(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
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- CAS-Nr.
- 560-09-8
- Englisch Name:
- (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
- Synonyma:
- Acid, L-caMphor;(-)-CAMPHORIC ACID;(-)-Camphoric acid;(+)-Camphoric Acid;L-(-)-CAMPHORIC ACID;(1S,3R)-CAMPHORIC ACID;(1S,3R)-(-)-CAMPHORIC ACID;(1S,3R)-(-)-CaMphoric acid 99%;(-)-CAMPHORIC ACID, UNNATURAL FORM;L-Camphoric acid|||Camphoric acid, (-)-
- CBNumber:
- CB2738895
- Summenformel:
- C10H16O4
- Molgewicht:
- 200.23
- MOL-Datei:
- 560-09-8.mol
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(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Eigenschaften
- Schmelzpunkt:
- 188-190 °C(lit.)
- Siedepunkt:
- 312.0±25.0 °C(Predicted)
- Dichte
- 1.177±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- L?slichkeit
- DMSO, Ethanol, Methanol
- Aggregatzustand
- Solid
- pka
- 4.57±0.60(Predicted)
- Farbe
- White to Off-White
- Optische Aktivit?t
- [α]20/D 48°, c = 10 in ethanol
- BRN
- 1874674
- CAS Datenbank
- 560-09-8(CAS DataBase Reference)
(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Chemische Eigenschaften,Einsatz,Produktion Methoden
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
White Solid
Verwenden
(1
S,3
R)-(?)-Camphoric acid can be used:
- As an enantiomeric linker in the preparation of chiral surface-anchored metal-organic frameworks (MOFs).
- To prepare porous MOFs having multifunctional properties; used in gas adsorption and separation of racemic alcohols.
- To prepare a cobalt(II) coordination polymer named {Co(phen)(H2O)[C8H14(COO)2]}n·(CH3OH)n , wherein “phen” is 1,10-phenanthroline and C8H14(COOH)2 is [(1S,3R)-camphoric acid.
l?uterung methode
Purify the acid by re-precipitation from an alkaline solution by HCl, filter it off, and recrystallise it from water several times, rejecting the first crop. It forms leaflets from EtOH and Me2CO and H2O and is insoluble in CHCl3. Its solubility in H2O is 0.8% at 25o and 10% at 100o, 50% in EtOH and 5% in ethylene glycol. The (±)-acid has m 202-203o. The (+)-1-methyl ester has m 86o (from pet ether) [] 20 +45o (c 4, EtOH), and the (+)-3-methyl ester has m 77o (from pet ether) []17.5 +53.9o (c 3, EtOH). [Rupe & Thommen Helv Chim Acta 30 933
(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 125)Lieferanten
560-09-8()Verwandte Suche:
Tris[1,7,7-trimethyl-3-(trifluoroacetyl)bicyclo[2.2.1]heptan-2-onato-O,O']ytterbium
cis-(±)-Camphorsure
Tris[1,7,7-trimethyl-3-(trifluoroacetyl)bicyclo[2.2.1]heptan-2-onato-O,O']praseodym
Tris[3-(2,2,3,3,4,4,4-heptafluorobutyryl)bornan-2-onato-O,O']europium
3-Oxa-2-oxobornan-4-carbonylchlorid
4,7,7-Trimethyl(2-oxabicyclo[2.2.1]hept-1-yl)carbonsure
d-Camphersure
Camphersure
Tris[3-(trifluoroacetyl)bornan-2-onato-O,O']europium
dl-Camphersureanhydrid
1-[1-(p-Tolyl)ethyl]hydrogencamphorat
1-(1-Phenylpentyl)hydrogencamphorat
- (-)-Camphoric acid, (1S,3R)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
- (1S)-1,2,2-Trimethylcyclopentane-1α,3α-dicarboxylic acid
- (1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid
- [1S,(-)]-1,2,2-Trimethyl-1α,3α-cyclopentanedicarboxylic acid
- 1,2,2-Trimethylcyclopentane-1α,3α-dicarboxylic acid
- (-)-CAMPHORIC ACID, UNNATURAL FORM
- Acid, L-caMphor
- (1S,3R)-(-)-CaMphoric acid 99%
- (1S,3R)-(-)-Camphoric Acid
- (-)-CAMPHORIC ACID
- L-(-)-CAMPHORIC ACID
- (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
- (1S,3R)-(-)-CAMPHORIC ACID
- (1S,3R)-CAMPHORIC ACID
- (-)-Camphoric acid
- (+)-Camphoric Acid
- 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1S,3R)-
- L-Camphoric acid|||Camphoric acid, (-)-
- 560-09-8
- Chiral Resolving Reagents
- Chiral Resolution Reagents
- Asymmetric Synthesis
- Chiral Reagents
- Miscellaneous Reagents
- Chiral Compound