cyclopropanol
|
|
|
- CAS-Nr.
- 16545-68-9
- Englisch Name:
- cyclopropanol
- Synonyma:
- cyclopropyl alcohol;opropanoL;cyclopropanol;2-Cyclopropanol;Cyclopropane-1-ol;(1α)-Cyclopropanol;Hydroxycyclopropane;16545-68-9, CFCD16545689;Cyclopropanol (7CI, 8CI, 9CI, ACI);1H-Benzimidazole-1-carboxylicacid,2,3-dihydro-3-oxo-,ethylester
- CBNumber:
- CB91318019
- Summenformel:
- C3H6O
- Molgewicht:
- 58.08
- MOL-Datei:
- 16545-68-9.mol
|
cyclopropanol Eigenschaften
- Schmelzpunkt:
- 180℃
- Siedepunkt:
- 101-102℃ (760 Torr)
- Dichte
- 9.9110 g/cm3
- Brechungsindex
- 1.4129 (589.3 nm 20℃)
- storage temp.
- 2-8°C
- pka
- 15.31±0.20(Predicted)
- InChI
- InChI=1S/C3H6O/c4-3-1-2-3/h3-4H,1-2H2
- InChIKey
- YOXHCYXIAVIFCZ-UHFFFAOYSA-N
- SMILES
- C1(O)CC1
cyclopropanol Chemische Eigenschaften,Einsatz,Produktion Methoden
Beschreibung
Cyclopropanols can be readily synthesized via synthetic transformations such as the Kulinkovich cyclopropanation and the Simmons-Smith reaction [1]. Due to the high strains built intrinsically in the three-membered ring, cyclopropanols and their derivatives are highly reactive and can undergo various ring opening/expansion/fragmentation reactions. A significant amount of these ring opening/expansion/fragmentation reactions are catalyzed/promoted by transition metal complexes. In many of these cases, cyclopropanols and their derivatives are considered as the equivalents of homoenolates or β-alkyl radicals.
Verwenden
Cyclopropanol is a basic building block.
Einzelnachweise
[1] Xinpei Cai, Mingji Dai, Weida Liang. “Total syntheses via cyclopropanols.” Tetrahedron 75 2 (2019): Pages 193-208.
cyclopropanol Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
cyclopropanol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 119)Lieferanten
16545-68-9()Verwandte Suche:
- cyclopropanol
- (1α)-Cyclopropanol
- Cyclopropane-1-ol
- 2-Cyclopropanol
- Hydroxycyclopropane
- 16545-68-9, CFCD16545689
- opropanoL
- cyclopropyl alcohol
- 1H-Benzimidazole-1-carboxylicacid,2,3-dihydro-3-oxo-,ethylester
- Cyclopropanol (7CI, 8CI, 9CI, ACI)
- 16545-68-9
