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N,N-Dimethyl-N'-(((methylamino)-carbonyl)-oxy)-phenylmethanimid-amid-hydrochlorid

FORMETANATE HYDROCHLORIDE Struktur
23422-53-9
CAS-Nr.
23422-53-9
Bezeichnung:
N,N-Dimethyl-N'-(((methylamino)-carbonyl)-oxy)-phenylmethanimid-amid-hydrochlorid
Englisch Name:
FORMETANATE HYDROCHLORIDE
Synonyma:
ep332;ep-332;CARZOL;sn36056;carzolsp;DICARZOL;ent-27566;Nsc379585;mortonep332;nor-amep332
CBNumber:
CB8372321
Summenformel:
C11H16ClN3O2
Molgewicht:
257.72
MOL-Datei:
23422-53-9.mol

N,N-Dimethyl-N'-(((methylamino)-carbonyl)-oxy)-phenylmethanimid-amid-hydrochlorid Eigenschaften

Schmelzpunkt:
201℃ (decomposition)
Dichte
1.3616 (rough estimate)
Dampfdruck
1.6 x 10-6 Pa (25 °C)
Brechungsindex
1.5270 (estimate)
storage temp. 
0-6°C
L?slichkeit
DMSO (Slightly), Methanol (Slightly), Water (Slightly)
pka
8.0 (base)
Wasserl?slichkeit
822,000 mg l-1 (25 °C)
Stabilit?t:
Hygroscopic
EPA chemische Informationen
Formetanate hydrochloride (23422-53-9)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher T+,N
R-S?tze: 26/28-43-50/53
S-S?tze: 24-28-37/39-45-60-61
RIDADR  2757
WGK Germany  3
RTECS-Nr. FC2514000
HazardClass  6.1(a)
PackingGroup  II
HS Code  29252900
Giftige Stoffe Daten 23422-53-9(Hazardous Substances Data)
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H317 Kann allergische Hautreaktionen verursachen. Sensibilisierung der Haut Kategorie 1A Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS09.jpg" width="20" height="20" /> P273, P391, P501
Sicherheit
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P302+P352 BEI BERüHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckm??ig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.

N,N-Dimethyl-N'-(((methylamino)-carbonyl)-oxy)-phenylmethanimid-amid-hydrochlorid Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R26/28:Sehr giftig beim Einatmen und Verschlucken.
R43:Sensibilisierung durch Hautkontakt m?glich.
R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.

S-S?tze Betriebsanweisung:

S24:Berührung mit der Haut vermeiden.
S28:Bei Berührung mit der Haut sofort abwaschen mit viel . . . (vom Hersteller anzugeben).
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.

Chemische Eigenschaften

Formetanate hydrochloride is a white or yellowish, crystalline solid or powder with a faint odor.

Verwenden

Formetanate is an insecticide and acaricide with contact and stomach action. It is used to control spider mites and some insects (Diptera, Hemiptera and Thysanoptera) on ornamentals, fruit, vegetables and alfalfa.

Allgemeine Beschreibung

White powder with a faint odor. Used as a plant insecticide, acaricide, and miticide.

Air & Water Reaktionen

Hydrolyzed at pH less than 4 [EPA, 1998].

Reaktivit?t anzeigen

FORMETANATE HYDROCHLORIDE is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

Health Hazard

Extremely toxic to humans. Not absorbed through contact with skin. Inhalation or ingestion may cause poisoning. Inhibits cholinesterase activity so effects are in relation to action on nervous system and can result in death.

Brandgefahr

FORMETANATE HYDROCHLORIDE may burn but does not ignite readily. Container may explode in heat of fire. Hydrolyzed at pH less than 4

Landwirtschaftliche Anwendung

Insecticide, Acaricide: Registered for use in the U.S. Not listed for use in EU countries. An insecticide used for thrips and true bug control on fruit crops.

Handelsname

CARZOL®; CARZOL® SP; DICARZOL®; ENT 27566®; EP-332®; MORTON® EP332; NOR-AM® EP 332; SCHERING® 36056; SN 36056®

Sicherheitsprofil

Poison by ingestion and intraperitoneal routes. Mddly toxic by skin contact. When heated to decomposition it emits very toxic fumes of NOx and HCl.

m?gliche Exposition

A potential danger to those involved in the manufacture, formulation, and application of this plant insecticide, acaricide and miticide.

