| Identification | More | [Name]
2-Fluorotoluene | [CAS]
95-52-3 | [Synonyms]
2-FLUOROTOLUENE
O-FLUOROTOLUENE
1-Fluor-2-methylbenzol
1-fluoro-2-methyl-benzen
1-Fluoro-2-methylbenzene
1-fluoro-2-methyl-benzene
1-Methyl-2-fluorobenzene
2-fluoromethylbenzene
Benzene,1-fluoro-2-methyl-
benzene,2-fluoro-1-methyl-
o-fluoro-toluen
o-Fluortoluol
ortho-Fluorotoluene
Toluene, o-fluoro-
Toluene,o-fluoro-
o-Fluorotoluene 2-Fluorotoluene
2-FLUOROTOLUENE, 99+%
o-Flouorotoluene
o-Fluorotoluene,99%
2-Fluorotoluene 99% | [EINECS(EC#)]
202-428-5 | [Molecular Formula]
C7H7F | [MDL Number]
MFCD00000322 | [Molecular Weight]
110.13 | [MOL File]
95-52-3.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to slightly yellow liquid | [Melting point ]
-62 °C (lit.) | [Boiling point ]
113-114 °C (lit.) | [density ]
1.001 g/mL at 25 °C(lit.)
| [vapor density ]
3.8 (vs air)
| [vapor pressure ]
21 mm Hg ( 20 °C)
| [refractive index ]
n20/D 1.473(lit.)
| [Fp ]
55 °F
| [storage temp. ]
Flammables area | [form ]
Liquid | [color ]
Clear colorless to slightly yellow | [Specific Gravity]
1.001 | [explosive limit]
1.3%(V) | [Water Solubility ]
immiscible | [Merck ]
14,4180 | [BRN ]
1853362 | [Dielectric constant]
4.2199999999999998 | [LogP]
2.73-2.74 | [CAS DataBase Reference]
95-52-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzene, 1-fluoro-2-methyl-(95-52-3) | [EPA Substance Registry System]
95-52-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xi | [Risk Statements ]
R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S33:Take precautionary measures against static discharges .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 2388 3/PG 2
| [WGK Germany ]
3
| [RTECS ]
XT2579000
| [Hazard Note ]
Flammable/Irritant | [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29036990 | [Toxicity]
LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 2000 mg/kg |
| Hazard Information | Back Directory | [General Description]
A colorless liquid with an aromatic odor. May sink or float on water. | [Reactivity Profile]
2-FLUOROTOLUENE(95-52-3) is of generally low reactivity. Reacts with strong oxidizing agents and strong reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides [USCG, 1999]. | [Air & Water Reactions]
Highly flammable. Insoluble in water. | [Health Hazard]
Inhalation of vapor may cause respiratory irritation. Prolonged and repeated vapor exposures may produce systemic toxic effects. | [Chemical Properties]
clear colorless to slightly yellow liquid | [Uses]
It is employed in organic synthesis. | [Purification Methods]
Dry o-fluorotoluene with P2O5 or CaSO4 and fractionally distil it through a silvered vacuum-jacketed glass column with 1/8th-in glass helices. A high reflux ratio is necessary because of the closeness of the boiling points of the o-, m-and p-isomers [Potter & Saylor J Am Chem Soc 37 90 1951]. [Beilstein 5 H 290, 5 III 676, 5 IV 799.] |
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