Identification | More | [Name]
HEPTANOIC ANHYDRIDE | [CAS]
626-27-7 | [Synonyms]
ENANTHIC ANHYDRIDE HEPTANOIC ANHYDRIDE N-HEPTANOIC ANHYDRIDE OENANTHIC ANHYDRIDE heptanoicacid,anhydride heptanoicacidanhydride Heptanoyl anhydride n-Heptanoic acid anhydride HEPTANOIC ANHYDRIDE 99% Enanthic acid anhydride heptylic anhydride Enanthic anhydride, Oenanthic anhydride Bisenanthic anhydride Bisheptanoic anhydride Diheptanoic anhydride | [EINECS(EC#)]
210-940-5 | [Molecular Formula]
C14H26O3 | [MDL Number]
MFCD00009536 | [Molecular Weight]
242.35 | [MOL File]
626-27-7.mol |
Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) . | [RIDADR ]
1760 | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29159000 |
Hazard Information | Back Directory | [Chemical Properties]
clear light yellow liquid | [Preparation]
To a flask containing 15.8 gm (0.2 mole) of dry pyridine and 25 ml of dry benzene is rapidly added with stirring 14.8 gm (0.1 mole) of heptanoyl chloride. The reaction is only slightly exothermic and then 13.0 gm (0.1 mole) of heptanoic acid is added dropwise (5 min) causing the temperature to rise to 60-65°C. After stirring for 10 min, the solid (pyridinium hydrochloride) is quickly filtered, washed twice with 25 ml portions of dry benzene, the benzene washings concentrated under reduced pressure, and the residue distilled to afford 19-20 gm (78-83%), b.p. 155-162°C (12 mm Hg), or 170-173°C (15 min).
| [Flammability and Explosibility]
Nonflammable |
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