Stoffwechselwegen

Formetanate is hydrolysed rapidly in field and laboratory soils under aerobic and anaerobic conditions. It is metabolised by similar pathways in plants and animals. It is hydrolytically deaminated to produce a formyl derivative and subsequently hydrolysed at the carbamate ester to give a phenolic product. The phenol is deformylated to 3-aminophenol and acetylated to 3-acetamidophenol. Formetanate and most phase 1 metabolites are found conjugated. Its metabolism has been reviewed by Cool and Jankowski (1985), Fukuto (1972) and Kuhr and Dorough (1976).

Versand/Shipping

UN2757 Carbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Inkompatibilit?ten

Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrideds and active metals. Contact with active metals or nitrides form flammable gas eous hydrogen. Incompatible with strongly oxidizing acids, peroxides, and hydroperoxides.

Waste disposal

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by follow ing package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥kg/mo) must conform with EPA regulations gov erning storage, transportation, treatment, and waste disposal.

N,N-Dimethyl-N'-(((methylamino)-carbonyl)-oxy)-phenylmethanimid-amid-hydrochlorid Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

23422-53-9(N,N-Dimethyl-N'-(((methylamino)-carbonyl)-oxy)-phenylmethanimid-amid-hydrochlorid)Verwandte Suche:


  • 3-dimethylaminomethyleneiminophenyl-n-methylcarbamate,hydrochloride
  • carbamicacid,methyl-,esterwithn’-(m-hydroxyphenyl)-n,n-dimethylformamidine,hydrochloride
  • carzolsp
  • ent-27566
  • ep332
  • ep-332
  • formetanatemonohydrochloride
  • m-(((dimethylamino)methylene)amino)phenylmethylcarbamatehydrochloride
  • m-[((dimethylamino)methylene)amino]phenylmethylcarbamatehydrochloride
  • mortonep332
  • n,n-dimethyl-n’-(((methylamino)carbonyl)oxy)phenylmethanimidamidemonohydroch
  • n,n-dimethyl-n’-(((methylamino)carbonyl)oxy)phenylmethanimidamidemonohydrochlo
  • n,n-dimethyl-n’-(3-(((methylamino)carbonyl)oxy)phenyl)-methanimidamidmon
  • n,n-dimethyl-n’-(3-(((methylamino)carbonyl)oxy)phenyl)-methanimidamidmonoh
  • n,n-dimethyl-n’-[3-[[(methylamino)carbonyl]oxy]phenyl]-methanimidamidmonoh
  • nor-amep332
  • schering36056
  • sn36056
  • Formetanate(content>40%)
  • FORMETANATE HYDROCHLORIDE
  • CARZOL
  • CARZOL SP(R)
  • DICARZOL
  • formetanate hydrochloride (bsi,iso,ansi,esa)
  • META((DIMETHYLAMINO)METHYLENE)AMINO-PHENYLMETHYLCARBAMATE
  • Formetanat-hydrochlorid
  • Methanimidamide,N,N-dimethyl-N’-[3-[[(methylamino)-carbonyl]oxyl]phenyl]-,monohydrochloride
  • FORMETANATE HYDROCHLORIDE STANDARD
  • formetanate hydrochloride 3-(N,N-dimethylaminomethyleneamino)phenyl N-methylcarbamate
  • 3-DIMETHYLAMINO METHYLENE AMINOPHENYL METHYLCARBAMATE HYDROCHLORIDE
  • ForMetanate hydrochlorid
  • (E)-3-(((diMethylaMino)Methylene)aMino)phenyl MethylcarbaMate hydrochloride
  • N,N-Dimethyl-N'-[3[[(methylamino)carbonyl]oxy]phenyl]methanimidamide monohydrochloride
  • Nsc379585
  • N,N-DIMETHYL-N'-[3-[[(METHYLAMINO)-CARBONYL]OXY]PHENYL]METHANIMIDAMIDE
  • N,N-DIMETHYL-N'-[3-[[(METHYLAMINO)-CARBONYL]OXY]PHENYL]METHANIMIDAMIDE HYDROCHLORIDE
  • FORMETANATE HYDROCHLORIDE PESTANAL, 250
  • FORMETANATE HYDROCHLORIDE, 1GM, NEAT
  • FormetanateHCl
  • Carzol 92SP
  • C13910000 FormetanatEhydrochloride
  • Formetanate hydrochloride in Cyclohexane:Acetone=1:1
  • Formetanate hydrochloride 10.0 μg/ml Acetonitrile
  • Formetanate hydrochloride in Acetonitrile
  • 23422-53-9
  • C11H15N3O2HCl
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