(1S)-2,2-Dimethyl-3-methylenbicyclo[2.2.1]heptan
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- CAS-Nr.
- 5794-04-7
- Bezeichnung:
- (1S)-2,2-Dimethyl-3-methylenbicyclo[2.2.1]heptan
- Englisch Name:
- (-)-CAMPHENE
- Synonyma:
- (1S)-2,2-DIMETHYL-3-METHYLENEBICYCLO[2.2.1]HEPTANE;2,2-dimethyl-3-methylene-,(1S)-Bicyclo[2.2.1]heptane;Bicyclo2.2.1heptane, 2,2-dimethyl-3-methylene-, (1S,4R)-;[1S,4R,(-)]-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane;L-Camphene;(-)-Camphene;(-)-Camphene,95%;(+/-)-Camphene, sum of camphene + fenchene;(1S,4R)-2,2-Dimethyl-3-methylenenorbornane;2-dimethyl-3-methylene-(1s)-bicyclo[2.2.1]heptan
- CBNumber:
- CB8468970
- Summenformel:
- C10H16
- Molgewicht:
- 136.23
- MOL-Datei:
- 5794-04-7.mol
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(1S)-2,2-Dimethyl-3-methylenbicyclo[2.2.1]heptan Eigenschaften
- Schmelzpunkt:
- 36-38 °C(lit.)
- Siedepunkt:
- 157.5-158.5 °C(lit.)
- Dichte
- 0.84 g/mL at 25 °C(lit.)
- Brechungsindex
- 1.4562 (estimate)
- Flammpunkt:
- 98 °F
- L?slichkeit
- Benzene (Slightly), Chloroform (Sparingly)
- Aggregatzustand
- Solid
- Farbe
- White to Off-White Waxy
- Geruch (Odor)
- at 10.00 % in dipropylene glycol. fresh woody fir terpene
- Geruchsart
- woody
- Merck
- 14,1730
- Stabilit?t:
- Volatile
- LogP
- 4.239 (est)
- EPA chemische Informationen
- Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-, (1S,4R)- (5794-04-7)
(1S)-2,2-Dimethyl-3-methylenbicyclo[2.2.1]heptan Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R11:Leichtentzündlich.
R10:Entzündlich.
S-S?tze Betriebsanweisung:
S16:Von Zündquellen fernhalten - Nicht rauchen.
S33:Ma?nahmen gegen elektrostatische Aufladungen treffen.
S29:Nicht in die Kanalisation gelangen lassen.
Definition
ChEBI: A camphene (2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane) that has S configuration at position 1 and R configuration at position 4.
l?uterung methode
Purify norbornane by fractionation through a Stedman column (see p. 11) at 100mm in a N2 atmosphere, crystallise it from EtOH and sublime it in a vacuum below its melting point. It is characterised by its camphenilone semicarbazone, m 217-218.5o, or camphor semicarbazone, m 236-238o. [NMR: Hana & Koch Chem Ber 111 2527 1978, Bartlett et al. Justus Liebigs Ann Chem 623 217 1959, Bain et al. J Am Chem Soc 72 3124 1950, Beilstein 5 IV 461.]
(1S)-2,2-Dimethyl-3-methylenbicyclo[2.2.1]heptan Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(1S)-2,2-Dimethyl-3-methylenbicyclo[2.2.1]heptan Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 19)Lieferanten
5794-04-7((1S)-2,2-Dimethyl-3-methylenbicyclo[2.2.1]heptan)Verwandte Suche:
- 2-dimethyl-3-methylene-(1s)-bicyclo[2.2.1]heptan
- L-Camphene
- (1R,4S)-3,3-Dimethyl-2-methylenebicyclo[2.2.1]heptane
- (1S,4R)-2,2-Dimethyl-3-methylenenorbornane
- ()-Camphene,(1S)-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
- (+/-)-Camphene, sum of camphene + fenchene
- (-)-Camphene,95%
- (-)-Camphene
- [1S,4R,(-)]-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
- Bicyclo2.2.1heptane, 2,2-dimethyl-3-methylene-, (1S,4R)-
- (1S)-2,2-DIMETHYL-3-METHYLENEBICYCLO[2.2.1]HEPTANE
- 2,2-dimethyl-3-methylene-,(1S)-Bicyclo[2.2.1]heptane
- (-)-CaMphene, tech. 80% (suM of caMphene + fenchene)
- 5794-04-7
- Alkenes
- Asymmetric Synthesis
- Chiral Building Blocks
- Organic Building Blocks
