ALLYLDIPHENYLPHOSPHINE OXIDE
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- CAS-Nr.
- 4141-48-4
- Englisch Name:
- ALLYLDIPHENYLPHOSPHINE OXIDE
- Synonyma:
- NSC 98715;NSC 616249;NISTC4141484;Alydiphenylphosphine oxide;ALLYLDIPHENYLPHOSPHINE OXIDE;Diphenylallylphosphine oxide;Allyldiphenylphosphine oxide 97%;[allyl(phenyl)phosphoryl]benzene;Allyldiphenylphosphine Oxide >Diphenyl-2-propenylphosphine oxide
- CBNumber:
- CB6427654
- Summenformel:
- C15H15OP
- Molgewicht:
- 242.25
- MOL-Datei:
- 4141-48-4.mol
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ALLYLDIPHENYLPHOSPHINE OXIDE Eigenschaften
- Schmelzpunkt:
- 110-114 °C(lit.)
- Siedepunkt:
- 200-202 °C(Press: 2 Torr)
- Dichte
- 1.0769 g/cm3
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- L?slichkeit
- sol THF; slightly sol ether; insol hexane.
- Aggregatzustand
- solid
ALLYLDIPHENYLPHOSPHINE OXIDE Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Verwenden
Reactant for:
- Preparaton of a-substituted alkylsilanes via regio- and chemoselective copper-catalyzed silylzincation and electrophilic substitution from terminal alkenes, and prepn. of α-substituted alcohols via Fleming-Tamao oxidation of alkylsilanes
- Olefin isomerization with Grubbs′ catalysts occluded in a hydrophobic matrix of polydimethylsiloxane (PDMS)
- C9-substituted trans-hydrindene via diastereotopic group-selective intramolecular Diels-Alder reaction
- Isomerization of allyl group-containing compounds to propenyl group-containing compounds in the presence of a Grubbs second-generation Ru catalyst
- Ruthenium-catalyzed olefin cross-metathesis of vinyl and allyl phosphine oxides to give alkenyl phosphine oxides and bis-phosphine oxides
Synthese
The synthesis method of Allyldiphenylphosphine Oxide: (1) rearrangement of allyl diphenylphosphinite and (2) Arbuzov reaction of alkyl diphenylphosphinite with Allyl Bromide. Other new methods have also been developed. Structurally related analogs prepared include 2- methylallyldiphenylphosphine oxide, 2-phenylallyldiphenylphosphine oxide, 1- methoxyallyldiphenylphosphine oxide, crotyldiphenylphosphine oxide, and 1-substituted allylic diphenylphosphine oxide[1].
ALLYLDIPHENYLPHOSPHINE OXIDE Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
ALLYLDIPHENYLPHOSPHINE OXIDE Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 61)Lieferanten
4141-48-4()Verwandte Suche:
- ALLYLDIPHENYLPHOSPHINE OXIDE
- Alydiphenylphosphine oxide
- NISTC4141484
- Diphenylallylphosphine oxide
- [allyl(phenyl)phosphoryl]benzene
- [phenyl(prop-2-enyl)phosphoryl]benzene
- Diphenyl-2-propenylphosphine oxide
- NSC 616249
- NSC 98715
- Allyldiphenylphosphine oxide 97%
- Phosphine oxide,diphenyl-2-propen-1-yl-
- Allyldiphenylphosphine Oxide >
- 4141-48-4
- H2CCHCH2PC6H52O
- C15H15OP
- Catalysis and Inorganic Chemistry
- Phosphorus Compounds
- Phosphine Ligands
- Phosphorus Compounds
- Catalysis and Inorganic Chemistry
- Phosphine Ligands
