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ChemicalBook--->CAS DataBase List--->635-93-8

635-93-8

635-93-8 Structure

635-93-8 Structure
IdentificationMore
[Name]

5-Chlorosalicylaldehyde
[CAS]

635-93-8
[Synonyms]

2-HYDROXY-5-CHLOROBENZALDEHYDE
5-CHLORO-2-HYDROXYBENZALDEHYDE
5-CHLOROSALICYLALDEHYDE
5-Chlorosalicylic aldehyde
AKOS 90774
TIMTEC-BB SBB004013
4-Chloro-2-formylphenol
5-chloro-2-hydroxy-benzaldehyd
5-chloro-salicylaldehyd
5-chorosalicylaldehyde
Benzaldehyde, 5-chloro-2-hydroxy-
Benzaldehyde,5-chloro-2-hydroxy-
Salicylaldehyde, 5-chloro-
5-Chlorosalicyladehyde
5-Cl-salicylal
5-Chloro-2-Hydroxybenzaldehyde (5-Chlorosalicylaldehyde)
5-Chlorosalicylaldehyde,98%
5-chloro-salicylal
CHLOROHYDROXYBENZALDEHYDE
5-CHLOROSALICYLALDEHYDE/5-CHLORO-2-HYDROXYBENZALDEHYDE
[EINECS(EC#)]

211-244-4
[Molecular Formula]

C7H5ClO2
[MDL Number]

MFCD00003331
[Molecular Weight]

156.57
[MOL File]

635-93-8.mol
Chemical PropertiesBack Directory
[Appearance]

white to very slightly yellow crystalline powder
[Melting point ]

100-102 °C(lit.)
[Boiling point ]

217.69°C (rough estimate)
[density ]

1.2683 (rough estimate)
[refractive index ]

1.5812 (estimate)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

Crystalline Powder
[pka]

7.73±0.18(Predicted)
[color ]

White to very slightly yellow
[Sensitive ]

Air Sensitive
[BRN ]

636632
[LogP]

2.570 (est)
[CAS DataBase Reference]

635-93-8(CAS DataBase Reference)
[NIST Chemistry Reference]

5-Chloro-2-hydroxy benzaldehyde(635-93-8)
[EPA Substance Registry System]

635-93-8(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

UN2811/6.1/PG III
[WGK Germany ]

3
[RTECS ]

VN5450000
[Hazard Note ]

Irritant
[TSCA ]

Yes
[HS Code ]

29130000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Salicylaldehyde
[Preparation Products]

5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID-->5-CHLORO-BENZOFURAN-2-CARBOXYLIC ACID ETHYL ESTER-->6-CHLORO-2-OXO-2H-CHROMENE-3-CARBOXYLIC ACID-->Diethyl succinosuccinate-->5-CHLORO-2-HYDROXYBENZYL ALCOHOL-->5-CHLORO-2-HYDROXY-3-NITRO-BENZALDEHYDE-->6-CHLORO-2H-1-BENZOPYRAN-3-CARBOXYLIC ACID-->3-Bromo-5-chlorosalicylaldehyde-->Ethyl 6-chloro-2-(trifluoromethyl)-2H-chromene-3-carboxylate-->1,2,3-benzoxathiazine, 6-chloro-, 2,2-dioxide-->2-(BENZYLOXY)-5-CHLOROBENZALDEHYDE-->2H-1-Benzopyran-2-one, 6-chloro-4-hydroxy-3-Methyl-
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

5-Chlorosalicylic aldehyde(635-93-8).msds
Hazard InformationBack Directory
[Chemical Properties]

white to very slightly yellow crystalline powder
[Uses]

5-Chlorosalicyaldehyde is a useful synthetic intermediate and a key precursor to a variety chelating agents.5-Chlorosalicyaldehyde is used to synthesize imine resveratrol (R150000) derivatives as multi-targeted agents against Alzheimer's disease.
[Synthesis Reference(s)]

Synthetic Communications, 20, p. 609, 1990 DOI: 10.1080/00397919008244911
Tetrahedron Letters, 15, p. 3463, 1974
[Purification Methods]

Steam distil it, then crystallise it from aqueous EtOH or *C6H6 (m 100o). It forms complexes with Cu2+ and Fe2+ . [Beilstein 8 H 53, 8 II 45, 8 III 181, 8 IV 224.]
Spectrum DetailBack Directory
[Spectrum Detail]

5-Chlorosalicylaldehyde(635-93-8)1HNMR
5-Chlorosalicylaldehyde(635-93-8)Raman
5-Chlorosalicylaldehyde(635-93-8)IR
5-Chlorosalicylaldehyde(635-93-8)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

5-Chlorosalicylaldehyde, 98%(635-93-8)
[Alfa Aesar]

5-Chlorosalicylaldehyde, 98%(635-93-8)
[Sigma Aldrich]

635-93-8(sigmaaldrich)
[TCI AMERICA]

5-Chlorosalicylaldehyde,>98.0%(GC)(635-93-8)
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