Identification | More | [Name]
N,N-Dimethylbenzamide | [CAS]
611-74-5 | [Synonyms]
LABOTEST-BB LT00793055 N,N-DIMETHYLBENZAMIDE Dimethylbenzamide Dimethylbenzmide n,n-dimethyl-benzamid N,N-Dimethylbenzamide98% Benzamide, N,N-dimethyl-(6CI,8CI,9CI) | [EINECS(EC#)]
210-279-2 | [Molecular Formula]
C9H11NO | [MDL Number]
MFCD00008320 | [Molecular Weight]
149.19 | [MOL File]
611-74-5.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R22:Harmful if swallowed. R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [RTECS ]
CV4500000
| [TSCA ]
Yes | [HS Code ]
29242990 |
Hazard Information | Back Directory | [Chemical Properties]
white to slightly yellow cryst. low melting solid | [Uses]
Reagent for deoxygenation of secondary alcohols. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 36, p. 2721, 1971 DOI: 10.1021/jo00817a036 Journal of the American Chemical Society, 77, p. 1114, 1955 DOI: 10.1021/ja01610a010 Synthetic Communications, 12, p. 989, 1982 DOI: 10.1080/00397918208061938 | [General Description]
N,N-Dimethylbenzamide is a hydrotropic agent and its ability to solubilize drugs with low aqueous solubility has been investigated. It reacts with PhLnI complexes (Ln-Eu, Sm, Yb) to yield benzophenone in good yields. Deuterium exchange labelling experimets on N,N-dimethylbenzamide using [IrH2(Me2CO)2(PPh3)2]BF4 as catalyst and deuterium gas as the source of isotope has been conducted. |
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