Benzoic acid, 4-[4-[(1-oxo-2-propenyl)oxy]butoxy]-, 2-Methyl-1,4-phenylene ester
|
|
|
- CAS-Nr.
- 132900-75-5
- Englisch Name:
- Benzoic acid, 4-[4-[(1-oxo-2-propenyl)oxy]butoxy]-, 2-Methyl-1,4-phenylene ester
- Synonyma:
- BYLC-2;2-Methyl-1,4-phenylene ester;1,4-Di[4-(4-acryloyloxybutoxy)benzoyloxy]-2-methylbenzene;Benzoic acid, 4-[4-[(1-oxo-2-propenyl)oxy]butoxy]-, 2-methyl...;2-methylbenzene-1,4-diyl bis{4-[4-(acryloyloxy)butoxy]benzoate};4-[4-[(1-Oxo-2-propenyl)oxy]butoxy]benzoic acid 2-methyl-1,4-phenylene ester;Benzoic acid, 4-[4-[(1-oxo-2-propenyl)oxy]butoxy]-, 2-Methyl-1,4-phenylene ester;Benzoicacid,4-[4-[(1-oxo-2-propen-1-yl)oxy]butoxy]-,1,1'-(2-methyl-1,4-phenylene)ester;Benzoic acid, 4-[4-[(1-oxo-2-propen-1-yl)oxy]butoxy]-, 1,1'-(2-methyl-1,4-phenylene) ester
- CBNumber:
- CB62570336
- Summenformel:
- C35H36O10
- Molgewicht:
- 616.65
- MOL-Datei:
- 132900-75-5.mol
|
Benzoic acid, 4-[4-[(1-oxo-2-propenyl)oxy]butoxy]-, 2-Methyl-1,4-phenylene ester Eigenschaften
- Siedepunkt:
- 748.5±60.0 °C(Predicted)
- Dichte
- 1.195±0.06 g/cm3(Predicted)
- Dampfdruck
- 0-0Pa at 20-50℃
- InChIKey
- NLGINBDFXRCWQW-UHFFFAOYSA-N
- SMILES
- C1(OC(=O)C2=CC=C(OCCCCOC(=O)C=C)C=C2)=CC=C(OC(=O)C2=CC=C(OCCCCOC(=O)C=C)C=C2)C=C1C
- LogP
- 5.1 at 25℃ and pH7
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Bildanzeige (GHS) |
|
| Alarmwort |
|
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H413 |
Kann für Wasserorganismen sch?dlich sein, mit langfristiger Wirkung. |
Langfristig (chronisch) gew?ssergef?hrdend |
Kategorie 4 |
|
|
|
|
| Sicherheit |
|
Benzoic acid, 4-[4-[(1-oxo-2-propenyl)oxy]butoxy]-, 2-Methyl-1,4-phenylene ester Chemische Eigenschaften,Einsatz,Produktion Methoden
synthetische
The preparation of Benzoic acid, 4-[4-[(1-oxo-2-propenyl)oxy]butoxy]-, 2-Methyl-1,4-phenylene ester is as follows:2-methylhydroquinone 3.0 g (24.2 mmol), 4-[3-(acryloyloxy)butoxy]benzoic acid 14.7 g (55.6 mmol), 4-dimethylaminopyridine (DMAP) 0.18 g (1.5 mmol) ) And 0.14 g (1.4 mmol) of 35% hydrochloric acid were added to 39 mL of tetrahydrofuran (THF) and stirred, and 7.0 g (55.6 mmol) of N,N-diisopropylcarbodiimide (DIC) was added dropwise to the solution. After completion of dropping, the mixture was stirred at 40° C. for 5 hours to obtain a reaction solution. The reaction solution was filtered to remove insoluble matter. A part of the solvent of the filtrate from which the insoluble matter was removed was distilled off to obtain 15 mL of a solution. 60 mL of methanol was added dropwise to 15 mL of the obtained solution to crystallize the polymerizable liquid crystal compound, and then the mixture was stirred under cooling. The obtained precipitate (crystal) is collected by filtration, and the collected precipitate (crystal) is dried to give 2-methyl-1,4-phenylene=bis{4-[3-(acryloyloxy)butoxy]. Benzoate} was obtained with a yield of 94% (14.0 g, 22.8 mmol). The purity of the obtained 2-methyl-1,4-phenylene=bis{4-[3-(acryloyloxy)butoxy]benzoate} was 97.8%. In addition, the content of N,N-diisopropylurea as a by-product contained in the finally obtained 2-methyl-1,4-phenylene bis{4-[3-(acryloyloxy)butoxy]benzoate} , 0.01% by mass relative to the yield, which was sufficiently reduced.
Benzoic acid, 4-[4-[(1-oxo-2-propenyl)oxy]butoxy]-, 2-Methyl-1,4-phenylene ester Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Benzoic acid, 4-[4-[(1-oxo-2-propenyl)oxy]butoxy]-, 2-Methyl-1,4-phenylene ester Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 39)Lieferanten
- Benzoic acid, 4-[4-[(1-oxo-2-propenyl)oxy]butoxy]-, 2-Methyl-1,4-phenylene ester
- 4-[4-[(1-Oxo-2-propenyl)oxy]butoxy]benzoic acid 2-methyl-1,4-phenylene ester
- Benzoic acid, 4-[4-[(1-oxo-2-propen-1-yl)oxy]butoxy]-, 1,1'-(2-methyl-1,4-phenylene) ester
- 2-Methyl-1,4-phenylene ester
- BYLC-2
- Benzoic acid, 4-[4-[(1-oxo-2-propenyl)oxy]butoxy]-, 2-methyl...
- 1,4-Di[4-(4-acryloyloxybutoxy)benzoyloxy]-2-methylbenzene
- Benzoicacid,4-[4-[(1-oxo-2-propen-1-yl)oxy]butoxy]-,1,1'-(2-methyl-1,4-phenylene)ester
- 2-methylbenzene-1,4-diyl bis{4-[4-(acryloyloxy)butoxy]benzoate}
- 132900-75-5
