2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin
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- CAS-Nr.
- 479-59-4
- Bezeichnung:
- 2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin
- Englisch Name:
- Julolidine
- Synonyma:
- JULOLIDINE;Julolidine>Julolidine,98%;Julolidine, 98% 25GR;Julolidine USP/EP/BP;Julolidine>97.0%(GC&T);5h-benzo[ij]quinolizine,2,3,6,7-tetrahydro-1;2,3,6,7-TETRAHYDRO-1H,5H-BENZO[IJ]QUINOLIZINE;1,2,3,5,6,7-Hexahydropyrido[3,2,1-ij]quinoline;2,3,6,7-Tetrahydro-1H,5H-benzop[ij]quinolizine
- CBNumber:
- CB3167092
- Summenformel:
- C12H15N
- Molgewicht:
- 173.25
- MOL-Datei:
- 479-59-4.mol
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2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin Eigenschaften
- Schmelzpunkt:
- 34-36 °C(lit.)
- Siedepunkt:
- 170-173°C 31mm
- Dichte
- 1.0030
- Brechungsindex
- 1.5680
- Flammpunkt:
- >230 °F
- storage temp.
- 2-8°C
- L?slichkeit
- Chloroform (Slightly), Ethyl Acetate (Slightly)
- pka
- 6.54±0.20(Predicted)
- Aggregatzustand
- Liquid After Melting
- Farbe
- Clear yellow to orange-brown
- Wasserl?slichkeit
- Soluble in toluene. Insoluble in water.
- Sensitive
- Air Sensitive
- BRN
- 139925
- InChIKey
- DZFWNZJKBJOGFQ-UHFFFAOYSA-N
- CAS Datenbank
- 479-59-4(CAS DataBase Reference)
- NIST chemische Informationen
- Julolidine(479-59-4)
- EPA chemische Informationen
- 1H,5H-Benzo[ij]quinolizine, 2,3,6,7-tetrahydro- (479-59-4)
2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin Chemische Eigenschaften,Einsatz,Produktion Methoden
S-S?tze Betriebsanweisung:
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
CLEAR YELLOW TO ORANGE-BROWN LIQUID AFTER MELTING
Verwenden
Julolidine used as amine building block and in chemoluminescent dye. Also used in photoconductive materials, chemiluminescence substances, chromogenic substrates in analytical redox reactions, dye intermediates, potential antidepressants and tranquilizers, nonlinear optical materials, high sensitivity photopolymerizable materials, and for improving color stability in photography.
l?uterung methode
Purify julolidine by dissolving it in dilute HCl, steam is bubbled through the solution and the residual acidic solution is basified with 10N NaOH, extracted with Et2O, washed with H2O, dried (NaOH pellets), filtered, evaporated and distilled in vacuo. The distillate crystallises on cooling (m 39-40o). It develops a red colour on standing in contact with air for several days. The colour can be removed by distilling or dissolving in 2-3 parts of hexane, adding charcoal, filtering and cooling in an Me2CO/Dry-ice bath when julolidine crystallises out (85-90% yield m 39-40o). The hydrobromide [83646-41-7] has m 218o (239-242o), the picrate has m 174o(165o) and the methiodide crystallises from MeOH, with m 186o [Glass & Weisberger Org Synth Coll Vol III 504 1955, Smith & Yu J Org Chem 17 1285 1952, Beilstein 20 H 332, 20 I 133, 20 II 214, 20 III/IV 3281.] Highly TOXIC.
2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Tetrahydroquinoline
1-Brom-3-chlorpropan
1H,5H-Benzo[ij]quinolizine, 2,3,6,7-tetrahydro-9-methoxy-
N-(3-Hydroxypropyl)aniline
2,3,6,7-Tetrahydro-1H,5H-benzo[ij]chinolizin-8-ol
Anilin
Propan-1,3-diol
p-Toluidin
Downstream Produkte
2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 149)Lieferanten
479-59-4(2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin)Verwandte Suche:
2-Benzothienylboronic acid
Mechitazin
Hydrochlorothiazid
2,3,6,7-Tetrahydro-9-methyl-1H,5H,11H-[1]benzopyrano[6,7,8-ij]chinolizin-11-on
2,3,6,7-Tetrahydro-11-oxo-1H,5H,11H-[1]benzopyrano[6,7,8-ij]chinolizin-10-carbonsure
10-Acetyl-2,3,6,7-tetrahydro-1H,5H,11H-[1]benzopyrano[6,7,8-ij]chinolizin-11-on
Hydrogen-9-(2,4-disulfonatophenyl)-2,3,6,7,12,13,16,17-octahydro-1H,5H,11H,15H-xantheno[2,3,4-ij:5,6,7-i'j']dichinolizin-18-ium
2,3,6,7-Tetrahydro-11-oxo-1H,5H,11H-[1]benzopyrano[6,7,8-ij]chinolizin-10-carbonitril
2,3,6,7-Tetrahydro-1H,5H-benzo[ij]chinolizin-8-ol
Ethyl-2,3,6,7-tetrahydro-11-oxo-1H,5H,11H-[1]benzopyrano[6,7,8-ij]chinolizin-10-carboxylat
2,3,6,7,10,11-Hexahydro-1H,5H-cyclopenta[3,4][1]benzopyrano[6,7,8-ij]chinolizin-12(9H)-on
tert-Butyl-2,3,6,7-tetrahydro-11-oxo-7H,5H,11H-[1]benzopyrano[6,7,8-ij]chinolizin-10-carboxylat
2,3,6,7-Tetrahydro-9-(trifluormethyl)-1H,5H,11H-[1]benzopyrano[6,7,8-ij]chinolizin-11-on
2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizin
- JULOLIDINE
- 2,3,6,7-TETRAHYDRO-1H,5H-BENZO[IJ]QUINOLIZINE
- 2,3,6,7-TETRAHYDRO-1H,5H-PYRIDO[3.2.1-IJ]QUINOLINE
- 1H,5H-BENZO[IJ]QUINOLIZINE, 2,3,6,7-TETRAHYDRO-
- 5h-benzo[ij]quinolizine,2,3,6,7-tetrahydro-1
- Julolidine,98%
- 2,3,6,7-Tetrahydro-1H,5H-benzop[ij]quinolizine
- Julolidine, 98% 25GR
- 1,2,3,5,6,7-Hexahydropyrido[3,2,1-ij]quinoline
- Julolidine>
- Julolidine>97.0%(GC&T)
- Julolidine USP/EP/BP
- 479-59-4
- Miscellaneous Natural Products
