(1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol
|
|
- CAS-Nr.
- 27779-29-9
- Bezeichnung:
- (1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol
- Englisch Name:
- (+)-ISOPINOCAMPHEOL
- Synonyma:
- Nsc167499;3-PINANOL;(+)-ISOPINOCAMPHEOL;(+)-Isopinocampheol;ISOPINOCAMPHEOL, (+)-;3-Pinanol, stereoisomer;ISOPINOCAMPHEOL, (-)-(SG);(1S,2S,3S,5R)-(+)-IsopinocaMpheol 98%;(1s,2s,3s,5r)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol;(1S,3R,4R,5R)-4,6,6-trimethylbicyclo[3.1.1]heptan-3-ol
- CBNumber:
- CB8441753
- Summenformel:
- C10H18O
- Molgewicht:
- 154.25
- MOL-Datei:
- 27779-29-9.mol
|
(1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol Eigenschaften
- Schmelzpunkt:
- 52-55 °C
- Siedepunkt:
- 219 °C(lit.)
- Dichte
- 0.8389 (rough estimate)
- Brechungsindex
- 1.4710 (estimate)
- Flammpunkt:
- 93 °C
- pka
- 15.35±0.60(Predicted)
- Aggregatzustand
- solid
- Optische Aktivit?t
- [α]20/D +35.1°, c =20 in ethanol
- LogP
- 2.805 (est)
Sicherheit
(1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol Chemische Eigenschaften,Einsatz,Produktion Methoden
Verwenden
(1
S,2
S,3
S,5
R)-(+)-Isopinocampheol may be used in the preparation of
- thermotropic chiral nematic side-chain copolymers
- ortho-(diphenylphosphino)phenylphosphonous acid di[(1S,2S,3S,5R)-2,6,6-trimethyl-bicyclo[3.1.1]-hept-3-yl]ester, a phosphino-phosphonite ligand
- O,O′bis[(1S,2S,3S,5R)2,6,6-trimethylbicyclo[3.1.1]hept-3-yl] dithiophosphoric acid, a bioactive compound with antifungal effect
Allgemeine Beschreibung
(1
S,2
S,3
S,5
R)-(+)-Isopinocampheol is a chiral terpenol.
l?uterung methode
Dissolve it in Et2O, dry over MgSO4, filter, evaporate, then recrystallise it from pet ether. Also recrystallise it from aqueous EtOH and distil it in a vacuum. [Kergomard & Geneix Bull Soc Chim Fr 394 1958, Zweifel & Brown J Am Chem Soc 86 393 1964.] The 3,4-dinitrobenzoyl derivative has m 100-101o, the phenylcarbamoyl derivative has m 137-138o and the acid -phthalate has m 125-126o. [Beilstein 6 III 282, 283.]
(1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 34)Lieferanten
27779-29-9((1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol)Verwandte Suche:
(±)-(1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol
[1S-(1α,2β,3α,5α)]-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol
(-)-Pinan-3-ol
[1R-(1α,2β,3α,5α)]-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol
- ISOPINOCAMPHEOL, (+)-
- (1s,2s,3s,5r)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol
- ISOPINOCAMPHEOL, (-)-(SG)
- (1S,2S,3S,5R)-3-Pinanol, 3-Pinanol, (1S,2S,3S,5R)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol
- (1S,2S,3S,5R)-3-Pinanol, (1S,2S,3S,5R)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol
- Bicyclo[3.1.1]heptan-3-ol, 2,6,6-trimethyl-, (1.alpha.,2.beta.,3.alpha.,5.alpha.)-
- Nsc167499
- (1S,2S,3S,5R)-(+)-IsopinocaMpheol 98%
- 3-PINANOL
- 3-Pinanol, stereoisomer
- (+)-ISOPINOCAMPHEOL
- (1S,3R,4R,5R)-4,6,6-trimethylbicyclo[3.1.1]heptan-3-ol
- Bicyclo[3.1.1]heptan-3-ol, 2,6,6-trimethyl-, (1R,2R,3R,5S)-rel-
- (+)-Isopinocampheol
- 27779-29-9
- Alcohols
- Organic Building Blocks
- Asymmetric Synthesis
- Chiral Building Blocks