| Identification | More | [Name]
3-Methylbenzyl bromide | [CAS]
620-13-3 | [Synonyms]
1-(BROMOMETHYL)-3-METHYLBENZENE
3-BROMOMETHYLTOLUENE
3-METHYLBENZYL BROMIDE
A-BROMO-M-XYLENE
ALPHA-BROMO-M-XYLENE
M-METHYLBENZYL BROMIDE
M-XYLYL BROMIDE
1-(bromomethyl)-3-methyl-benzen
alpha-bromo-m-xylen
Benzene, 1-(bromomethyl)-3-methyl-
bromo-xylene
m-(Bromomethyl)toluene
m-Xylene, alpha-bromo-
omega-bromo-m-xylene
alpha-Bromo-m-xylene~m-Xylyl bromide
à-bromo-m-xylene
α-bromo-m-xylene
3-Methylbenzyl bromide 98%
3-METHYLBENZYL BROMIDE/M-XYLYL BROMIDE
alpha-Dibromo-m-xylene | [EINECS(EC#)]
210-625-2 | [Molecular Formula]
C8H9Br | [MDL Number]
MFCD00000177 | [Molecular Weight]
185.06 | [MOL File]
620-13-3.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to light yellow liquid | [Melting point ]
-20.49°C (estimate) | [Boiling point ]
185 °C340 mm Hg(lit.) | [density ]
1.37 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.566(lit.)
| [Fp ]
180 °F
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
Chloroform (Sparingly), Methanol (Slightly) | [form ]
Liquid | [color ]
Clear colorless to light yellow | [Water Solubility ]
practically insoluble | [Detection Methods]
GC,NMR | [Merck ]
14,10090 | [BRN ]
2076425 | [CAS DataBase Reference]
620-13-3(CAS DataBase Reference) | [NIST Chemistry Reference]
1-Bromomethyl-3-methylbenzene(620-13-3) | [EPA Substance Registry System]
620-13-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R20/22:Harmful by inhalation and if swallowed .
R34:Causes burns.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S7/9:Keep container tightly closed and in a well-ventilated place . | [RIDADR ]
UN 1701 6.1/PG 2
| [WGK Germany ]
3
| [RTECS ]
CY9039200 | [Hazard Note ]
Corrosive | [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
29039990 | [Hazardous Substances Data]
620-13-3(Hazardous Substances Data) |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
3-Methyl-1-dibromomethylbenzene-->6-Oxatricyclo[3.2.1.02,7]octan-8-one-->Cobalt, bis[[2,3-butanedione di(oximato-κN)](1-)][(3-methylphenyl)methyl](pyridine)-, (OC-6-12)- (9CI)-->1,3-Bis(bromomethyl)benzene-->1-bromo-2-(bromomethyl)-4-methylbenzene-->Bromotrichloromethane-->3-Methylbenzyl alcohol-->Carbon tetrabromide-->P-XYLENE-->m-Tolualdehyde-->m-Xylene | [Preparation Products]
M-TOLYL-METHANESULFONYL CHLORIDE-->2,4-Dimethylbromobenzene-->METHYL 3-METHYLPHENYLACETATE-->4,4,5,5-tetramethyl-2-(4-((3-methylbenzyl)oxy)phenyl)-1,3,2-dioxaborolane |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to light yellow liquid | [Uses]
3-(Bromomethyl)toluene is used to prepare TNF-??a converting enzyme (TACE) converting enzyme inhibitors. It is also used to synthesize chromen-4-ones as DNA-dependent protein kinase inhibitors. |
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