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Propham

Propham Struktur
122-42-9
CAS-Nr.
122-42-9
Bezeichnung:
Propham
Englisch Name:
Propham
Synonyma:
IPC;y2;Y 2;IFC;IFK;INPC;IPPC;Tixit;IPC(R);Birgin
CBNumber:
CB2179522
Summenformel:
C10H13NO2
Molgewicht:
179.22
MOL-Datei:
122-42-9.mol

Propham Eigenschaften

Schmelzpunkt:
90°C
Siedepunkt:
311.75°C (rough estimate)
Dichte
1.0900
Brechungsindex
1.4989 (estimate)
Flammpunkt:
11 °C
storage temp. 
APPROX 4°C
Aggregatzustand
Solid
pka
13.74±0.70(Predicted)
Farbe
Dark brown, blue-black
Wasserl?slichkeit
0.1g/L(25 ºC)
Merck 
13,7908
BRN 
2209666
CAS Datenbank
122-42-9(CAS DataBase Reference)
IARC
3 (Vol. 12, Sup 7) 1987
NIST chemische Informationen
Carbamic acid, phenyl-, 1-methylethyl ester(122-42-9)
EPA chemische Informationen
Propham (122-42-9)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher F,T,Xn
R-S?tze: 36/37/38-39/23/24/25-23/24/25-11-22
S-S?tze: 26-36-45-16-7-36/37
RIDADR  UN 1230 3/PG 2
WGK Germany  3
RTECS-Nr. FD9100000
TSCA  Yes
HS Code  29242990
Giftige Stoffe Daten 122-42-9(Hazardous Substances Data)
Toxizit?t LD50 in male, female rats (mg/kg): 3724, 4315 orally (Gaines, Linder)
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitssch?dlich bei Verschlucken. Akute Toxizit?t oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
Sicherheit

Propham Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
R22:Gesundheitssch?dlich beim Verschlucken.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S16:Von Zündquellen fernhalten - Nicht rauchen.
S7:Beh?lter dicht geschlossen halten.

Chemische Eigenschaften

Propham is a colorless crystalline solid.

Verwenden

Herbicide, applied as a spray to the soil.

Allgemeine Beschreibung

Colorless crystalline solid.

Reaktivit?t anzeigen

Propham is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

Hazard

Toxic by ingestion.

Health Hazard

Moderately toxic herbicide; exhibited low tomoderate toxicity in experimental animalswhen administered by oral, intraperitoneal,intravenous, and subcutaneous routes; skinabsorption is slow; cholinesterase inhibitor;in human ingestion can cause carbamatepoisoning, which can be lethal when takenin large amount; probable lethal oral dosein adult human estimated to be larger thanother carbamate insecticides within the range35–50 g.

Sicherheitsprofil

Poison by intraperitoneal route. Moderately toxic to humans by ingestion. Moderately toxic experimentally by ingestion and possibly other routes. An experimental teratogen. Human mutation data reported. Questionable carcinogen with experimental neoplastigenic data. An herbicide. When heated to decomposition it emits toxic fumes of NO,. See also CARBAMATES.

m?gliche Exposition

A potential danger to those involved in the manufacture, formulation and application of this car- bamate/organonitrogen grass-control herbicide.

Environmental Fate

Biological. Rajagopal et al. (1989) reported that Achromobacter sp. and an Arthrobacter sp. utilized propham as a sole carbon source. Metabolites identified were Nphenylcarbamic acid, aniline, catechol, monoisopropyl carbonate, 2-propanol and carbon dioxide (Rajagopal et al., 1989).
Soil. Readily degraded by soil microorganisms forming aniline and carbon dioxide (Humburg et al., 1989). The reported half-life in soil is approximately 15 and 5 days at 16 and 29°C, respectively (Hartley and Kidd, 1987).
Groundwater. According to the U.S. EPA (1986) propham has a high potential to leach to groundwater.
Plant. The major plant metabolite which was identified from soybean plants is isopropyl N-2-hydroxycarbanilate (Hartley and Kidd, 1987; Humburg et al., 1989).
Chemical/Physical. Hydrolysis of propham yields N-phenylcarbamic acid and 2-propanol. The acid is very unstable and is spontaneously decomposed to form aniline and carbon dioxide (Still and Herrett, 1976). Emits toxic fumes of nitrogen oxides when heated to decomposition (Sax and Lewis, 1987).

