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Hexachloroplatinsure

Chloroplantinic acid Struktur
16941-12-1
CAS-Nr.
16941-12-1
Bezeichnung:
Hexachloroplatinsure
Englisch Name:
Chloroplantinic acid
Synonyma:
CPA;CHLOROPLATINIC ACID;PLATINUM CHLORIDE;Chloroplatinic acid hexahydrate;PL 50T;nsc4958;atinic acid;speier’scatalyst;CHLORPLATINICACID;PLATINIC CHLORIDE
CBNumber:
CB2271499
Summenformel:
Cl6H2Pt
Molgewicht:
409.81
MOL-Datei:
16941-12-1.mol

Hexachloroplatinsure Eigenschaften

Schmelzpunkt:
60 °C(lit.)
Dichte
2.43 g/mL at 25 °C(lit.)
Dampfdruck
0Pa at 20℃
Brechungsindex
n20/D 1.347
storage temp. 
2-8°C
L?slichkeit
H2O: 0.5 M at 20 °C, clear, orange
Aggregatzustand
powder and chunks
Farbe
orange
Wasserl?slichkeit
soluble
Merck 
14,7526
Expositionsgrenzwerte
ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3
Stabilit?t:
May decompose on exposure to light, air or moisture.
InChIKey
GBFHNZZOZWQQPA-UHFFFAOYSA-J
EPA chemische Informationen
Platinate(2-), hexachloro-, hydrogen (1:2), (OC-6-11)- (16941-12-1)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher T,C,Xi
R-S?tze: 25-34-42/43-36/38-36/37/38-22
S-S?tze: 26-27-36/37/39-45-22-23
RIDADR  UN 3264 8/PG 3
WGK Germany  1
RTECS-Nr. TP1510000
3-8-10
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  28439000
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H290 Kann gegenüber Metallen korrosiv sein. Korrosiv gegenüber Metallen Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS05.jpg" width="20" height="20" /> P234, P390, P404
H301 Giftig bei Verschlucken. Akute Toxizit?t oral Kategorie 3 Achtung GHS hazard pictogramssrc="/GHS06.jpg" width="20" height="20" /> P264, P270, P301+P310, P321, P330,P405, P501
H314 Verursacht schwere Ver?tzungen der Haut und schwere Augensch?den. ?tzwirkung auf die Haut Kategorie 1B Achtung GHS hazard pictogramssrc="/GHS05.jpg" width="20" height="20" /> P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 Kann allergische Hautreaktionen verursachen. Sensibilisierung der Haut Kategorie 1A Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H334 Kann bei Einatmen Allergie, asthmaartige Symptome oder Atembeschwerden verursachen. Sensibilisierung der Atemwege Kategorie 1 Achtung GHS hazard pictogramssrc="/GHS08.jpg" width="20" height="20" /> P261, P285, P304+P341, P342+P311,P501
H373 Kann die Organe sch?digen bei l?ngerer oder wiederholter Exposition. Spezifische Zielorgan-Toxizit?t (wiederholte Exposition) Kategorie 2 Warnung P260, P314, P501
H411 Giftig für Wasserorganismen, mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 2
Sicherheit
P234 Nur im Originalbeh?lter aufbewahren.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P303+P361+P353 BEI BERüHRUNG MIT DER HAUT (oder dem Haar): Alle kontaminierten Kleidungsstücke sofort ausziehen. Haut mit Wasser abwaschen oder duschen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

Hexachloroplatinsure Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R25:Giftig beim Verschlucken.
R34:Verursacht Ver?tzungen.
R42/43:Sensibilisierung durch Einatmen und Hautkontakt m?glich.
R36/38:Reizt die Augen und die Haut.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S27:Beschmutzte, getr?nkte Kleidung sofort ausziehen.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S22:Staub nicht einatmen.

Chemische Eigenschaften

Orange/Red Crystals

Verwenden

Chloroplantinic acid (H2PtCl6) is one of the most commercially important compounds of platinum. Its many uses include etching on zinc, making indelible ink, plating, and coloring in fine porcelains and use in photography, in mirrors, and as a catalyst.

Definition

chloroplatinic acid: A reddish crystallinecompound, H2PtCl6, made bydissolving platinum in aqua regia.

Allgemeine Beschreibung

Chloroplatinic acid, is a reddish-brown solid. Chloroplatinic acid is soluble in water and will yield a mildly acidic solution. Chloroplatinic acid may cause illness from inhalation of the dust and Chloroplatinic acid is irritating to skin and eyes. When heated to high temperatures Chloroplatinic acid may decompose to toxic chloride fumes. Chloroplatinic acid may burn, but may be difficult to ignite. Chloroplatinic acid is used for manufacturing indelible ink and in electroplating processes.

