1,2-Dichlorethen Chemische Eigenschaften,Einsatz,Produktion Methoden
ERSCHEINUNGSBILD
FARBLOSE FLüSSIGKEIT MIT CHARAKTERISTISCHEM GERUCH.
PHYSIKALISCHE GEFAHREN
Die D?mpfe sind schwerer als Luft und k?nnen sich am Boden ausbreiten. Fernzündung m?glich.
CHEMISCHE GEFAHREN
Zersetzung beim Erhitzen oder unter Einfluss von Luft, Lichtund Feuchtigkeit unter Bildung giftiger und ?tzender Rauche mit Chlorwasserstoff. Reagiert mit starken Oxidationsmitteln. Reagiert mit Kupfer / Kupferlegierungenund Basen unter Bildung vongiftigem Chloracetylen, das sich bei Kontakt mit Luft spontan entzündet. Greift Kunststoff an.
ARBEITSPLATZGRENZWERTE
TLV: 200 ppm (als TWA); (ACGIH 2005).
MAK: 200 ppm, 800 mg/m? Spitzenbegrenzung: überschreitungsfaktor II(2); (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den K?rper durch Inhalation der D?mpfe und durch Verschlucken.
INHALATIONSGEFAHREN
Beim Verdampfen bei 20°C tritt schnell eine gesundheitssch?dliche Kontamination der Luft ein; viel schneller jedoch beim Versprühen oder Dispergieren.
WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION: Die Substanz reizt die Augen und die Atemwege. M?glich sind Auswirkungen auf das Zentralnervensystem in hohen Konzentrationen mit nachfolgender Bewusstseinstrübung.
WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION
Die Flüssigkeit entfettet die Haut. M?glich sind Auswirkungen auf die Leber.
LECKAGE
Zündquellen entfernen. Belüftung. Ausgelaufene Flüssigkeit m?glichst in abdichtbaren Beh?ltern sammeln. Reste mit trockenem Sand oder inertem Absorptionsmittel aufnehmen und an einen sicheren Ort bringen. NICHT in die Kanalisation spülen. Pers?nliche Schutzausrüstung: Vollschutzanzug mit umgebungsluftunabh?ngigem Atemschutzger?t.
R-S?tze Betriebsanweisung:
R11:Leichtentzündlich.
R20:Gesundheitssch?dlich beim Einatmen.
R52/53:Sch?dlich für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
S-S?tze Betriebsanweisung:
S7:Beh?lter dicht geschlossen halten.
S16:Von Zündquellen fernhalten - Nicht rauchen.
S29:Nicht in die Kanalisation gelangen lassen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Beschreibung
Acetylene dichloride is a colourless liquid (usually a mixture of the cis and trans isomers)
with a slightly acrid, chloroform-like odour. Acetylene dichloride is a chemical used
mainly in the production of perfumes, dyes, and thermoplastics. The type and severity
of symptoms varies depending on the amount of chemical involved and the nature of
the exposure. It is incompatible with strong oxidisers, strong alkalis, potassium hydroxide,
and copper. Acetylene dichloride is highly flammable and in a fire gives off irritating
or toxic fumes/gases. (Acetylene dichloride usually contains inhibitors to prevent
polymerisation.)
Chemische Eigenschaften
1,2-Dichloroethylene exists in three isomers,
sym-, cis-60% and trans-40%. There are variations in toxicity between these two forms. At room temperature, these
chemicals are colorless liquids with a slightly acrid, ethereal odor. The Odor Threshold in air is 17 ppm.
sym-isomer:
Verwenden
1,2-Dichloroethylene is used as a
solvent for organic materials and as an intermediate
in the synthesis of other chlorinated
compounds; it may be produced by the chlorination
of acetylene but is often produced as a
by-product in the manufacture of other chlorinated
compounds.
Allgemeine Beschreibung
A clear colorless liquid with ether-like odor. Mixture of cis and trans isomers. Flashpoint 36 - 43° F. Denser than water and insoluble in water. Vapors heavier than air.
Air & Water Reaktionen
Highly flammable. 1,2-DICHLOROETHYLENE is sensitive to air, light and moisture. Heat contributes to instability. Insoluble in water.
Reaktivit?t anzeigen
1,2-DICHLOROETHYLENE reacts violently with sodium, sodium hydroxide, copper and copper alloys. 1,2-DICHLOROETHYLENE can react with caustic alkynes or their concentrated solutions. 1,2-DICHLOROETHYLENE forms explosive mixtures with N2O4. 1,2-DICHLOROETHYLENE is incompatible with strong oxidizers. 1,2-DICHLOROETHYLENE is corrosive to metals. 1,2-DICHLOROETHYLENE attacks some forms of plastics, rubber and coatings.
Health Hazard
Inhalation causes nausea, vomiting, weakness, tremor, epigastric cramps, central nervous depression. Contact with liquid causes irritation of eyes and (on prolonged contact) skin. Ingestion causes slight depression to deep narcosis.
Chemische Reaktivit?t
Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Will not occur under ordinary conditions of shipment. The reaction is not vigorous; Inhibitor of Polymerization: None used.
Sicherheitsprofil
Poison by inhalation.
Moderately toxic by ingestion. A skin
irritant. When heated to decomposition it
emits highly toxic fumes of Cl-. See also
ACETYLENE COMPOUNDS, and
CHLORINATED HYDROCARBONS,
ALIPHATIC .
m?gliche Exposition
Primary irritant (w/o allergic reaction).
1,2-Dichloroethylene is used as a solvent for waxes, resins,
and acetylcellulose. It is also used in the extraction of rubber, as a refrigerant; in the manufacture of pharmaceuticals
and artificial pearls; and in the extraction of oils and fats
from fish and meat.
Carcinogenicity
In genotoxic assays the cis isomer induced
chromosomal aberrations in mouse bone
marrow cells after intraperitoneal injections.7
Neither isomer was mutagenic in bacterial
assays, nor did they produce chromosomal
aberrations or sister chromatid exchanges in
mammalian cells in vitro.
The 2003 ACGIH threshold limit valuetime-
weighted average (TLV-TWA) for 1,2-
dichloroethylene is 200ppm (793mg/m3).
Versand/Shipping
UN1150 Dichloroethylene, Hazard Class: 3;
Labels: 3-Flammable liquid.
l?uterung methode
Shake it successively with conc H2SO4, water, aqueous NaHCO3 and water. Dry it with MgSO4 and fractionally distil it to separate the cis-and trans-isomers. [Beilstein 1 IV 707-709.]
Inkompatibilit?ten
May form explosive mixture with air.
Attacks some plastics, rubber, and coatings. Incompatible
with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.);
contact may cause fires or explosions. Keep away from
alkaline materials, strong bases, strong acids, oxoacids, and
epoxides. Gradual decomposition results in hydrochloric
acid formation in the presence of ultraviolet light or upon
contact with hot metal or other hot surfaces. Reacts with
strong bases; potassium hydroxide; difluoromethylene,
dihypofluoride, nitrogen tetroxide (explosive); or copper
(and its alloys) producing toxic chloroacetylene which is
spontaneously flammable on contact with air. Attacks some
plastics and coatings.
Waste disposal
Incineration, preferably after
mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove
the halo acids produced. Consult with environmental
regulatory agencies for guidance on acceptable disposal
practices. Generators of waste containing this contaminant
(≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.
1,2-Dichlorethen Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
