(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
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- CAS-Nr.
- 35193-64-7
- Englisch Name:
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
- Synonyma:
- (R)-(-)-BNP ACID;(R)-(-)-BPA;(R)-(-)-BNPA;(11bS)-;(S)-(+)-BPA;(S)-(+)-BNPA;(S)-(+)-BNDHP.;(S)-(+)-BNP ACID;(S)-(+)-1,1'-Binapht;Galactose Impurity 11
- CBNumber:
- CB5107331
- Summenformel:
- C20H13O4P
- Molgewicht:
- 348.29
- MOL-Datei:
- 35193-64-7.mol
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(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Eigenschaften
- Schmelzpunkt:
- ≥300 °C
- alpha
- 607.5 º (c=1.4,MeOH)
- Siedepunkt:
- 619.5±38.0 °C(Predicted)
- Dichte
- 1.49±0.1 g/cm3(Predicted)
- Brechungsindex
- 595 ° (C=1, MeOH)
- storage temp.
- Sealed in dry,Room Temperature
- L?slichkeit
- Soluble in DMSO and methanol (hot).
- pka
- 1.14±0.20(Predicted)
- Aggregatzustand
- Powder
- Farbe
- white
- Optische Aktivit?t
- [α]22/D +595°, c = 1.35 in methanol
- BRN
- 4787775
- CAS Datenbank
- 35193-64-7(CAS DataBase Reference)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Bildanzeige (GHS) |
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Alarmwort |
Warnung |
Gefahrenhinweise |
Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P302+P352, P321,P332+P313, P362 |
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Sicherheit |
P302+P352 |
BEI BERüHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckm??ig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen. |
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(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R20/21/22:Gesundheitssch?dlich beim Einatmen,Verschlucken und Berührung mit der Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S22:Staub nicht einatmen.
Chemische Eigenschaften
white to light yellow crystal powde
Verwenden
The S enantiomer of binaphthol derivative as chiral quenching agent.
l?uterung methode
Recrystallise it from EtOH. Reflux for 3hours in N NaOH is required to hydrolyse the cyclic phosphate. [Jacques et al. Tetrahedron Lett 4617 1971, Arnold et al. Tetrahedron 24, 343 1983.]
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 296)Lieferanten
35193-64-7()Verwandte Suche:
SULPHOSUCCINIC ACID ESTER
(S)-(-)-1,1'-Bi-2-naphthol
Methyl-7-chlor-6,7,8-tridesoxy-6-(((1-methyl-4-propyl-2-pyrrolidi-nyl)carbonyl)amino)-1-thio-L-threo-alpha-D-galacto-octopyrano-sid-2-(dihydrogenphosphat),(2S-trans)-
1,1'-Binaphthyl-2,2'-diol
1,1'-Binaphthyl
4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-oxid
Water treatment agent POE
- (S)-(+)-BNP ACID
- (S)-(+)-BNPA
- (S)-(+)-BPA
- (S)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOPHEPIN-4-OXID
- (S)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE
- (S)-(+)-1,1'-BINAPHTHELENE-2,2'-DIYL-PHOSPHATE
- (S)-(+)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
- S-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
- (S)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE
- S(+)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE
- S(+)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE
- (S)-(+)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
- (S)-4-HYDROXYDINAPHTHO[2,1-D:1'',2''-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE: (S)-(+)-BNP ACID
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 98+%
- (11bS)-4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-Oxide
- (S)-(+)-1,1μ-Binaphthalene-2,2μ-diyl hydrogen phosphate, (S)-4-Hydroxydinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, min. 98%
- [aS,(+)]-2,2'-Phosphinicobisoxy-1,1'-binaphthalene
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate,99%
- (S)-(+)-1,1'-Binapht
- (S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate
- (11bS)-
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate
- (S)-(+)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ol 4-oxide, (S)-(+)-BNDHP
- (11bS)-4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate,(S)-(-)-BNDHP
- (R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL-PHOSPHATE
- (R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE
- R(-)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE
- (R)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE
- (R)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOSPHEPIN-4-OXID
- (R)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
- 2-HYDROXY-2LAMBDA5-DINAPHTHO[2,1-D:1,2-F][1,3,2]DIOXAPHOSPHEPIN-2-ONE
- (+/-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
- (S)-(+)-BNDHP.
- S-(+)BNP ACID / S-(-)-1,1''-BINAPHTHYL-2,2''-DIPHEMYL PHOSPHINE
- (S)-(+)-1,1-Binaphthyl-2,2'-dihydrogenphosphate
- (S)-(+)-1,1'-binaphthyl-2
- (S)-(+)-BINAPHTHYL-2,2'-DIYL HYDROGENPHO SPHATE
- S-(+)-1,1Binaphthalene-2,2Dihydrogen Phosphate
- (S)-(+)-1,1'-Binaphthyl-2,2'-diylhydrogenephosphate
- (S)-(+)-1,1'-BINAPHTHALENE-2,2'-DIYL-PHOSPHATE
- (S)-(+)-1,1'-Binaphthyl-2,2'-d
- (S)-(+)-1,1'-Binaphthyl-2,2'-diylhydrogenphosphate,min.98%
- Dinaphtho2,1-d:1,2-f1,3,2dioxaphosphepin, 4-hydroxy-, 4-oxide, (11bS)-
- S)-(+)-1,1'-Binaphthyl-2,2'-diyl
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 97%
- (S)-(+)-1,1'-Biphthyl-2,2'-diyl hydrogenphosphate
- (S)-1,1'-Binaphthalene-2,2'-diyl Hydrogen Phosphate,99%e.e.
- (S)-(+)-1,1'-Binaphthalene-2,2'-diyl-phosphate for synthesis
- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-, 4-oxide, (S)-
- (11bS)-4-Hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
- (S)-(+)-1,1'-BINAPHTHE
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate >
- (R)-(-)-BPA
- (R)-(-)-BNPA
- (R)-(-)-BNP ACID
- (+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate