYLSILYLCHLORIDE;DK394;DK900;DK437;CP0160;DMPSCI;DKFELEX0239;Phenylchlorodimethylsilane
- CBNumber:
- CB0480954
- Molecular Formula:
- C8H11ClSi
- Molecular Weight:
- 170.71
- MDL Number:
- MFCD00000499
- MOL File:
- 768-33-2.mol
- MSDS File:
- SDS
Last updated:2025-01-27 09:38:02
| Melting point | <0°C |
|---|---|
| Boiling point | 194-198 °C |
| Density | 1.017 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 143 °F |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Miscible with tetrahydrofuran, ether and hexane. |
| form | clear liquid |
| color | Colorless to Light yellow |
| Specific Gravity | 1.017 |
| Water Solubility | MAY DECOMPOSE |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| Sensitive | Moisture Sensitive |
| BRN | 606292 |
| InChIKey | KWYZNESIGBQHJK-UHFFFAOYSA-N |
| CAS DataBase Reference | 768-33-2(CAS DataBase Reference) |
| FDA UNII | D9XK5MV9A8 |
| NIST Chemistry Reference | Silane, chlorodimethylphenyl-(768-33-2) |
| EPA Substance Registry System | Silane, chlorodimethylphenyl- (768-33-2) |
| UNSPSC Code | 12352002 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34-37 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 2987 8/PG 2 | |||||||||
| WGK Germany | 1 | |||||||||
| F | 10-21 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
Chlorodimethylphenylsilane price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 113379 | Chloro(dimethyl)phenylsilane 98% | 768-33-2 | 5g | $61.1 | 2024-03-01 | Buy |
| Sigma-Aldrich | 113379 | Chloro(dimethyl)phenylsilane 98% | 768-33-2 | 25g | $197 | 2024-03-01 | Buy |
| TCI Chemical | D1147 | Chlorodimethylphenylsilane >96.0%(GC) | 768-33-2 | 5mL | $29 | 2024-03-01 | Buy |
| TCI Chemical | D1147 | Chlorodimethylphenylsilane >96.0%(GC) | 768-33-2 | 25mL | $73 | 2024-03-01 | Buy |
| Alfa Aesar | A15638 | Chlorodimethylphenylsilane, 97+% | 768-33-2 | 5g | $36.65 | 2024-03-01 | Buy |
Chlorodimethylphenylsilane Chemical Properties,Uses,Production
Chemical Properties
clear colorless to light yellow liquid
Uses
Chlorodimethylphenylsilane is used in the synthesis of enantioenriched allenylsilanes through an ortho-ester Claisen rearrangement of chiral and silylpropargylic alcohols.
Application
Chlorodimethylphenylsilane can be used for nucleophilic silylation; alcohol derivatization; antenna chromophores; enolate capture; and Kumada-FlemingTamao oxidation.
storage
Like other chlorosilanes, this compound can be destructive to tissue of the mucous membranes, upper respiratory tract, eyes and skin. Store in a cool dry place; the compound is moisture sensitive.
Purification Methods
Fractionate it through a 1.5 x 18inch column packed with stainless steel helices, or a spinning band column. [Daudt & Hyde J Am Chem Soc 74 386 1952, Lewis et al. J Am Chem Soc 70 1115 1948, Eaborn J Chem Soc 494 1953.] It is used for standardising MeLi or MeMgBr which form Me3PhSi which is estimated by GC. [Maienthal et al. J Am Chem Soc 76 6392 1954, House & Respess J Organomet Chem 4 95 1965, Beilstein 16 IV 1475.] TOXIC and MOISTURE SENSITIVE.
Chlorodimethylphenylsilane Preparation Products And Raw materials
Raw materials
1of4
Preparation Products
Global( 279)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Zhengzhou Lingzhiyue Technology Co., Ltd | +86-0371-55074660 +86-13783527580 | Lingzhiyue@aliyun.com | China | 3145 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8803 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29685 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 19875 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21632 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32965 | 60 |
| Zjartschem | +86-571 87238903 | jocelynpan@zjarts.com | CHINA | 988 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29869 | 58 |
| Zhengzhou Yuanli Biological Technology Co., Ltd | 0086-371-67897870 | sales02@zzyuanli.cn | CHINA | 149 | 58 |
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- Dec 27，2019
View Lastest Price from Chlorodimethylphenylsilane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-02-28 | Chlorodimethylphenylsilane
768-33-2
|
US $0.00 / Kg/Drum | 1Kg/Drum | 96%min | 200TON | Hebei Mujin Biotechnology Co.,Ltd | |
 |
2025-02-19 | Chlorodimethylphenylsilane
768-33-2
|
US $0.00-0.00 / KG | 1KG | 99% | 20 mt | Hebei Weibang Biotechnology Co., Ltd | |
 |
2022-10-01 | Chlorodimethylphenylsilane
768-33-2
|
US $0.00-0.00 / KG | 1KG | 98% | 1ton | Henan Aochuang Chemical Co.,Ltd. |
-
- Chlorodimethylphenylsilane
768-33-2
- US $0.00 / Kg/Drum
- 96%min
- Hebei Mujin Biotechnology Co.,Ltd
-
- Chlorodimethylphenylsilane
768-33-2
- US $0.00-0.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
-
- Chlorodimethylphenylsilane
768-33-2
- US $0.00-0.00 / KG
- 98%
- Henan Aochuang Chemical Co.,Ltd.
768-33-2(Chlorodimethylphenylsilane)Related Search:
DIMETHYLSILANE
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tert-Butyldimethylsilyl chloride
Diethoxydimethylsilane
PHENYLACETOXYTRIMETHYLSILANE
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Trimethoxyphenylsilane
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DIMETHYLTHEXYLSILYL CHLORIDE
PHENYLDICHLOROSILANE
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CHLORODIMETHYLPHENYLSILANE
DMPSCI
DIMETHYLPHENYL-CHLOROSILANE
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CP0160
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Phenylchlorodimethylsilane
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Benzene, (chlorodiMethylsilyl)-
Chlorodimethylphenylsilane >
Chlorodimethylphenylsilane, 97%, for synthesis
PHENYLDIMETHYLCHLOROSILANE
DIMETHYLPHENYLSILYLCHLORIDE
DMPSCl
DK394
DK900
DK437
DKFELEX0239
768-33-2
C8H11ClS1
C8H11ClSi
C6H5SiCH32Cl
C8H11SiCl
Si (Classes of Silicon Compounds)
Monochlorosilanes
Si-Cl Compounds
Silicon Compounds (for Synthesis)
Protecting and Derivatizing Reagents
Protection and Derivatization
Silicon-Based
Synthetic Reagents
Monochlorosilanes
Si (Classes of Silicon Compounds)
Si-Cl Compounds
Silicon Compounds (for Synthesis)
Synthetic Organic Chemistry