Titantrifluorid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R20/21/22:Gesundheitssch?dlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R34:Verursacht Ver?tzungen.
R32:Entwickelt bei Berührung mit S?ure sehr giftige Gase.
R14:Reagiert heftig mit Wasser.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
Chemische Eigenschaften
Red to brown crystalline powder
Blue rhombic crystals are stable in air and unusually resistant to acids and bases. Sublimation begins at about 930°C in a less than 0.1 mm vacuum. M.p. >1100°C; d%5 2.98. Insoluble in water and alcohol. Disproportionation to TiF4 and Ti begins at 950°C.
Verwenden
It is used as a laboratory chemicals & for manufacture of chemicals.
Vorbereitung Methode
Titanium metal is hydrogenated at 600-700°C. It is then placed in a small nickel boat and inserted into the horizontal nickel tube (closed at one end). The hydride is fluorinated with gaseous HF. The open end of the tube has a cooling jacket and is sealed with picein to a copper cover. Two copper tubes are silver-soldered into the cover and serve as an inlet and outlet for the hydrogen; the inlet tube also contains a concentric silver tube for introducing HF. The output gases pass through an empty polyethylene bottle, a bubble counter filled with paraffin oil and a polyethylene trap to freeze excess HF gas. The closed end of the reaction tube is placed in a tubular furnace. The temperature is measured externally. After thoroughly flushing the apparatus with Hs, fluorination followed with a 1 4 mixture of H2 and HF for four to five hours. The HF flow is first started at a temperature above 200°C. The water temperature in the cooling jacket should be higher than 20°C to prevent condensation of the HF. After completion of the fluorination, the product is left to cool in a stream of hydrogen. The yield is 90%.
Titantrifluorid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
