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(8ξ,9ξ,10ξ,11ξ,12ξ,13ξ,14ξ)-2-(Tetrahydro-4-methyl-5-oxofuran-2-yl)stenine

(8ξ,9ξ,10ξ,11ξ,12ξ,13ξ,14ξ)-2-(Tetrahydro-4-methyl-5-oxofuran-2-yl)stenine Struktur
20460-41-7
CAS-Nr.
20460-41-7
Englisch Name:
(8ξ,9ξ,10ξ,11ξ,12ξ,13ξ,14ξ)-2-(Tetrahydro-4-methyl-5-oxofuran-2-yl)stenine
Synonyma:
Stemonine;Stemonine【C22 alkaloid】;(8ξ,9ξ,10ξ,11ξ,12ξ,13ξ,14ξ)-2-(Tetrahydro-4-methyl-5-oxofuran-2-yl)stenine;Furo[2,3-h]pyrrolo[3,2,1-jk][1]benzazepin-10(2H)-one, 8-ethyldodecahydro-11-methyl-2-(tetrahydro-4-methyl-5-oxo-2-furanyl)-
CBNumber:
CB12281248
Summenformel:
C22H33NO4
Molgewicht:
375.5
MOL-Datei:
20460-41-7.mol

(8ξ,9ξ,10ξ,11ξ,12ξ,13ξ,14ξ)-2-(Tetrahydro-4-methyl-5-oxofuran-2-yl)stenine Eigenschaften

Schmelzpunkt:
151°C

Sicherheit

(8ξ,9ξ,10ξ,11ξ,12ξ,13ξ,14ξ)-2-(Tetrahydro-4-methyl-5-oxofuran-2-yl)stenine Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

This base occurs with Stemonidine (q.v.) in Stemona ovata Nakai. It is laevo_x0002_rotatory with [α]16D - 113.84° and crystallizes as colourless prisms. It gives crystalline salts such as the hydrochloride, m.p. 302°C (dec.) and is a secondary base. With methyl iodide it forms methylstemonine methiodide, m.p. 276°C (dec. ).

Einzelnachweise

Suzuki., J. Pharm. Soc., Japan, 49, 78 (1929)
Suzuki., ibid, 51,43 (1931)
Suzuki., ibid, 54, 101 (1934)

(8ξ,9ξ,10ξ,11ξ,12ξ,13ξ,14ξ)-2-(Tetrahydro-4-methyl-5-oxofuran-2-yl)stenine Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


(8ξ,9ξ,10ξ,11ξ,12ξ,13ξ,14ξ)-2-(Tetrahydro-4-methyl-5-oxofuran-2-yl)stenine Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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  • (8ξ,9ξ,10ξ,11ξ,12ξ,13ξ,14ξ)-2-(Tetrahydro-4-methyl-5-oxofuran-2-yl)stenine
  • Stemonine
  • Stemonine【C22 alkaloid】
  • Furo[2,3-h]pyrrolo[3,2,1-jk][1]benzazepin-10(2H)-one, 8-ethyldodecahydro-11-methyl-2-(tetrahydro-4-methyl-5-oxo-2-furanyl)-
  • 20460-41-7
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