| Identification | More | [Name]
1-Chloromethyl naphthalene | [CAS]
86-52-2 | [Synonyms]
1-(CHLOROMETHYL)NAPHTHALENE
1-CHLOROMETHYLNAPHTHYL
1-NAPHTHYLMETHYL CHLORIDE
2,5-BIS[(1,3-DIOXOBUTYL)AMINO]BENZENESULFONIC ACID
2,5-DIACETOACETAMIDO BENZENE SULFONIC ACID
AKOS BBS-00004040
CHLOROMETHYLNAPHTHALENE(1-)
1-(Chlormethyl)naftalen
1-(chloromethyl)-naphthalen
1-(Chloromethyl)naphthene
1-chloromethyl-naphthalen
1-Menaphthyl chloride
1-menaphthylchloride
alpha-(Chloromethyl)naphthalene
alpha-chloromethyl-naphthalen
alpha-Naphthylmethyl chloride
alpha-naphthylmethylchloride
-Menaphthylchloride
Naphthalene, alpha-(chloromethyl)-
Naphthalene,1-(chloromethyl)- | [EINECS(EC#)]
201-678-2 | [Molecular Formula]
C11H9Cl | [MDL Number]
MFCD04972525 | [Molecular Weight]
176.64 | [MOL File]
86-52-2.mol |
| Chemical Properties | Back Directory | [Appearance]
Solid | [Melting point ]
32 °C(lit.)
| [Boiling point ]
291 °C | [density ]
1.18 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.635(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Refrigerator | [solubility ]
Chloroform, Ethyl Acetate (Slightly), Methanol (Sparingly) | [form ]
Liquid After Melting | [color ]
deep brown
| [Specific Gravity]
1.18 | [Water Solubility ]
Insoluble in water. | [Sensitive ]
Moisture Sensitive | [BRN ]
636885 | [InChIKey]
XMWGTKZEDLCVIG-UHFFFAOYSA-N | [LogP]
3.97 at 20℃ | [CAS DataBase Reference]
86-52-2(CAS DataBase Reference) | [NIST Chemistry Reference]
Naphthalene, 1-(chloromethyl)-(86-52-2) | [EPA Substance Registry System]
86-52-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
C,Xn | [Risk Statements ]
R21/22:Harmful in contact with skin and if swallowed .
R34:Causes burns.
R36/37/38:Irritating to eyes, respiratory system and skin .
R36:Irritating to the eyes.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S20:When using, do not eat or drink .
S27:Take off immediately all contaminated clothing . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [RTECS ]
QJ2800000
| [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29036990 |
| Hazard Information | Back Directory | [Chemical Properties]
Solid | [Uses]
1-(Chloromethyl)naphthalene is a key material for synthesis dye pigment and as fluorescent brightening agent. It is employed in synthetic resin and medicine. Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives produce ortho- or para-substituted carbocycles in satisfactory to excellent yields. | [General Description]
Kinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated. |
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