Identification | More | [Name]
2-Vinylnaphthalene | [CAS]
827-54-3 | [Synonyms]
2-VINYLNAPHTHALENE BETA-VINYLNAPHTHALENE VINYLNAPHTHALENE-2 2-EthenyInaphthalene 2-ethenyl-naphthalen 2-ethenylnaphthalene 2-VINYLNAPHTHALENE, 99+% 2-VINYLNAPHTHALIN 98% 2-Vinylnaphthalene, stabilized, 98% Naphthalene, 2-ethenyl- 2-VINYLNAPHTHALENE , STABILIZED WITH CA 0.4% 4-T-BUTYLCATECHOL 2-Vinylnaphthalene, 97%, stab. with ca 0.4% 4-tert-butylcatechol (2-Naphthyl)ethylene b-Vinylnaphthalene 2-Vinylnaphthalene, 98%, stabilized 2-Vinylnaphthalene, 97%, stab. with ca 0.4% 4-t-butylcatechol | [EINECS(EC#)]
212-573-6 | [Molecular Formula]
C12H10 | [MDL Number]
MFCD00004125 | [Molecular Weight]
154.21 | [MOL File]
827-54-3.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R20/22:Harmful by inhalation and if swallowed . R36/38:Irritating to eyes and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [Hazard Note ]
Keep Cold | [HS Code ]
29029090 |
Hazard Information | Back Directory | [Chemical Properties]
Tan powder | [Application]
Used in plastic scintillators, neutron detectors and other demanding device applications. Poly(2-vinyl naphthalene) is synthesized by free radical or anionic living polymerization 2-vinylnaphthalene. | [Uses]
2-Vinylnaphthalene is employed in the synthesis of various copolymers such as Poly (sodium styrenesulfonate-co-2-vinyl-napthalene) copolymer?and Poly (2-vinylnapthalene-alt-maleic acid)-graft-polystyrene. The latter finds applications as a photoactive polymer micelle and stabilizer for polystyrene latexes. | [Definition]
ChEBI: A vinylnaphthalene carrying a vinyl group at position 2. | [Synthesis Reference(s)]
Tetrahedron Letters, 24, p. 2723, 1983 DOI: 10.1016/S0040-4039(00)88005-3 | [General Description]
2-Vinylnaphthalene (2VNP) can be prepared by the alkylation of naphthalene to I-and 2 ethylnapthalenes followed by dehydrogenation, or by oxidation followed by dehydration. 2VNP is the monomer for poly-(2-vinylnapthalene). | [Purification Methods]
The flammable solid can be fractionally distilled under reduced pressure using a spinning-band column; dry it with CaH2 and again distil it under vacuum. It crystallises from aqueous MeOH, EtOH (m 66o) or pet ether (m 66-66.5o). Store it in sealed ampoules in a freezer. The picrate has m 91-92o (from EtOH). [Beilstein 5 III 1775, 5 IV 1833.] It is an irritant. |
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