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(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Struktur
138517-66-5
CAS-Nr.
138517-66-5
Englisch Name:
(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
Synonyma:
(S,S)-11,12-Diamino-9,10-dihydro-9,10-ethanoanthracene;(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE;(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine>9,10-Ethanoanthracene-11,12-diamine, 9,10-dihydro-, (11S,12S)-;(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >=95.0% (HPLC);(11S,12S)-11,12-diamino-9,10-dihydro-9,10-ethanoanthracene (R)-mandelate monoammonium salt
CBNumber:
CB5500732
Summenformel:
C16H16N2
Molgewicht:
236.31
MOL-Datei:
138517-66-5.mol

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Eigenschaften

Schmelzpunkt:
158 °C
Siedepunkt:
396.7±42.0 °C(Predicted)
Dichte
1.195±0.06 g/cm3(Predicted)
Brechungsindex
20 ° (C=1, MeOH)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
Aggregatzustand
powder to crystal
pka
9.38±0.40(Predicted)
Farbe
White to Orange to Green
BRN 
8693351
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xi
R-S?tze: 36/37/38
S-S?tze: 26
WGK Germany  3
HS Code  2921.51.5000
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Chemische Eigenschaften,Einsatz,Produktion Methoden

Verwenden

(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine is a chiral diamine, which can be used as a reactant:
  • To synthesize pyridine based C2-symmetrical chiral organocatalysts via palladium catalyzed coupling reaction with 2-bromo-4-(alkylamino)pyridine.
  • To prepare porous organic imine cages by cycloimination reaction with triformylbenzene.
  • To synthesize Ga/Yb-Schiff base complex, which is utilized as a catalyst for the asymmetric synthesis of 5-amino-2-(hydroxyalkyl)oxazoles by enantioselective α-addition of α-isocyano amides to aldehydes.

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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  • (11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
  • (S,S)-11,12-Diamino-9,10-dihydro-9,10-ethanoanthracene
  • (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >=95.0% (HPLC)
  • (11S,12S)-11,12-diamino-9,10-dihydro-9,10-ethanoanthracene (R)-mandelate monoammonium salt
  • (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine>
  • 9,10-Ethanoanthracene-11,12-diamine, 9,10-dihydro-, (11S,12S)-
  • 138517-66-5
  • Asymmetric Synthesis
  • Synthetic Organic Chemistry
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