Bis(pentan-2,4-dionato-O,O')mangan
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- CAS-Nr.
- 14024-58-9
- Bezeichnung:
- Bis(pentan-2,4-dionato-O,O')mangan
- Englisch Name:
- MANGANESE(II) ACETYLACETONATE
- Synonyma:
- NSC 4656;Mn(acac)2;NSC 52334;NSC 177707;Manganesepentanedionate;MANGANOUS ACETYLACETONATE;MANGANESE ACETYLACETONATE;acetylacetonemanganese(ii);bis(acetylacetone)manganese;manganese(2+)acetylacetonate
- CBNumber:
- CB3422931
- Summenformel:
- C10H14MnO4
- Molgewicht:
- 253.15
- MOL-Datei:
- 14024-58-9.mol
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Bis(pentan-2,4-dionato-O,O')mangan Eigenschaften
- Schmelzpunkt:
- 248-250 °C (dec.)(lit.)
- Siedepunkt:
- 130.3°C
- Dichte
- 1,6 g/cm3
- storage temp.
- Store below +30°C.
- L?slichkeit
- 11.5g/l
- Aggregatzustand
- Powder
- Farbe
- tan
- Wichte
- 1.60
- Wasserl?slichkeit
- Soluble in water
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- Sensitive
- Hygroscopic
- BRN
- 4157965
- Expositionsgrenzwerte
- OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
- Stabilit?t:
- hygroscopic
- EPA chemische Informationen
- Manganese, bis(2,4-pentanedionato-.kappa.O,.kappa.O')- (14024-58-9)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher |
Xn |
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R-S?tze: |
20/21/22-36/37/38-40 |
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S-S?tze: |
26-36 |
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WGK Germany |
3 |
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RTECS-Nr. |
OO9350000 |
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TSCA |
Yes |
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HS Code |
2914 19 90 |
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Bildanzeige (GHS) |
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Alarmwort |
Warnung |
Gefahrenhinweise |
Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P302+P352, P321,P332+P313, P362 |
H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P305+P351+P338,P337+P313P |
H335 |
Kann die Atemwege reizen. |
Spezifische Zielorgan-Toxizit?t (einmalige Exposition) |
Kategorie 3 (Atemwegsreizung) |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
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H351 |
Kann vermutlich Krebs verursachen. |
Karzinogenit?t |
Kategorie 2 |
Warnung |
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P201, P202, P281, P308+P313, P405,P501 |
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Sicherheit |
P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
P301+P312 |
BEI VERSCHLUCKEN: Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen. |
P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen. |
P308+P313 |
BEI Exposition oder falls betroffen: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen. |
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Bis(pentan-2,4-dionato-O,O')mangan Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R20/21/22:Gesundheitssch?dlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R40:Verdacht auf krebserzeugende Wirkung.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
Beige solid
Allgemeine Beschreibung
Manganese(II) acetylacetonate (Mn(acac)
2) is a transition metal acetylacetonate that is trimeric in hydrocarbon solvents. It is monomeric and tetrahedral in its vapor state. It shows Mn-O bond energy of 65 kcal mol
-1. It can be used with potassium permanganate in preparation of manganese triad (Mn(acac)
3).
Sicherheitsprofil
Questionable
carcinogen with experimental neoplastigenic
and tumorigenic data. When heated to
decomposition it emits acrid smoke and
irritating fumes. See also iMANGANESE
COMPOUNDS.
l?uterung methode
Purify it by stirring 16g of reagent for a few minutes with 100mL absolute EtOH and filter by suction as rapidly as possible through coarse filter paper. Sufficient EtOH is added to the filtrate, to make up for the loss of EtOH and to redissolve any solid that separates. Water (15mL) is added to the filtrate, and the solution is evaporated with a stream of N2 until reduced to half its volume. Cool for a few minutes and filter off the yellow crystals, dry them under a stream of N2, then in a vacuum at room temperature for 6-8hours. These conditions are important for obtaining the dihydrate. A vacuum to several mm of Hg or much lower pressure for several days produces the anhydrous complex. The degree of hydration can be established by determining the loss in weight of 100g of sample after heating for 4hours at 100o and <20mmHg. The theoretical loss in weight for 2H2O is 12.5%. The material sublimes at 200o/2mm. It is soluble in heptane, MeOH, EtOH or *C6H6 at 30o. [Charles Inorg Synth VI 164 1960, Fernelius & Biswas Inorg Synth V 105 1957, Beilstein 3 II 3122.]
