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Dibenzofuran

Dibenzofuran Struktur
132-64-9
CAS-Nr.
132-64-9
Bezeichnung:
Dibenzofuran
Englisch Name:
Dibenzofuran
Synonyma:
DBF;DIBENZO[B,D]FURAN;DIPHENYLENE OXIDE;ibenzofuran;DIBENZOFURON;DIBENZOFURAN;Dibenzofurane;Biphenylenoxid;Dibenzofuran 1;Dibenzofuran>
CBNumber:
CB0338385
Summenformel:
C12H8O
Molgewicht:
168.19
MOL-Datei:
132-64-9.mol

Dibenzofuran Eigenschaften

Schmelzpunkt:
80-82 °C (lit.)
Siedepunkt:
154-155 °C/20 mmHg (lit.)
Dichte
1,3 g/cm3
Dampfdruck
2.48 x 10-3 mmHg at 25 °C (Chirico et al., 1990)
Brechungsindex
1.6480
Flammpunkt:
130 °C
storage temp. 
Store below +30°C.
L?slichkeit
Insoluble in wate(<1 mg/mL). Soluble in nonpolar organic solvents.
Aggregatzustand
Solid
Farbe
White to Almost white
Wasserl?slichkeit
<0.1 g/100 mL at 20 ºC
BRN 
121100
Henry's Law Constant
5.82 x 10-5 atm?m3/mol at 25 °C (approximate - calculated from water solubility and vapor pressure)
Dielectric constant
3.0(100℃)
InChIKey
TXCDCPKCNAJMEE-UHFFFAOYSA-N
CAS Datenbank
132-64-9(CAS DataBase Reference)
NIST chemische Informationen
Dibenzofuran(132-64-9)
EPA chemische Informationen
Dibenzofuran (132-64-9)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher N,Xn,T,F
R-S?tze: 51/53-22-39/23/24/25-23/24/25-11-20/21/22-63-43-36/37/38-45-67-40
S-S?tze: 22-24/25-61-29-45-36/37-16-7-7/9-23-53
RIDADR  UN3077
WGK Germany  3
RTECS-Nr. HP4430000
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29329995
Giftige Stoffe Daten 132-64-9(Hazardous Substances Data)
Toxizit?t Heitmuller et al. (1981) reported a NOEC of 1.0 ppm.
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H225 Flüssigkeit und Dampf leicht entzündbar. Entzündbare Flüssigkeiten Kategorie 2 Achtung GHS hazard pictogramssrc="/GHS02.jpg" width="20" height="20" /> P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Gesundheitssch?dlich bei Verschlucken. Akute Toxizit?t oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
H370 Sch?digt die Organe. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 1 Achtung GHS hazard pictogramssrc="/GHS08.jpg" width="20" height="20" /> P260, P264, P270, P307+P311, P321,P405, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
H411 Giftig für Wasserorganismen, mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 2
Sicherheit
P210 Von Hitze, hei?en Oberfl?chen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.
P260 Dampf/Aerosol/Nebel nicht einatmen.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P301+P310 BEI VERSCHLUCKEN: Sofort GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.
P311 GIFTINFORMATIONSZENTRUM/Arzt anrufen.
P391 Verschüttete Mengen aufnehmen.
P501 Inhalt/Beh?lter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen.

Dibenzofuran Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R51/53:Giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
R22:Gesundheitssch?dlich beim Verschlucken.
R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
R20/21/22:Gesundheitssch?dlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R63:Kann das Kind im Mutterleib m?glicherweise sch?digen.
R43:Sensibilisierung durch Hautkontakt m?glich.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R45:Kann Krebs erzeugen.

S-S?tze Betriebsanweisung:

S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S29:Nicht in die Kanalisation gelangen lassen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S16:Von Zündquellen fernhalten - Nicht rauchen.
S7:Beh?lter dicht geschlossen halten.
S7/9:Beh?lter dicht geschlossen an einem gut gelüfteten Ort aufbewahren.
S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
S53:Exposition vermeiden - vor Gebrauch besondere Anweisungen einholen.

