(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE
|
|
|
- CAS-Nr.
- 82499-43-2
- Englisch Name:
- (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE
- Synonyma:
- (bicyclo(2.2.1)hepta-2,5-diene)(1,4-bis-(diphenyl;bicycloheptadiene(diphenylphosphino)butane rhodium BF4;(BICYCLO(2.2.1)HEPTA-2,5-DIENE)(1,4-BIS- (DIPHENYLPHOS)BUTANE)RH(I) BF4;(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE;bicyclo[2.2.1]hepta-2,5-diene,4-diphenylphosphanylbutyl(diphenyl)phosphane,rhodium,tetrafluoroborate
- CBNumber:
- CB2698915
- Summenformel:
- C35H36BF4P2Rh
- Molgewicht:
- 708.32
- MOL-Datei:
- 82499-43-2.mol
|
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE Eigenschaften
- Schmelzpunkt:
- 210 °C (dec.)(lit.)
- storage temp.
- Inert atmosphere,2-8°C
- L?slichkeit
- insol Et2O, pentane; sol CH2Cl2, MeOH, etc
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R20/21/22:Gesundheitssch?dlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
synthetische
a solution of [Rh(nbd)acac] in THF is treated with fluoroboric acid, followed by addition of 1,4-bis(diphenylphosphino)butane (dppb). The solution becomes deep red and ether is added to precipitate the catalyst, which is then isolated by filtration. The unpurified product is generally adequately pure for most applications. Recrystallization from methanol can be performed to obtain orange needles of [Rh(nbd)(dppb)]BF4. Although air-sensitive in solution, the crystalline complex is indefinitely stable when prepared pure and stored under N2 or Ar below 0 °C. A convenient preparation of the corresponding trifluoromethanesulfonate has been described. The cyclooctadiene (cod) analog has been characterized by X-ray crystallography, and the dynamic solution structure of related systems has been studied by multinuclear NMR techniques.
Lager
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE should store under argon in freezer; stable as solid; solutions are air sensitive. Literature describes the use of perchlorate salts but their use cannot be recommended due to risk of detonation. Use in a fume hood.
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 38)Lieferanten
82499-43-2()Verwandte Suche:
- (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE
- (bicyclo(2.2.1)hepta-2,5-diene)(1,4-bis-(diphenyl
- (BICYCLO(2.2.1)HEPTA-2,5-DIENE)(1,4-BIS- (DIPHENYLPHOS)BUTANE)RH(I) BF4
- bicycloheptadiene(diphenylphosphino)butane rhodium BF4
- bicyclo[2.2.1]hepta-2,5-diene,4-diphenylphosphanylbutyl(diphenyl)phosphane,rhodium,tetrafluoroborate
- 82499-43-2
- C35H36BF4P2Rh
- Catalysis and Inorganic Chemistry
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- Rhodium