Air & Water Reaktionen

Soluble in water.

Reaktivit?t anzeigen

Oxidizing acids are generally soluble in water with the release of hydrogen ions. The resulting solutions have pH's of less than 7.0. Materials in this group react with chemical bases (for example: amines and inorganic hydroxides) to form salts. These neutralization reactions occur as the base accepts hydrogen ions that the acid donates. Neutralizations can generate dangerously large amounts of heat in small spaces. The dissolution of acids in water or the dilution of their concentrated solutions with water may generate significant heat. The addition of water acids often generates sufficient heat in the small region of mixing to boil some of the water explosively. The resulting "bumping" spatters acid widely. These materials have significant ability as oxidizing agents. but that ability varies (for example, from high for nitric acid to low for sulfuric acid and most sulfonic acids). They can react with active metals, including iron and aluminum, and also many less active metals, to dissolve the metal and liberate hydrogen and/or toxic gases. Like other acids, materials in this group can initiate polymerization in certain classes of organic compounds. Their reactions with cyanide salts and compounds release gaseous hydrogen cyanide. Flammable and/or toxic gases are also often generated by their reactions with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides, and weak or strong reducing agents. Additional gas-generating reactions occur with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), and even carbonates: the carbon dioxide gas from the last is nontoxic but the heat and spattering from the reaction can be troublesome. Acids often catalyze (increase the rate) of chemical reactions.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Brandgefahr

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Sicherheitsprofil

Poison by intravenous and intraperitoneal routes. Mutation data reported. See PLATINUM COMPOUNDS and CHLORIDES. Incompatible with BrF3. When heated to decomposition it emits toxic fumes of Cl-.

m?gliche Exposition

Chloroplatinic acid has many uses, among them are platinum plating, photography, and catalysis.

Versand/Shipping

UN2507 Chloroplatinic acid, solid, Hazard class: 8; Labels: 8-Corrosive material.

l?uterung methode

If it is to be purified, or regenerated from Pt recovered from catalytic hydrogenations, it should be dissolved in aqua regia followed by evaporation to dryness and dissolution in the minimum volume of H2O. Then the aqueous solution is treated with saturated ammonium chloride until all the ammonium hexachloroplatinate separates. The (NH4)2PtCl6 is filtered off and dried at 100o. Igniting this salt gives Pt sponge; dissolve the Pt sponge in aqua regia, boil to dryness, dissolve the residue in concentrated HCl, boil to dryness again and repeat the process. Protect it from light. [Hickers J Am Chem Soc 43 1268 1921, Adams et al. Org Synth Coll Vol I 463, 466 1941, Bruce J Am Chem Soc 58 687 1936.]

Inkompatibilit?ten

Oxidizing acids are generally soluble in water with the release of hydrogen ions. The resulting solutions have pH’s of <7.0. Materials in this group react with chemical bases (e.g., amines and inorganic hydroxides) to form salts. These neutralization reactions occur as the base accepts hydrogen ions that the acid donates. Neutralizations can generate dangerously large amounts of heat in small spaces. The dissolution of acids in water or the dilution of their concentrated solutions with water may generate significant heat. The addition of water acids often generates sufficient heat in the small region of mixing to boil some of the water explosively. The resulting “bumping” spatters acid widely. These materials have significant ability as oxidizing agents. but that ability varies (e.g., from high for nitric acid to low for sulfuric acid and most sulfonic acids). They can react with active metals, including iron and aluminum, and also many less active metals, to dissolve the metal and liberate hydrogen and/or toxic gases. Like other acids, materials in this group can initiate polymerization in certain classes of organic compounds. Their reactions with cyanide salts and compounds release gaseous hydrogen cyanide. Flammable and/or toxic gases are also often generated by their reactions with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides, and weak or strong reducing agents. Additional gas-generating reactions occur with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), and even carbonates: the carbon dioxide gas from the last is nontoxic but the heat and spattering from the reaction can be troublesome. Acids often catalyze (increase the rate) of chemical reactions.

