| Identification | More | [Name]
Methyl tiglate | [CAS]
6622-76-0 | [Synonyms]
METHYL E-2,3-DIMETHYLACRYLATE
METHYL TIGLATE
METHYL-TRANS-2-METHYL-2-BUTENOATE
TIGLIC ACID METHYL ESTER
(E)-2-Methyl-but-2-enoicacidmethylester
2-Butenoic acid, 2-methyl-, methyl ester, (E)-
2-Butenoicacid,2-methyl-,methylester,(2E)-
2-Carbomethoxy-2-butene, (E)-
2-methyl-,methylester,(e)-2-butenoicaci
2-methyl-,methylester,(e)-crotonicaci
2-Methylerotonic acid (Tiglicacid), methyl ester
Crotonic acid, 2-methyl-, methyl ester, (E)-
Methyl (2E)-2-methyl-2-butenoate
methyl (E)-2-methyl-2-butenoate
Methyl (E)-2-methylcrotonate
Methyl alpha-methylcrotonate
Methyl trans-2-methylcrotonate
Methyl(E)-2-methyl-2-butenoate
methyl(e)-2-methylcrotonate
methylalpha-methylcrotonate | [EINECS(EC#)]
229-575-8 | [Molecular Formula]
C6H10O2 | [MDL Number]
MFCD00016654 | [Molecular Weight]
114.14 | [MOL File]
6622-76-0.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless liquid | [Melting point ]
37.22°C (estimate) | [Boiling point ]
137-138 °C758 mm Hg(lit.) | [density ]
0.95 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.436(lit.)
| [Fp ]
95 °F
| [storage temp. ]
Flammables area | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Odor]
at 10.00 % in dipropylene glycol. ethereal rum | [Stability:]
Stable. Flammable. Incompatible with strong oxidising agents. | [Odor Type]
ethereal | [Water Solubility ]
Soluble in alcohol, water 3813 mg/L @ 25°C (est). | [Merck ]
14,9433 | [BRN ]
1720455 | [LogP]
1.869 (est) | [CAS DataBase Reference]
6622-76-0(CAS DataBase Reference) | [NIST Chemistry Reference]
Methyl tiglate(6622-76-0) | [EPA Substance Registry System]
6622-76-0(EPA Substance) |
| Safety Data | Back Directory | [Risk Statements ]
R10:Flammable. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 3272 3/PG 3
| [WGK Germany ]
2
| [RTECS ]
EM9254600
| [TSCA ]
Yes | [HS Code ]
2915.60.5000 | [HazardClass ]
3 | [PackingGroup ]
III |
| Hazard Information | Back Directory | [Chemical Properties]
colourless liquid | [Uses]
Methyl Tiglate is a useful reactant in elaboration of conjugagted alkenes initiated by insertion into a vinylic C-H bond. | [Definition]
ChEBI:Methyl tiglate is a fatty acid ester. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 108, p. 3016, 1986 DOI: 10.1021/ja00271a034 |
|
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Alfa Aesar
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400-6106006 |
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Energy Chemical
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| Website: |
http://www.energy-chemical.com |
| Company Name: |
Maya High Purity Chemicals
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