| Identification | More | [Name]
Methyl 4-boronobenzoate | [CAS]
99768-12-4 | [Synonyms]
4-CARBOMETHOXYPHENYLBORONIC ACID
4-METHOXYCARBONYLBENZENEBORONIC ACID
4-METHOXYCARBONYLPHENYLBORONIC ACID
AKOS BRN-0122
METHYL 4-BORONOBENZOATE
P-(METHOXYCARBONYL)PHENYLBORONIC ACID
RARECHEM AH PB 0115
4-METHOXYCATBONYLPHENYLBORONICACID
4-METHOXYCARBONYLPHENYLBORONIC ACID 97%
4-(Methoxycabonyl)phenylboronic acid
4-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) | [EINECS(EC#)]
619-459-9 | [Molecular Formula]
C8H9BO4 | [MDL Number]
MFCD01632203 | [Molecular Weight]
179.97 | [MOL File]
99768-12-4.mol |
| Chemical Properties | Back Directory | [Appearance]
White to light yellow crystal powde | [Melting point ]
197-200 °C (lit.) | [Boiling point ]
345.8±44.0 °C(Predicted) | [density ]
1.25±0.1 g/cm3(Predicted) | [storage temp. ]
0-6°C | [solubility ]
Soluble in methanol. | [form ]
powder | [pka]
7.69±0.10(Predicted) | [color ]
white to off-white | [InChI]
InChI=1S/C8H9BO4/c1-13-8(10)6-2-4-7(5-3-6)9(11)12/h2-5,11-12H,1H3 | [InChIKey]
PQCXFUXRTRESBD-UHFFFAOYSA-N | [SMILES]
C1=CC(C(OC)=O)=CC=C1B(O)O | [CAS DataBase Reference]
99768-12-4(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [TSCA ]
No | [HazardClass ]
IRRITANT | [HS Code ]
29319099 |
| Hazard Information | Back Directory | [Chemical Properties]
White to light yellow crystal powde | [Uses]
4-(Methoxycarbonyl)phenylboronic Acid is a reagent used for• ;Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence1 • ;Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides2 • ;One-pot ipso-nitration of arylboronic acids3 • ;Copper-catalyzed nitration4 • ;Cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling5 • ;Reagent used in Preparation of• ;Biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid6† • ;Chromenones and their
| [Uses]
suzuki reaction |
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