Bis(pentan-2,4-dionato-O,O')mangan Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Bis(pentan-2,4-dionato-O,O')mangan Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 148)Lieferanten
14024-58-9(Bis(pentan-2,4-dionato-O,O')mangan)Verwandte Suche:
Tris(pentan-2,4-dionato-O,O')neodym
Kupfer(II)-4-oxopent-2-en-2-olat
Chrom(III)-4-oxopent-2-en-2-olat
Ethyl-2,4-dioxovalerat
Bis(pentan-2,4-dionato-O,O')nickel
Oxobis(pentan-2,4-dionato-O,O')vanadium
Tris(pentan-2,4-dionato-O,O')gallium
Bis(pentan-2,4-dionato-O,O')eisen
Tris(pentan-2,4-dionato-O,O')indium
Pentan-2,4-dion, MonoLithiumsalz
Tris(pentan-2,4-dionato-O,O')vanadium
Tris(pentan-2,4-dionato-O,O')yttrium
Oxobis(pentan-2,4-dionato-O,O')titan
Mangantris(4-oxopent-2-en-2-oat)
Methylacetopyruvat
Dioxobis(pentan-2,4-dionato-O,O')molybdaen
Tris(pentan-2,4-dionato-O,O')cobalt
Zinkacetylacetonat
- 2,4-PENTANEDIONE, MANGANESE(II) DERIVATIVE
- ACETYLACETONE, MANGANESE(II) DERIVATIVE
- ACETYLACETONE MANGANESE(II) SALT
- acetylacetonemanganese(ii)
- bis(2,4-pentanedionato)-manganes
- BIS(ACETYLACETONATO)MANGANESE(II)
- BIS(2,4-PENTANEDIONATO)MANGANESE(2)
- BIS(2,4-PENTANEDIONATO)MANGANESE(II)
- MANGANOUS ACETYLACETONATE
- MANGANESE(II) 2,4-PENTANEDIONATE
- MANGANESE II 2,4-PENTANEDIONATE TRIMERIC
- MANGANESE(II) ACETYLACETONATE
- MANGANESE ACETYLACETONATE
- Manganese(II)acetylacetonate,95%
- Manganese, bis(2,4-pentanedionato-.kappa.O,.kappa.O)-
- 2,4-Pentanedione manganese(II) derivative, Manganous acetylacetonate, Mn(acac)2
- Bis(2,4-pentanedionato)manganese(II) Dihydrate
- Manganese(Ⅱ) 2,4-Pentanedionate
- Mn(acac)2
- manganesebis(2,4-pentanedionate)
- manganesebis(acetylacetonate)
- Manganese(II)2,4-pentanedionate 95%
- Manganesepentanedionate
- bis(pentane-2,4-dionato-O,O')manganese
- Manganese(II) acetylacetonate hydrate
- Bis(2,4-pentanedionato)manganese
- bis(2,4-pentanedionato-o,o’)-manganes
- bis(acetylacetone)manganese
- Manganese bis(2,4-pentanedionate)
- Manganese bis(acetylacetonate)
- Manganese(2+) acetylacetonate
- manganese(2+)acetylacetonate
- Manganese(II) bis(acetylacetonate)
- manganese(ii)2,4-pentanedionate95%
- manganese(ii)bis(acetylacetonate)
- Manganese, bis(2,4-pentanedionato)-
- Manganese, bis(2,4-pentanedionato-O,O')-
- Acetylacetone Manganese(II) Salt
Manganese(II) Acetylacetonate
- Bis(2,4-pentanedionato)Manganese(II) 
- MANGANESE(II) ACETYLACETONATE FOR SYNTHE
- NSC 177707
- NSC 4656
- NSC 52334
- Manganese(II) Acetyllacetonate
- Manganese(Ⅱ) acetylacetonate
- MANGANESE (II) ACETYLACETONATEMANGANESE (II) ACETYLACETONATEMANGANESE (II) ACETYLACETONATE
- MANGANESE(II) 2,4-PENTANEDIONATE, tech-95
- Bis(2,4-pentanedionato)manganese(II)Dihydrate>
- Manganese(II) Acetylacetonate,>98%
- MANGANESE(II) ACETYLACETONATE ISO 9001:2015 REACH
- Bis(2,4-pentanedionato)manganese Dihydrate
- 2,4-Pentanedione-manganese (2:1)
- 14024-58-9
- CH3COCHCOCH32Mn
- C10H14MnO42H2O
- C10H14O4Mn
- MnCH3COCHCOCH32
- C10H14MnO4