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ChemicalBook--->CAS DataBase List--->87749-50-6

87749-50-6

87749-50-6 Structure

87749-50-6 Structure
IdentificationMore
[Name]

Tetrabutylammonium fluoride trihydrate
[CAS]

87749-50-6
[Synonyms]

TBAF
TBAF 3H2O
TBAF TRIHYDRATE
TETRABUTYLAMMONIUM FLUORIDE HYDRATE
TETRABUTYLAMMONIUM FLUORIDE TRIHYDRATE
TETRA-N-BUTYLAMMONIUM FLUORIDE TRIHYDRATE
TETRABUTYLAMMONIUMFLUORID-3-HYDRAT
TETRA-N-BUTYLAMMONIUM FLUORIDE 3 H2O
1-Butanaminium, N,N,N-tributyl-, fluoride, trihydrate
Tetrabutylammonium fluoride trihydrate 97%
Tetrabutylammoniumfluoridetrihydrate97%
[EINECS(EC#)]

207-057-2
[Molecular Formula]

C16H42FNO3
[MDL Number]

MFCD00149981
[Molecular Weight]

315.51
[MOL File]

87749-50-6.mol
Chemical PropertiesBack Directory
[Appearance]

white crystals or crystalline powder
[Melting point ]

62-63 °C(lit.)
[Fp ]

-17℃
[storage temp. ]

Store below +30°C.
[form ]

Crystalline Powder, Crystals and/or Chunks
[color ]

White to slightly yellow
[Specific Gravity]

0.887
[PH]

pH (50g/l, 25℃) : 5.0~8.0
[Water Solubility ]

SOLUBLE
[Sensitive ]

Hygroscopic
[BRN ]

3761900
[Exposure limits]

ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
[InChI]

InChI=1S/C16H36N.FH.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;/h5-16H2,1-4H3;1H;1H2/q+1;;/p-1
[InChIKey]

UQCWXKSHRQJGPH-UHFFFAOYSA-M
[SMILES]

[N+](CCCC)(CCCC)(CCCC)CCCC.[F-].O
[CAS DataBase Reference]

87749-50-6(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

C,Xi
[Risk Statements ]

R34:Causes burns.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 1759 8/PG 1
[WGK Germany ]

3
[F ]

3-10
[Hazard Note ]

Irritant
[TSCA ]

T
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29211990
Hazard InformationBack Directory
[Description]

Tetrabutylammonium fluoride trihydrate is a commonly used salt within the realms of organic chemistry and biochemistry. This compound is employed as a potent base, finding extensive use in diverse applications, including organic compound synthesis, buffer preparation, and protein purification. It plays a pivotal role in the synthesis of various organic compounds, such as carboxylic acids, amines, and alcohols. Additionally, this compound facilitates the purification of nucleic acids, including DNA and RNA. Acting as a strong base, tetrabutylammonium fluoride trihydrate possesses the ability to deprotonate a wide range of organic compounds. It is commonly used in applications such as preparation of deprotecting agents, synthesis of lipophilic peprides during DNA transfections, and many more.
[Chemical Properties]

white crystals or crystalline powder
[Uses]

Reactant for:
Preparation of deprotecting agents in preparation of cellulose derivatives
Synthesis of lipophilic peptides for DNA transfections in vivo
Dehydrobromination reactions
[General Description]

Tetrabutylammonium fluoride trihydrate is a mild base used in reactions like aldol-type condensation reactions, Michael-type reactions, ring-opening reactions. Its is also used as a promoter in cross-coupling reactions and cyclization of carbocycles and heterocycles.
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Tetrabutylammonium fluoride trihydrate, 99%(87749-50-6)
[Alfa Aesar]

Tetra-n-butylammonium fluoride trihydrate, 98%(87749-50-6)
[Sigma Aldrich]

87749-50-6(sigmaaldrich)
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