Versand/Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous haz- ardous material, Technical Name Required. UN2757 Carbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Inkompatibilit?ten

Carbamates are incompatible with reduc- ing agents, strong acids, oxidizing acids, peroxides, and bases. Contact with active metals or nitrides cause the release of flammable, and potentially explosive, hydrogen gas. May react violently with bromine, ketones. Incompatible with azo dyes, caustics, ammonia, amines, boranes, hydrazines, strong

Waste disposal

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. In accordance with 40CFR165, follow recom- mendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following pack- age label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Propham Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Propham Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 104)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hebei Weibang Biotechnology Co., Ltd
+8615531157085
abby@weibangbio.com China 8810 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21634 55
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28172 58
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22963 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873
sales@chemdad.com China 39894 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 49374 58
career henan chemical co
+86-0371-86658258 +8613203830695
factory@coreychem.com China 29811 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763
sales@tnjchem.com China 34563 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739
info@dycnchem.com China 52849 58
Suzhou Victorypharm Co.,Ltd.
+86-13916956214
sales@victory-pharm.com China 1299 58

122-42-9(Propham)Verwandte Suche:


  • Propan-2-yl N-phenylcarbamate
  • Propham 1g [122-42-9]
  • IPC(R)
  • INPC(R)
  • ISO-PPC(R)
  • ISOPROPYL PHENYLCARBAMATE
  • ISOPROPYL N-PHENYLCARBAMATE
  • ISO-PROPYL CARBANILATE
  • isopropyl carbanilic acid ester
  • CARBANILIC ACID ISOPROPYL ESTER
  • 2-Methylethylphenylcarbamate
  • Propham? Tixit
  • isopropyl N-phenylcarbamate,IPC
  • PROPHAM PESTANAL (ISOPROPYL PHENYL CARBA
  • PROPHAM, 1GM, NEAT
  • ifk (ussr)
  • propham (bsi,iso,wssa)
  • propham solution
  • ISOPROPYLCARBANILICACID
  • isopropil-n-fenil-carbammato[italian][qr]
  • Isopropyl phenyl urethane
  • Isopropyl phenylcarbmate
  • Isopropylester kyseliny karbanilove
  • isopropylesterkyselinykarbanilove
  • Isopropyl-N-fenyl-carbamaat
  • isopropyl-n-fenyl-carbamaat[dutch][qr]
  • Isopropyl-N-phenyl-carbamat
  • isopropyl-n-phenyl-carbamat[german][qr]
  • isopropyl-n-phenylcarbamate[qr]
  • Isopropyl-N-phenylurethan
  • MSS IPC 50
  • N-Phenyl isopropyl carbamate
  • N-Phenylcarbamate d'isopropyle
  • n-phenylcarbamated’isopropyle
  • Triherbide
  • Triherbide-IPC
  • Tuberit
  • USAF D-9
  • usafd-9
  • Y 2
  • y2
  • PROPHAM
  • phenylcarbamic acid 1-methylethyl ester
  • O-ISOPROPYL N-PHENYLCARBAMATE
  • 1-Methylethyl phenylcarbamate
  • 1-methylethylphenylcarbamate[qr]
  • Agermin
  • Ban-Hoe
  • Beet-Kleen
  • Birgin
  • Carbamate pesticide IPC
  • Carbamic acid, phenyl, isopropyl ester
  • carbamicacid,phenyl-,1-methylethylester
  • Chem Hoe FL4
  • Chem-Hoe
  • Collavin
  • IFC
  • IFK
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