| Identification | Back Directory | [Name]
TATM | [CAS]
92051-23-5 | [Synonyms]
TATM
TATM USP/EP/BP
MANNOSE TRIFLATE
MANNOSE TRIFLATE F
beta-D-Mannopyranose
Mannose triflate≥ 99%(GC)
1,3,4,6-Tetra-O-acetyl-2-O-
Mannose Triflate, ultra pure
Mannose Triflate PLUS, ultra pure
Tetra-O-acetyl-mannose triflate CRS
TETRA-O-ACETYL-2-O-TRIFLUOROMETHANE- &
BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-AC&
1,3,4,6-Tetra-O-acetyl-2-O-trifluoroMethane
tetra-O-acetyl-2-O-trifluoromethane-sulfonyl-beta
1,3,4,6-Tetraacetate 2-(trifluoroMethanesulfonate)
BETA-D-MANNOPYRANOSE 1,3,4,6-TETRAACETATE 2-TRIFLATE
1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUORO-*METHANESULFONY
1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-
Mannose Triflate, ultra pure packing for GE Microlab
1,3,4,6-tetra-O-acetyl-2-O-triflat-beta-D-mannopyranose
tetraacetyltrifluoromethanesulfonyl-beta-D-mannopyranose
Mannose Triflate, ultra pure packing for GE TRACERlab MXFDG
TATM, 1,3,4,6-Tetra-O-acetyl-2-O-triflyl-beta-D-mannopyranose
Mannose triflate C15H19F3O12S high quality Cas number：92051-23-5
1,3,4,6-Tetraacetate 2-(trifluoromethanesulfonate) -D-Mannopyranose
1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethylsulfonyl-β-D-mannopyranose
b-D-Mannopyranose,1,3,4,6-tetraacetate 2-(trifluoroMethanesulfonate)
1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE
1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULPHONYL-B-D-MANNOPYRANOSE
1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-b-D-mannopyranose
β-D-Maopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate
β-D-Mannopyranose, 1,3,4,6-tetraacetate 2-(trifluoromethanesulfonate)
1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose
β-D-Mannopyranose1,3,4,6-tetra-O-acetate2-O-trifluoromethanesulfonate
1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose
β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate
1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHANSULFONYL-BETA-D-MANNOPYRANOSE
1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate-β-D-Mannopyranose
1,3,4,6-Tetra-O-Acetyl-2-O-(trifluoromethanesulfonyl)-a-D-mannopyranose
1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUORO-METHANESULFONYL-BETA-D-MANNOPYRANOSE
BETA-D-MANNOPYRANOSE, 1,3,4,6-TETRAACETATE 2-(TRIFLUOROMETHANE-SULFONATE)
BETA-D-MANNOPYRANOSE 1,3,4,6-TETRA-O-ACETATE 2-O-TRIFLUOROMETHANESULFONATE
1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE, TATM
1-O,3-O,4-O,6-O-Tetraacetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose
1-O,3-O,4-O,6-O-Tetraacetyl-2-O-(trifluoromethylsulfonyl)-β-D-mannopyranose
1,3,4,6-Tetra-O-acetyl-2-O-[(trifluoromethyl)sulphonyl]-beta-D-mannopyranose
β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate(TATM)
TATM,1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose
beta-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoroMethanesulfonate 98%
acetic acid [3,4,6-triacetyloxy-5-(trifluoromethylsulfonyloxy)-2-oxanyl]methyl ester
1,3,4,6-TETRA-O-ACETYL-2-O-TRIFLUOROMETHYLSULFONYL-B-D-MANNOPYRANOSE(MANNOSE TRIFLATE)
β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate Mannose triflate
[(2R,3R,4S,5S,6S)-3,4,6-triacetyloxy-5-(trifluoromethylsulfonyloxy)oxan-2-yl]methyl acetate
Mannose triflate, TATM, 1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose
β-D-Mannopyranose 1,3,4,6-tetra-O-acetate 2-O-trifluoromethanesulfonate,1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose, Mannose triflate, TATM | [EINECS(EC#)]
200-001-8 | [Molecular Formula]
C15H19F3O12S | [MDL Number]
MFCD00012353 | [MOL File]
92051-23-5.mol | [Molecular Weight]
480.36 |
| Chemical Properties | Back Directory | [Melting point ]
118-122 °C
| [alpha ]
[α]D20 -14～-17゜(c=1,CHCl3) | [Boiling point ]
481.6±45.0 °C(Predicted) | [density ]
1.50±0.1 g/cm3(Predicted) | [refractive index ]
-16 ° (C=1, CHCl3) | [storage temp. ]
−20°C
| [solubility ]
Chloroform (Slightly), Ethyl Acetate (Slightly) | [form ]
neat | [color ]
White to Off-White | [optical activity]
[α]22/D -16°, c = 1 in chloroform | [BRN ]
4341413 | [InChI]
InChI=1/C15H19F3O12S/c1-6(19)25-5-10-11(26-7(2)20)12(27-8(3)21)13(14(29-10)28-9(4)22)30-31(23,24)15(16,17)18/h10-14H,5H2,1-4H3/t10-,11-,12+,13+,14-/s3 | [InChIKey]
OIBDVHSTOUGZTJ-UBBZJQTNNA-N | [SMILES]
[C@H]1(OC(=O)C)[C@H](OC(=O)C)[C@H](O[C@@H](OC(=O)C)[C@H]1OS(=O)(=O)C(F)(F)F)COC(=O)C |&1:0,5,10,12,17,r| |
| Hazard Information | Back Directory | [Description]
Mannose triflate is a glucose analog. Mannose triflate is a well-known precursor for 18F-FDG synthesis for PET applications. 18F-FDG is an imaging technique for cancer.
| [Chemical Properties]
White to off-white powder or crystal | [Physical properties]
White to off-white powder or crystal | [Uses]
1,3,4,6-Tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose is a radiolabelled pharmaceutical preparation for diagnostic aims used in positron emission tomography.
| [Preparation]
The tetraacetyl mannose (1.8 g, 5 mmol) was dissolved in anhydrous CH2Cl2(14 mL) containing dry pyridine (0.9 mL, 11 mmol). This solution was cooled to -15°C, and trifluoromethanesulfonic anhydride (triflic anhydride) (0.9 mL, 5.2 mmol) was added dropwise over 25 min under a nitrogen atmosphere with vigorous stirring. The mixture was then allowed to reach room temperature overnight. The reaction mixture was successively washed with ice-cold saturated aqueous NaHCO3(50 mL) and water (50 mL). The organic layer was dried over anhydrous Na2SO4, filtered, and concentrated on a rotary evaporator.2-Tf-O-AcManwas isolated by column chromatography on silica with hexane :EtOAc=1: 1 as the eluant as white solid Mannose triflate(1.4 g, 56percent).
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