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fumitremorgin B

fumitremorgin B Struktur
12626-17-4
CAS-Nr.
12626-17-4
Englisch Name:
fumitremorgin B
Synonyma:
Lanosulin;Fumitremorgin;FUMITREMORGENB;fumitremorgin B;B Fumitremorgin B;(5aR)-1,2,3,5a,6,11,12,14aβ-Octahydro-5aβ,6β-dihydroxy-9-methoxy-11-(3-methyl-2-butenyl)-12α-(2-methyl-1-propenyl)-5H,14H-pyrrolo[1'',2'':4',5']pyrazino[1',2':1,6]pyrido[3,4-b]indole-5,14-dione;5H,14H-Pyrrolo[1'',2'':4',5']pyrazino[1',2':1,6]pyrido[3,4-b]indole-5,14-dione, 1,2,3,5a,6,11,12,14a-octahydro-5a,6-dihydroxy-9-methoxy-11-(3-methyl-2-buten-1-yl)-12-(2-methyl-1-propen-1-yl)-, (5aR,6S,12S,14aS)-
CBNumber:
CB11387239
Summenformel:
C27H33N3O5
Molgewicht:
479.57
MOL-Datei:
12626-17-4.mol

fumitremorgin B Eigenschaften

Schmelzpunkt:
205-207 °C
Siedepunkt:
724.3±60.0 °C(Predicted)
Dichte
1.35±0.1 g/cm3(Predicted)
storage temp. 
Store at -20°C
L?slichkeit
DMSO: Soluble,Methanol: Soluble
Aggregatzustand
A solid
pka
10.74±0.60(Predicted)

Sicherheit

fumitremorgin B Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

This tremorgenic alkaloid is highly toxic and is elaborated by Aspergillus jurnigatus. The structure given above has been determined from X-ray crystallography. The crystals are orthorhombic with space group P2 1212 1, a = 14.771, b = 24.925 and c = 7.321 A with Z = 4. The absolute configuration is based upon that of L( - )-proline formed by acid hydrolysis of the alkaloid.

Definition

ChEBI: An organic heteropentacyclic compound that is a mycotoxic indole alkaloid produced by several fungi via a tryptophan-proline diketopiperazine intermediate.

Einzelnachweise

Yamazaki et al., Tetrahedron Lett., 27 (1975)

fumitremorgin B Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

fumitremorgin B Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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  • fumitremorgin B
  • FUMITREMORGENB
  • (5aR)-1,2,3,5a,6,11,12,14aβ-Octahydro-5aβ,6β-dihydroxy-9-methoxy-11-(3-methyl-2-butenyl)-12α-(2-methyl-1-propenyl)-5H,14H-pyrrolo[1'',2'':4',5']pyrazino[1',2':1,6]pyrido[3,4-b]indole-5,14-dione
  • Lanosulin
  • 5H,14H-Pyrrolo[1'',2'':4',5']pyrazino[1',2':1,6]pyrido[3,4-b]indole-5,14-dione, 1,2,3,5a,6,11,12,14a-octahydro-5a,6-dihydroxy-9-methoxy-11-(3-methyl-2-buten-1-yl)-12-(2-methyl-1-propen-1-yl)-, (5aR,6S,12S,14aS)-
  • B Fumitremorgin B
  • Fumitremorgin
  • 12626-17-4
  • C27H33N3O5
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