| Identification | More | [Name]
N,N-DIMETHYLTHIOFORMAMIDE | [CAS]
758-16-7 | [Synonyms]
N,N-DIMETHYLTHIOFORMAMIDE
THIOFORMIC ACID DIMETHYLAMIDE
Dimethylthioformamide
Formamide, N,N-dimethylthio-
HCSN(CH3)2
n,n-dimethyl-methanethioamid
N,N-dimethylmethanethioamide
N,N-dimethylthioforamide
N,N-DIMETHYLTHIOFORMAMIDE, 98+%
Methanethioamide, N,N-dimethyl-
(Dimethylamino)formthialdehyde
(Dimethylamino)methanethione
N,N-Dimethylformthioamide | [EINECS(EC#)]
212-060-7 | [Molecular Formula]
C3H7NS | [MDL Number]
MFCD00004943 | [Molecular Weight]
89.16 | [MOL File]
758-16-7.mol |
| Chemical Properties | Back Directory | [Appearance]
clear yellow liquid | [Melting point ]
-9°C(lit.) | [Boiling point ]
58-60 °C1 mm Hg(lit.) | [density ]
1.047 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.576(lit.)
| [Fp ]
211 °F
| [storage temp. ]
2-8°C | [solubility ]
sol THF, ethyl acetate, toluene, DMF | [form ]
liquid | [pka]
1.71±0.50(Predicted) | [Water Solubility ]
Fully miscible in water. | [BRN ]
1737191 | [Dielectric constant]
47.5 | [InChIKey]
SKECXRFZFFAANN-UHFFFAOYSA-N | [CAS DataBase Reference]
758-16-7(CAS DataBase Reference) | [EPA Substance Registry System]
Methanethioamide, N,N-dimethyl- (758-16-7) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R21/22:Harmful in contact with skin and if swallowed . | [Safety Statements ]
S36/37:Wear suitable protective clothing and gloves . | [RIDADR ]
UN 2810 6.1/PG 3
| [WGK Germany ]
3
| [F ]
13 | [TSCA ]
Yes | [HS Code ]
29309090 |
| Hazard Information | Back Directory | [Chemical Properties]
clear yellow liquid | [Uses]
It is used in telecommunication. | [General Description]
N,N-Dimethylthioformamide undergoes desulfurization reaction with hydrosilane under photo irradiation in the presence of a methyl iron complex. It forms a deep-orange complex with anhydrous bismuth(III) trifluoromethanesulfonate. | [Synthesis]
As with other
thioamides, N,N-Dimethylthioformamide is best obtained by treatment of the parent amide with a suitable thionating reagent (see also
2,4-Bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane 2,4-Disulfide) (eq 1).3d More recently, efficient
conversion has been effected using Phosphorus(V) Sulfide that has been activated using solid Sodium
Carbonate.
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