Identification | More | [Name]
(Bromomethyl)cyclopropane | [CAS]
7051-34-5 | [Synonyms]
1-(BROMOMETHYL)CYCLOPROPANE (BROMOMETHYL)CYCLOPROPANE CYCLOPROPYLMETHYL BROMIDE Cyclopropanemethyl bromide CYCLOPROPYLMETYL BROMIDE CyclopropylmethylBromide96% Cyclopropyl bromo methane Cyclopropane, (bromomethyl)- Cyclopropylmethylbromid CPMBr Cyclopropylcarbinyl bromide Bromo(cyclopropyl)methane | [EINECS(EC#)]
230-331-8 | [Molecular Formula]
C4H7Br | [MDL Number]
MFCD00001306 | [Molecular Weight]
135 | [MOL File]
7051-34-5.mol |
Chemical Properties | Back Directory | [Appearance]
Colorless to yellow liquid | [Melting point ]
87-90 °C | [Boiling point ]
105-107 °C(lit.)
| [density ]
1.392 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.457(lit.)
| [Fp ]
107 °F
| [storage temp. ]
0-6°C | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Liquid | [color ]
Clear colorless to slightly colored | [Specific Gravity]
1.392 | [Stability:]
Stable. Flammable. Incompatible with strong bases, strong oxidizing agents. | [Water Solubility ]
Not miscible in water. | [Detection Methods]
GC | [BRN ]
605296 | [InChIKey]
AEILLAXRDHDKDY-UHFFFAOYSA-N | [CAS DataBase Reference]
7051-34-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Cyclopropane, (bromomethyl)-(7051-34-5) |
Questions And Answer | Back Directory | [Uses]
(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents.
| [Description]
(Bromomethyl) cyclopropane is a cyclopropane derivative. It can be used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1, 4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.
|
Safety Data | Back Directory | [Hazard Codes ]
Xi,F,Xn | [Risk Statements ]
R10:Flammable. R36/37/38:Irritating to eyes, respiratory system and skin . R22:Harmful if swallowed. | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) . S24/25:Avoid contact with skin and eyes . S37/39:Wear suitable gloves and eye/face protection . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S16:Keep away from sources of ignition-No smoking . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN 1993 3/PG 3
| [WGK Germany ]
3
| [Hazard Note ]
Irritant | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29035990 |
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