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Cyanoferrocene

Cyanoferrocene Struktur
1273-84-3
CAS-Nr.
1273-84-3
Englisch Name:
Cyanoferrocene
Synonyma:
Cyanoferrocene;Ferrocene, cyano-;Ferrocenylnitrile;Ferrocenyl cyanide;Cyclopentadienecarbonitrile, cyclopentadienyliron deriv.
CBNumber:
CB21457014
Summenformel:
C6H4N.C5H5.Fe
Molgewicht:
211.044
MOL-Datei:
1273-84-3.mol

Cyanoferrocene Eigenschaften

Schmelzpunkt:
107-108℃

Sicherheit

Cyanoferrocene Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

Cyanoferrocene, [Fe(C5H5)(C6H4N)], forms sheets through hydrogen bonding. The N atom in the molecule accepts hydrogen bonds from C-H bonds in two other molecules, resulting in each molecule being hydrogen-bonded to four others. cyanoferrocene has occupied an important position since it can be converted to a structurally diverse set of ferrocenyl compounds that are attractive synthetic targets due to their chemical and biological properties.

synthetische

The synthesis of cyanoferrocene involved treating 3.1g (0.01 mol) of iodoferrocene and 3.6g (0.04 mol) of copper(I) cyanide with 20 ml of pyridine, using the same procedure used for preparing chloroferrocene. The resulting crude product was purified by chromatography on Florisil, yielding 1.75 g of cyanoferrocene with a yield of 83%. The melting point of cyanoferrocene was 106-107°C (lit. 107-108°C). A by-product of unidentified yellow crystals was also obtained, weighing 0.15g with a melting point of 157-158°C.

Einzelnachweise

The Reaction of Haloferrocenes with Copper(Ⅰ) Salts
DOI: 10.1246/bcsj.42.1976
Cyanoferrocene: a Two-Dimensional Network Generated by Short C-H...N Hydrogen Bonds
DOI: 10.1107/S0108270196006233
Efficient one-pot synthesis of cyanoferrocene from ferrocenecarboxaldehyde using NH2OH · HCl/KI/ZnO/CH3CN system
DOI: 10.1016/j.jorganchem.2007.02.002

Cyanoferrocene Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Cyanoferrocene Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 50)Lieferanten
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Shaanxi Dideu Medichem Co. Ltd
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Capot Chemical Co.,Ltd.
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Coresyn Pharmatech Co., Ltd.
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PT CHEM GROUP LIMITED
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GIHI CHEMICALS CO.,LIMITED
+8618058761490
info@gihichemicals.com China 49978 58

1273-84-3()Verwandte Suche:


  • Cyclopentadienecarbonitrile, cyclopentadienyliron deriv.
  • Ferrocenyl cyanide
  • Ferrocenylnitrile
  • Ferrocene, cyano-
  • Cyanoferrocene
  • 1273-84-3
  • C11H9FeN
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