| Identification | More | [Name]
1-Bromotridecane | [CAS]
765-09-3 | [Synonyms]
1-BROMOTRIDECANE
N-TRIDECYL BROMIDE
TRIDECYL BROMIDE
1-bromo-tridecan
n-Tridecyl-1-bromide
tridecane,1-bromo- | [EINECS(EC#)]
212-138-0 | [Molecular Formula]
C13H27Br | [MDL Number]
MFCD00000227 | [Molecular Weight]
263.26 | [MOL File]
765-09-3.mol |
| Chemical Properties | Back Directory | [Appearance]
light yellow liquid | [Melting point ]
4-7 °C (lit.) | [Boiling point ]
148-150 °C/10 mmHg (lit.) | [density ]
1.03 g/mL at 25 °C(lit.)
| [vapor density ]
9.2 (vs air)
| [refractive index ]
n20/D 1.459(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform, Methanol | [form ]
Oil | [color ]
Colourless | [Stability:]
Stable. Incompatible with strong bases, strong oxidizing agents. | [BRN ]
1739992 | [CAS DataBase Reference]
765-09-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Tridecane, 1-bromo-(765-09-3) | [EPA Substance Registry System]
765-09-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed.
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection . | [WGK Germany ]
3
| [RTECS ]
YD3100000
| [F ]
8 | [HS Code ]
2903.99.8001 |
| Hazard Information | Back Directory | [Chemical Properties]
light yellow liquid | [Uses]
1-Bromotridecane is a long chain alkyl bromide with skin sensitization potency. 1-Bromotridecane may potentially enhance plant stimulator activity. | [Application]
1-Bromotridecane was used in the synthesis of:
tetradecanoic acid enriched with 13C at carbons 1, 3, or 6
(Z)-7-henicosene
Pentadecanal
(Z)-(2′R)-[N-carboethoxypyrrolidine]tetradec-1-ene
2,3,6,7,10,11,14,15-octaalkyloxytetrabenzo[a,d,g,jlcyclododecatetraenes (CTTV-n) containing n=4-15 methylenic units in the alkyloxy substituents
Coupling reaction between the dilithio-derivative of propargyl alcohol with 1-bromotridecane in liquid ammonia gave 2-hexadecyne-1-ol. | [Preparation]
1-Bromotridecane is prepared from 1-tridecanol.
 | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 44, p. 3405, 1979 DOI: 10.1021/jo01333a029 |
|
|