Trimethylentrinitramin Chemische Eigenschaften,Einsatz,Produktion Methoden
ERSCHEINUNGSBILD
WEISSES KRISTALLINES PULVER ODER FARBLOSE KRISTALLE
CHEMISCHE GEFAHREN
Bei Sto?, Reibung oder Erschütterung explosionsartige Zersetzung m?glich. Kann beim Erhitzen unter Bildung von Stickoxiden explodieren. Reagiert mit starken Oxidationsmitteln und brennbaren Stoffen
ARBEITSPLATZGRENZWERTE
TLV: 0.5 mg/m?als TWA Hautresorption Krebskategorie A4 (nicht klassifizierbar als krebserzeugend für den Menschen); (ACGIH 2006).
MAK nicht festgelegt.
AUFNAHMEWEGE
Aufnahme in den K?rper in gef?hrlichen Mengen durch Inhalation und durch Verschlucken.
INHALATIONSGEFAHREN
Eine gesundheitssch?dliche Partikelkonzentration in der Luft kann schnell erreicht werden.
WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION: M?glich sind Auswirkungen auf das Zentralnervensystem mit Reizbarkeit, Schlaflosigkeit, Kr?mpfen und Bewusstlosigkeit.
WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION
M?glich sind Auswirkungen auf das Zentralnervensystem. Wiederholter oder andauernder Hautkontakt kann Dermatitis hervorrufen.
LECKAGE
Gefahrenbereich verlassen! Fachmann zu Rate ziehen! Zündquellen entfernen. NICHT in die Umwelt gelangen lassen.
R-S?tze Betriebsanweisung:
R11:Leichtentzündlich.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S16:Von Zündquellen fernhalten - Nicht rauchen.
S27:Beschmutzte, getr?nkte Kleidung sofort ausziehen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
Chemische Eigenschaften
Hexahydro-1,3,5-trinitro-S-triazine is a
white crystalline compound.
Verwenden
Cyclonite is a high explosive and principal constituent of plastic bombs. It is preparedby treating hexamethylenetetramine with nitric acid,ammoniumnitrate,andaceticanhydride: It is also used as a rat poison.
Definition
ChEBI: An N-nitro compound that is 1,3,5-triazinane in which all three of the hydrogens attached to the nitrogens have been replaced by nitro groups. It is widely used in both industrial and military explosives.
Allgemeine Beschreibung
Cyclotrimethylene trinitramine is an explosive. The explosion can be initiated by a sudden shock, high temperature or a combination of the two. The primary hazard is from blast effect and not from flying projectiles and fragments. Under prolonged exposure to heat or fire they can explode.
Air & Water Reaktionen
Insoluble in water.
Reaktivit?t anzeigen
CYCLOTRIMETHYLENE TRINITRAMINE is incompatible with strong oxidizing agents, combustible materials and heat. Detonates on contact with mercury fulminate . Danger of explosion when dry. The self heating and explosive decomposition of the explosive and aqueous alkali (calcium hydroxide) has been studied, [Chem Abs., 1988, 109, 112968].
Health Hazard
Cyclonite is a highly toxic substance. Repeated exposure can cause nausea, vomiting, and convulsions.
LD50 value, oral (rats): 100 mg/kg.
Brandgefahr
MAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE REACHES CARGO.
Sicherheitsprofil
Poison by ingestion,
intraperitoneal, and intravenous routes. An
experimental teratogen. Other experimental
reproductive effects. A corrosive irritant to
skin, eyes, and mucous membranes. Cases of
epileptifonn convulsions have been reported
from exposure. It is one of the most
powerful high explosives in use today. Has
more shattering power than TNT and is
often mixed with TNT as a bursting charge
for aerial bombs, mines, and torpedoes. It is
easily initiated by mercury fulrmnate, which
may be used as a booster. When heated to
decomposition it emits toxic fumes of NOx.
See also MINES, NITRATES, and
EXPLOSIVES, HIGH.
m?gliche Exposition
A potential danger to those involved
in the manufacture of this material and its handling in
munitions and solid-propellant manufacture. It is also used
as a rat poison; a powerful military explosive; a base
charge for detonators; and in plastic explosives.
Versand/Shipping
UN0483 Cyclotrimethylenetrinitramine, desensi-
tized or Cyclonite, desensitized or Hexogen, desensitized or
RDX, desensitized, Hazard Class: 1D; Labels: 1D-
Explosive (with a mass explosion hazard); D-Substances or
articles which may mass detonate (with blast and/or frag-
ment hazard) when exposed to fire. UN0072
Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted
or Hexogen, wetted or RDX, wetted with not ,15% water
by mass, Hazard Class: 1D; Labels: 1D-Explosive (with a
mass explosion hazard); D-Substances or articles which
may mass detonate (with blast and/or fragment hazard)
when exposed to fire.
l?uterung methode
RDX crystallises from acetone. [Bachmann & Sheehan J Am Chem Soc 71 1842 1949, Beilstein 26 II 5, 26 III/IV 22.] EXPLOSIVE.
Inkompatibilit?ten
Heat, physical damage, shock, and deto-
nators. Detonates on contact with mercury fulminate. Keep
away from other explosives, combustibles, oxidizers (such
as chlorates, nitrates, perchlorates, permanganates, perox-
ides; bromine, chlorine, and fluorine); reducing agents; and
aqueous alkaline solutions.
Waste disposal
Pour over soda ash, neutralize
and flush to sewer with water. Also HMX may be recov-
ered from solid propellant waste.
Trimethylentrinitramin Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