Beschreibung

Dioxins and furans, two well-known environmental pollutants, are extremely toxic to humans and many other species. Dibenzofurans are released into the air from combustion sources, and are listed as pollutants of concern due to its persistence in the environment, potential to bioaccumulate, and toxicity to humans and the environment. These compounds, when adsorbed on soils or other substrates, are highly persistent under normal environmental conditions. The Office of Environmental Health Hazard Assessment reviews risk assessments submitted under the Air Toxics ‘Hot Spots’ Program (AB 2588) in which chlorinated dibenzo-p-dioxins and dibenzofurans are listed. Chlorinated dibenzofurans were calculated as total 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) equivalents in the AB 2588 risk assessments. Dibenzofuran is cited in the Clean Air Act 1990 Amendments – Hazardous Air Pollutants as a volatile hazardous air pollutant of potential concern. The Superfund Amendment Reauthorization Act Section 110 placed dibenzofuran on the revised Agency for Toxic Substances and Disease Registry priority list of hazardous substances to be the subject of a toxicological profile. Dibenzofuran is also listed in the Massachusetts Substance List for Right to Know Law, the New Jersey Department of Health Hazard Right to Know Program Hazardous Substance List, the Pennsylvania Department of Labor and Industry Hazardous Substance List, and the California’s Air Toxics ‘Hot Spots’ List (Assembly Bill 2588).

Chemische Eigenschaften

Dibenzofuran is a white crystalline powder.

Physikalische Eigenschaften

Colorless crystals having a creosote-like odor. The least detectable odor threshold concentration in water at 60 °C was 2 μg/L (Alexander et al., 1982).

Verwenden

Dibenzofuran is an industrial chemical or by-product, and is used as an insecticide, in the production of PVC, industrial bleaching and incineration.

Definition

ChEBI: A mancude organic heterotricyclic parent that consists of a furan ring flanked by two benzene rings ortho-fused across the 2,3- and 4,5-positions.

Allgemeine Beschreibung

Colorless white crystalline solid.

Air & Water Reaktionen

Insoluble in water.

Reaktivit?t anzeigen

Dibenzofuran is sensitive to prolonged exposure to light .

Brandgefahr

Flash point data for Dibenzofuran are not available. Dibenzofuran is probably combustible.

m?gliche Exposition

This material is used as an insecticide and in organic synthesis to make other chemicals. It is derived from coal tar creosote.

Environmental Fate

Biological. Dibenzofuran was oxidized by salicylate-induced cells of Pseudomonas sp. strain 9816/11 and isopropyl-β-D-thiogalactopyranoside-induced cells of Escherichia coli JM109(DE3) (pDTG141) to (1R,2S)-cis-1,2-dihydroxy-1,2-dihydrodibenzofuran (60–70% yield) and (3S,4R)- cis-3,4-dihydroxy-3,4-dihydrodibenzofuran (30–40% yield) (Resnick and Gibson, 1996).
Soil. The estimated half-lives of dibenzofuran in soil under aerobic and anaerobic conditions were 7 to 28 and 28 to 112 d, respectively (Lee et al., 1984).
Groundwater. Based on aerobic acclimated and unacclimated groundwater die away test data, the estimated half-life of dibenzofuran in groundwater ranged from 8.54 to 34.9 d (Lee et al., 1984).
Photolytic. The estimated half-life for the reaction of dibenzofuran with OH radicals in the atmosphere ranged from 1.9 to 19 h (Atkinson, 1987).
Chemical/Physical. It was suggested that the chlorination of dibenzofuran in tap water accounted for the presence of chlorodibenzofuran (Shiraishi et al., 1985).
Dibenzofuran will not hydrolyze because it has no hydrolyzable functional group (Kollig, 1995).

Versand/Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

l?uterung methode

Dissolve dibenzofuran in diethyl ether, then shake it with two portions of aqueous NaOH (2M), wash it with water, separate and dry (MgSO4) it. After evaporating the ether, dibenzofuran is crystallised from aqueous 80% EtOH and then dried under vacuum. [Cass et al. J Chem Soc 1406 1958.] High purity material is obtained by zone refining. [Beilstein 17 V 234.]

Inkompatibilit?ten

This material is used as an insecticide and in organic synthesis to make other chemicals. It is derived from coal tar creosote.

Waste disposal

In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed prop- erly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Dibenzofuran Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Dibenzofuran Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 410)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hebei Weibang Biotechnology Co., Ltd
+8615531157085
abby@weibangbio.com China 8810 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578
sales@hbmojin.com China 12835 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-13131129325
sales1@chuanghaibio.com China 5889 58
Hebei Weibang Biotechnology Co., Ltd
+8617732866630
bess@weibangbio.com China 18151 58
airuikechemical co., ltd.
+undefined86-15315557071
sales02@sdzhonghuimaterial.com China 983 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
+8613343047651
admin@zlchemi.com China 3002 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886
info@dakenam.com China 18751 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21634 55
Hubei XinRunde Chemical Co., Ltd.
+8615102730682
bruce@xrdchem.cn CHINA 566 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795
ivan@atkchemical.com China 32957 60

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