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ChemicalBook--->CAS DataBase List--->99-57-0

99-57-0

99-57-0 Structure

99-57-0 Structure
IdentificationMore
[Name]

2-Amino-4-nitrophenol
[CAS]

99-57-0
[Synonyms]

2-AMINO-4-NITROPHENOL
2-HYDROXY-5-NITROANILINE
3-AMINO-4-HYDROXYNITROBENZENE
4-NAP
4-NITRO-2-AMINOPHENOL
PARA NITRO 2-AMINO PHENOL
P-NITRO-O-AMINOPHENOL
p-Nitro-o-aminophenol 4-Nitro-2-aminophenol
1-amino-2-hydroxy-5-nitrobenzene
1-hydroxy-2-amino-4-nitrobenzene
2-amino-4-nitrofenol
2-amino-4-nitro-pheno
4-nitro-2-aminofenol
4-nitro-2-aminofenol(czech)
amino-2nitro-4phenol
c.i.76530
ci76530
nci-c55958
p-nitroaminofenol
rodol42
[EINECS(EC#)]

202-767-9
[Molecular Formula]

C6H6N2O3
[MDL Number]

MFCD00007695
[Molecular Weight]

154.12
[MOL File]

99-57-0.mol
Chemical PropertiesBack Directory
[Appearance]

OCHRE CRYSTALLINE POWDER
[Melting point ]

140-143 °C (lit.)
[Boiling point ]

322.46°C (rough estimate)
[density ]

1.3617 (estimate)
[vapor pressure ]

0.005Pa at 25℃
[refractive index ]

1.6890 (rough estimate)
[Fp ]

100 °C
[storage temp. ]

Refrigerator, Under Inert Atmosphere
[solubility ]

DMSO (Slightly), Methanol (Slightly)
[form ]

Solid
[pka]

6.82±0.22(Predicted)
[color ]

Dark Yellow to Brown
[Water Solubility ]

slightly soluble
[Detection Methods]

HPLC
[BRN ]

776533
[LogP]

1.26
[CAS DataBase Reference]

99-57-0(CAS DataBase Reference)
[IARC]

3 (Vol. 57) 1993
[EPA Substance Registry System]

99-57-0(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R68:Possible risk of irreversible effects.
R43:May cause sensitization by skin contact.
R40:Limited evidence of a carcinogenic effect.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36:Wear suitable protective clothing .
[RIDADR ]

2811
[WGK Germany ]

2
[RTECS ]

SJ6300000
[Hazard Note ]

Irritant
[TSCA ]

Yes
[HS Code ]

29071990
[Hazardous Substances Data]

99-57-0(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sulfur-->Sodium sulfide-->Sodium sulfide nonahydrate-->2,4-Dinitrochlorobenzene-->SODIUM TETRASULFIDE
[Preparation Products]

6-NITRO-2H-1,4-BENZOXAZIN-3(4H)-ONE-->Acid Black 168-->Mordant Brown 33-->Solvent Red KL-->Reactive Grey K-B4RP-->Neutral Brown Rl-->Reactive Black 8-->Leather Coating Red GL-->Leather Coating Black RL-->Leather Coating Yellow GL-->Picramic acid-->6-AMINO-2H-1,4-BENZOXAZIN-3(4H)-ONE-->PALATINE CHROME GREEN-->Acid Brown 470-->7,7'-(Carbonyldiimino)bis[4-hydroxy-3-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenesulfonic acid]disodium salt-->AZOSOL FAST ORANGE RA-->trihydrogen bis[4-[4,5-dihydro-4-[(2-hydroxy-5-nitrophenyl)azo]-3-methyl-5-oxo-1H-pyrazol-1-yl]benzenesulphonato(3-)]chromate(3-)-->2,4-Dihydro-4-[(2-hydroxy-5-nitrophenyl)azo]-5-methyl-2-phenyl-3H-pyrazol-3-one chromium complex-->Mordant Brown 33-->Solvent Red 100
Hazard InformationBack Directory
[General Description]

Orange prisms or yellow powder. No odor.
[Reactivity Profile]

Oxidation of this chemical may occur in the presence of air and violent decomposition may occur if 2-AMINO-4-NITROPHENOL(99-57-0) is allowed to dry out completely at elevated temperatures. 2-AMINO-4-NITROPHENOL(99-57-0) is stable when stored protected from light and under nitrogen for two weeks at temperatures up to 140° F, and storage under nitrogen for up to 24 weeks at room temperature (77° F) should produce no loss of stability. This chemical is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. 2-AMINO-4-NITROPHENOL(99-57-0) is also incompatible with iron.
[Air & Water Reactions]

Insoluble in water.
[Fire Hazard]

Flash point data for this chemical are not available. 2-AMINO-4-NITROPHENOL is probably combustible.
[Chemical Properties]

OCHRE CRYSTALLINE POWDER
[Uses]

2-Amino-4-nitrophenol is used in preparing some mordant dyes and in some hair dyes.
[Uses]

An aromatic constituent found in hair dyes and other cosmetic products with very low levels of mutagenic activity.
[Definition]

ChEBI: 2-Amino-4-nitrophenol is a member of 4-nitrophenols.
[Synthesis Reference(s)]

Organic Syntheses, Coll. Vol. 3, p. 82, 1955
The Journal of Organic Chemistry, 45, p. 4992, 1980 DOI: 10.1021/jo01312a039
[Flammability and Explosibility]

Nonflammable
[Purification Methods]

Crystallise the phenol from water. [Beilstein 13 IV 896.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

3-Amino-4-hydroxynitrobenzene(99-57-0).msds
Spectrum DetailBack Directory
[Spectrum Detail]

2-Amino-4-nitrophenol(99-57-0)MS
2-Amino-4-nitrophenol(99-57-0)1HNMR
2-Amino-4-nitrophenol(99-57-0)IR1
2-Amino-4-nitrophenol(99-57-0)IR2
2-Amino-4-nitrophenol(99-57-0)IR3
2-Amino-4-nitrophenol(99-57-0)Raman
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