| Identification | More | [Name]
2,4-Dibromoaniline | [CAS]
615-57-6 | [Synonyms]
2,4-DIBROMOANILINE
2,4-DIBROMOBENZENAMINE
2,4-Dibromanilin
2,4-dibromo-benzenamin
2 4-DIBROMOANILINE 98% (GC)
2,4-Dibromoaniline, 98+% | [EINECS(EC#)]
210-434-4 | [Molecular Formula]
C6H5Br2N | [MDL Number]
MFCD00007633 | [Molecular Weight]
250.92 | [MOL File]
615-57-6.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi,N,T | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R33:Danger of cumulative effects.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R25:Toxic if swallowed. | [Safety Statements ]
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
2811 | [WGK Germany ]
3 | [TSCA ]
T | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29214210 |
| Hazard Information | Back Directory | [Chemical Properties]
beige powder | [Uses]
2,4-Dibromoaniline can be used as:
- A starting material to synthesize acetylenic amine by reacting with trimethylsilylacetylene, which is used as a ligand to prepare the bis-amido complex of Ti(IV).
- A substrate in the Pd-catalyzed ortho-selective cross-coupling reactions of dihaloarenes with Grignard reagents.
- A reactant to prepare dialkyl-substituted aminoaryl sulfides using a Grignard reagent.
- A starting material to synthesize substituted 2-mercapto benzimidazoles.
| [Uses]
2,4-Dibromoaniline is used in preparation of glycopeptides and targeted bifunctional degraders. | [Purification Methods]
Crystallise the aniline from aqueous EtOH. The picrate has m 124o. [Beilstein 12 H 655, 12 I 326, 12 II 356, 12 III 1471, 12 IV 1532.] |
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