Hexachloroplatinsure Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Hexachloroplatinsure Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 312)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Shanghai Bojing Chemical Co.,Ltd.
+86-86-02137122233 +8613795318958
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Hebei Yanxi Chemical Co., Ltd.
+8617531190177
peter@yan-xi.com China 5857 58
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+86-13131129325
sales1@chuanghaibio.com China 5889 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21634 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075
jack.li@time-chemicals.com China 1803 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795
ivan@atkchemical.com China 32957 60
AB PharmaTech,LLC
323-480-4688
sales@acrospharmatech.com United States 989 55
career henan chemical co
+86-0371-86658258 +8613203830695
sales@coreychem.com China 29880 58
Jinan Shengqi pharmaceutical Co,Ltd
86+18663751872
christine@shengqipharm.com CHINA 491 58
Jinan Finer Chemical Co., Ltd
+86-531-88989536 +86-15508631887
sales@finerchem.com China 2961 58

16941-12-1(Hexachloroplatinsure)Verwandte Suche:


  • CHLOROPLATINIC ACID CRYSTAL
  • CHLOROPLANITIC ACID
  • CHLORPLATINICACID
  • Platinum(IV) chloride, hydrate
  • hexachloro-, dihydrogen, (OC-6-11)-Platinate
  • CHLOROPLATINIC ACID HEXAHYDRATE: (38-40% PT), 99.9%
  • HEXACHLOROPLATINIC(IV) ACID HEXAHYDRATE (40% PT)
  • Hexachloroplatinic acid hexahydrate
  • Dihydrogen hexachloroplatinate(IV) solution, Pt 20% (cont. Pt)
  • Chloro Platinic Acid Crystal (Hydrogen Hexachloro Platinate (IV) Hydrate)
  • Dihydrogen hexachloroplatinate: (Chloroplatanic acid)
  • PLATINUM CHLORIDE SOLUTION
  • Dihydrogen hexachloroplatinate(IV) solution, Pt 20 wt. % in water (cont. Pt)
  • Platinic chloride solution
  • Platinum(IV) chloride solution
  • Hexachloroplatinic(IV) acid solution about
  • Platinum (IV) Chloride Solution, 10% w/v
  • PLATINIC CHLORIDE
  • PLATINIC CHLORIDE HYDRATE
  • Dihydrogen Hexachloroplatinate (IV), Pt 40%
  • Dihydrogen hexachloroplatinate(IV) solution, Pt 30% (cont. Pt)
  • Hexachloroplatinic(IV) acid solution, Hydrogen hexachloroplatinate(IV) solution
  • Hexachloroplatinic acid solution, Hydrogen hexachloroplatinate(IV) solution, Platinic chloride solution, Platinum(IV) chloride solution
  • Hydrogen hexachloroplatinate(IV) solution,Hexachloroplatinic(IV) acid solution
  • Chloroplatinic acid solution,Hexachloroplatinic acid solution, Hydrogen hexachloroplatinate(IV) solution, Platinic chloride solution, Platinum(IV) chloride solution
  • CHLOROPLATINIC ACID REAGENT (ACS)
  • chloroplatinic(iv)acid
  • chloroplatinicacid,solid
  • dihydrogen,(oc-6-11)-platinate(2-hexachloro-
  • dihydrogenhexachloroplatinate
  • dihydrogenhexachloroplatinate(2-)
  • hexachloro-,dihydrogen,(OC-6-11)-Platinate(2-)
  • hexachloroplatinic(iv)
  • hydrogenhexachloroplatinate(4+)
  • hydrogen-hexachloroplatinic(4+)aci
  • nsc4958
  • platinumchloride(h2ptcl6)
  • speier’scatalyst
  • DIHYDROGEN HEXACHLOROPLATINATE (IV)
  • HEXACHLOROPLATINIC ACID
  • HEXACHLOROPLATINIC ACID HYDRATE
  • HEXACHLOROPLATINIC(IV) ACID
  • HYDROGEN HEXACHLOROPLATINATE[IV]
  • Platinate(2-), hexachloro-, hydrogen (1:2), (OC-6-11)-
  • Chloroplatinic(IV) acid (6CI)
  • PL 50T
  • Platinate(2-), hexachloro-, dihydrogen (8CI)
  • (Hydro)chloroplatinic acid
  • Chloroplatinic acid solution 8 wt. % in H2O
  • Dihydrogen hexachloroplatinate(IV) solution
  • PLATINUM ICP STANDARD SOLUTION FLUKA, FO R ICP
  • HYDROGEN HEXACHLOROPLATINATE(IV), 8 WT. % SOLUTION IN WATER
  • PLATINUM ATOMIC SPECT. STANDARD SOL. FLU KA, IN HYDROCH.A.
  • Hydrogen hexachloroplatinate(IV) solution
  • Hydrogen hexachloroplatinate(IV) hydrate, 98+%
  • Hexachloroplatinum(Ⅳ)Acid Hydrat
  • Chloroplatinicacidhexahydrate(38-40%Pt)(99.9%-Pt)
  • Platinate(2-), hexachloro-, dihydrogen, (OC-6-11)-
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